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81.
Falah Alobaid Nabil Baraki Bernd Epple 《Particuology》2014,(5):41-53
The Euler-Lagrange approach combined with a discrete element method has frequently been applied to elucidate the hydrodynamic behavior of dense fluid-solid flows in fluidized beds. In this work, the efficiency and accuracy of this model are investigated. Parameter studies are performed; in these studies, the stiffness coefficient, the fluid time step and the processor number are varied under conditions with different numbers of particles and different particle diameters. The obtained results are compared with measurements to derive the optimum parameters for CFD/DEM simulations. The results suggest that the application of higher stiffness coefficients slightly improves the simulation accuracy. However, the average computing time increases exponentially. At larger fluid time steps, the results show that the average computation time is independent of the applied fluid time step whereas the simulation accuracy decreases greatly with increasing the fluid time step. The use of smaller time steps leads to negligible improvements in the simulation accuracy but results in an exponential rise in the average computing time. The parallelization accelerates the DEM simulations if the critical number for the domain decomposition is not reached. Above this number, the performance is no longer proportional to the number of processors. The critical number for the domain decomposition depends on the number of particles. An increase in solid contents results in a shift of the critical decomposition number to higher numbers of CPUs. 相似文献
82.
Ricardo G. Simões Ana I. Aleixo Ana L. C. Lagoa Manuel E. Minas da Piedade João P. Leal Thorsten Peitsch Matthias Epple 《Journal of Thermal Analysis and Calorimetry》2010,100(2):509-517
A thermoanalytical, morphological, and structural study of fluoridated calcium phosphates that were prepared by different
variants of a synthesis in anhydrous alcohols is reported. The obtained materials were neither fully amorphous nor single-phased
crystalline, and their nature considerably depended on the synthesis conditions. In all cases, the retention of significant
amounts of solvent in the solid product was observed. A complete removal of the solvent was only possible by heating to temperatures
above ~573–673 K which resulted in variations in the elemental composition, phase changes, and an increase of the crystallinity.
Consequently, this synthesis in anhydrous alcohols is not a viable route to obtain materials with a defined crystallinity
and stoichiometry. 相似文献
83.
Wijs J. J. A. Elsdon G. D. Stubbs J. R. Lührig H. Atkinson H. Azadian A. Spitzer G. Epple F. W. Manley C. H. Shrewsbury H. S. Cocks L. V. Nightingale E. Hoton L. Steuart D. W. Smith P. Leopold G. H. de Mooy W. J. Gilmour G. van B. Blichfeldt S. H. Thornley T. Smith E. L. Kaufmann H. P. Bolton E. R. Revis C. 《Analytical and bioanalytical chemistry》1930,80(7-8):303-314
Analytical and Bioanalytical Chemistry - 相似文献
84.
85.
86.
Calcium phosphate nanoparticles can be prepared in almost uniform size and shape by a continuous precipitation process that also allows their functionalisation by organic molecules (DNA, surfactants). 相似文献
87.
Weiss N Cren T Epple M Rusponi S Baudot G Rohart S Tejeda A Repain V Rousset S Ohresser P Scheurer F Bencok P Brune H 《Physical review letters》2005,95(15):157204
We report on the magnetic properties of two-dimensional Co nanoparticles arranged in macroscopically phase-coherent superlattices created by self-assembly on Au(788). Our particles have a density of 26 Tera/in2 (1 Tera=10(12)), are monodomain, and have uniaxial out-of-plane anisotropy. The distribution of the magnetic anisotropy energies has a half width at half maximum of 17%, a factor of 2 more narrow than the best results reported for superlattices of three-dimensional nanoparticles. Our data show the absence of magnetic interactions between the particles. Co/Au(788) thus constitutes an ideal model system to explore the ultimate density limit of magnetic recording. 相似文献
88.
Inhaltsübersicht. Fluortrirutile LiMIIMIIIF6 kristallisieren tetragonal in dor Raumgruppe P42/mnm mit Li in Position (2a) und MII und MIII statistisch vorteilt in (4e). An Einkristallen und durch Pulvermessungen wurde die Verteilung der Kationen untersucht, wozu die neu dargestellte Rhodiumverbindung LiZnRhF6 auf Grund des unterschiedlichen Streuvermögens der Kationen besonders geeignet war. Verbindungen LiCuMIIIF6 zeigen die einfache Rutilstruktur. Investigations of the Quaternary Fluorides LiMIIMIIIF6. On the Distribution of Cations in Fluorotrirutiles Abstract. Trirutiles LiMIIMIIIF6 crystallize tetragonally in the space group P42/mnm with Li in position (2a) und MII and MIII statistically distributed in (4e). By single-crystal X-Ray diffraction and by powder work cation ordering was examined for which the new compound LiZnRhF, was especially adapted. Compounds LiCuMIIIF6 are disordered rutile phases. 相似文献
89.
Two microporous biodegradable polyesters, i.e., PGA and PDLLA, were obtained by solid-state polymerization reaction from the sodium salts of the corresponding alpha-hydroxycarboxylic acids after washing out the by-product sodium chloride. The polymers were shaped by cold uniaxial pressing, by hot uniaxial pressing, and by extrusion at elevated temperature. Due to the special microporosity of the polymers, the introduction of drugs is possible at moderate temperature. The release kinetics of the model drug Phe and of the anti-tumor drug goserelin (an LH-RH agonist) from compacted polymer samples were fast (approx. 2 d). The release kinetics of goserelin were corrected for the decomposition of the drug. External coatings with PDLLA or PLLA obtained by immersion in polymer solution strongly slowed down the release kinetics in the case of the PDLLA coating, giving an almost linear release during 100 d. A coating with PLLA was unsuitable to slow down the release kinetics. 相似文献
90.
Michael Maas Heinz Rehage Holger Nebel Matthias Epple 《Colloid and polymer science》2007,285(12):1301-1311
In this publication, we describe the growth of thin films of calcium carbonate beneath Langmuir monolayers of stearic acid.
The size and shape of the crystalline structures were systematically studied by means of different microscopic techniques
including Brewster angle microscopy, atomic force microscopy and scanning electron microscopy. In a series of experiments,
we explored the calcium carbonate crystallization process for different lipid monolayers and subphases. The observed phenomena
support a crystallization process which is induced by a thin, film-like structure of a precursor phase. The basic processes
of crystal and aggregate formation can be represented by a simple model which is based on electrostatic interactions between
the surfactant film and the inorganic calcium carbonate structures. 相似文献