全文获取类型
收费全文 | 127篇 |
免费 | 2篇 |
专业分类
化学 | 99篇 |
晶体学 | 1篇 |
力学 | 3篇 |
数学 | 9篇 |
物理学 | 17篇 |
出版年
2022年 | 2篇 |
2021年 | 4篇 |
2019年 | 2篇 |
2015年 | 4篇 |
2014年 | 8篇 |
2013年 | 6篇 |
2012年 | 3篇 |
2011年 | 6篇 |
2010年 | 2篇 |
2009年 | 1篇 |
2008年 | 7篇 |
2007年 | 1篇 |
2006年 | 2篇 |
2005年 | 4篇 |
2004年 | 3篇 |
2003年 | 11篇 |
2002年 | 14篇 |
2001年 | 12篇 |
2000年 | 5篇 |
1999年 | 2篇 |
1998年 | 6篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1995年 | 5篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1976年 | 2篇 |
1972年 | 4篇 |
1930年 | 2篇 |
排序方式: 共有129条查询结果,搜索用时 15 毫秒
11.
12.
The three water‐free calcium carbonate polymorphs calcite, aragonite and vaterite were prepared from aqueous solutions without additives using standard laboratory equipment in a continuous process. Variation parameters were the way of mixing, the solution concentrations, and the reactor residence time. The samples were crystallographically and chemically pure, but a thorough elemental analysis revealed the presence of small amounts of sodium carbonate which was not detectable by X‐ray powder diffraction. The continuous process avoids the inherent variability of batch syntheses. By adapting the crystallization parameters, magnesium‐substituted amorphous calcium carbonate (molar ratio of Mg:Ca of 1:2.68) was prepared in this continuous process. 相似文献
13.
14.
Paulo Debiagi Coskun Yildiz Marcel Richter Jochen Ströhle Bernd Epple Tiziano Faravelli Christian Hasse 《Proceedings of the Combustion Institute》2021,38(3):4053-4061
Coal combustion releases elevated amounts of pollutants to the atmosphere including SOX. During the pyrolysis step, sulfur present in the coal is released to the gas phase as many different chemical species such as H2S, COS, SO2, CS2, thiols and larger tars, also called SOX precursors, as they form SOX during combustion. Understanding the sulfur release process is crucial to the development of reliable kinetic models, which support the design of improved reactors for cleaner coal conversion processes. Sulfur release from two bituminous coals, Colombian hard coal (K1) and American high sulfur coal (U2), were studied in the present work. Low heating rate (LHR) experiments were performed in a thermogravimetric analyzer coupled with mass spectrometry (TG-MS), allowing to track the mass loss and the evolution of many volatile species (CO, CO2, CH4, SO2, H2S, COS, HCl and H2O). High heating rate (HHR) experiments were performed in an entrained flow reactor (drop-tube reactor – DTR), coupled with MS and nondispersive infrared sensor (NDIR). HHR experiments were complemented with CFD simulation of the multidimentional reacting flow field. A kinetic model of coal pyrolysis is employed to reproduce the experiments allowing a comprehensive assessment of the process. The suitability of this model is confirmed for LHR. The combination of HHR experiments with CFD simulations and kinetic modeling revealed the complexity of sulfur chemistry in coal combustion and allowed to better understand of the individual phenomena resulting in the formation of the different SOX precursors. LHR and HHR operating conditions lead to different distribution of sulfur species released, highly-dependent on the gas-phase temperature and residence time. Higher retention of total sulfur in char is observed at LHR (63%) when compared to HHR (37–44%), at 1273 K. These data support the development of reliable models with improved predictability. 相似文献
15.
16.
Characterisation of exosomes derived from human cells by nanoparticle tracking analysis and scanning electron microscopy 总被引:1,自引:0,他引:1
Sokolova V Ludwig AK Hornung S Rotan O Horn PA Epple M Giebel B 《Colloids and surfaces. B, Biointerfaces》2011,87(1):146-150
Exosomes from three different cell types (HEK 293T, ECFC, MSC) were characterised by scanning electron microscopy (SEM), dynamic light scattering (DLS) and nanoparticle tracking analysis (NTA). The diameter was around 110 nm for the three cell types. The stability of exosomes was examined during storage at -20°C, 4°C, and 37°C. The size of the exosomes decreased at 4°C and 37°C, indicating a structural change or degradation. Multiple freezing to -20°C and thawing did not affect the exosome size. Multiple ultracentrifugation also did not change the exosome size. 相似文献
17.
18.
The solvent-free reduction of benzophenone and five substituted benzophenones with sodium borohydride to the corresponding alcohols was studied by thermal analysis, X-ray powder diffractometry, NMR spectroscopy, and scanning electron microscopy. In most cases, the reaction occurs via liquid eutectic phases that are formed between the benzophenone and the resulting benzohydrol. Nevertheless, this reaction can be carried out without the need for a solvent, leading to pure alcohol without side products. In some cases, heating may be necessary to achieve a reasonably short reaction time. In conclusion, this reaction type appears to be feasible as a preparative organic reaction that avoids a solvent.This revised version was published online in November 2005 with corrections to the Cover Date. 相似文献
19.
20.