全文获取类型
收费全文 | 194篇 |
免费 | 7篇 |
专业分类
化学 | 165篇 |
晶体学 | 3篇 |
力学 | 2篇 |
数学 | 19篇 |
物理学 | 12篇 |
出版年
2023年 | 2篇 |
2022年 | 1篇 |
2021年 | 2篇 |
2020年 | 4篇 |
2019年 | 2篇 |
2018年 | 4篇 |
2017年 | 1篇 |
2016年 | 2篇 |
2015年 | 4篇 |
2014年 | 3篇 |
2013年 | 10篇 |
2012年 | 3篇 |
2011年 | 5篇 |
2010年 | 4篇 |
2009年 | 5篇 |
2008年 | 8篇 |
2007年 | 17篇 |
2006年 | 4篇 |
2005年 | 14篇 |
2004年 | 9篇 |
2003年 | 9篇 |
2002年 | 17篇 |
2001年 | 13篇 |
2000年 | 6篇 |
1999年 | 6篇 |
1998年 | 5篇 |
1997年 | 13篇 |
1996年 | 4篇 |
1995年 | 4篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1984年 | 1篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1972年 | 2篇 |
1968年 | 1篇 |
1882年 | 1篇 |
排序方式: 共有201条查询结果,搜索用时 31 毫秒
71.
G. Becker O. Mundt M. Sachs H. J. Breunig E. Lork J. Probst A. Silvestru 《无机化学与普通化学杂志》2001,627(4):699-714
Element–Element Bonds. X. Studies of Chloro(diphenyl)stibane, Tribenzylstibane and Tribenzyldibromostiborane – Molecular Structures and Isotypism Chlorodiphenylstibane ( 1 d ) {P21/c; Z = 4; a = 1191.8(1); b = 853.4(1); c = 1112.0(1) pm; β = 93.60(1)°; –100 ± 2 °C} crystallizes isotypically with a series of homologous (H5C6)2E–X compounds (E = As, X = Cl, Br, I; E = Sb, X = Br, I); the structure type of tribenzylstibane ( 5 d ) {Pbca; Z = 8; a = 832.1(2); b = 2681.3(5) pm; c = 1600.9(3); –100 ± 3 °C} is already known from tribenzylmethanol, ‐silanol and ‐silane. Tribenzyldibromostiborane ( 6 ) {P21/n; Z = 4; a = 938.4(2); b = 2292.4(5); c = 1019.7(2) pm; β = 112.71(1)°; –100 ± 3 °C} does not show an analogous relationship to known structure types. Characteristic mean bond lengths and angles are { 1 d , Sb–Cl 240.9(1), Sb–C 214.0 pm, Cl–Sb–C 93.8°, C–Sb–C 98.6(1)°; 5 d , Sb–C 217.5(3) pm, C–Sb–C 94.9(6)°; 6 , Sb–Br 264.6; Sb–C 217.0(8) pm, Br–Sb–Br 179.4(1)°; C–Sb–C 120°; Br–Sb–C 84.8(2)° to 94.7(2)°}. Stiborane 6 exhibits very weak intermolecular Sb‥Br interactions of 417 pm which, however, affect the molecular conformation in a striking way. 相似文献
72.
A [2]-catenane consisting of methylene groups and two additional acetylated aza groups has been synthesized in a multi-step sequence. After splitting off the acetyl bonds, the resulting secondary diamine should provide a good starting material for stepreaction (condensation or addition, respectively) polymerization. 相似文献
73.
74.
75.
Hans Fritz Paul Hug Hanspeter Sauter Tammo Winkler Enno Logemann 《Magnetic resonance in chemistry : MRC》1977,9(2):108-112
Carbon-13 n.m.r. spectra of formic, acetic, propionic and butyric acid amides with N,N-di-n-alkyl substituents have been completely assigned with the aid of extensive double resonance experiments. The data obtained were used to study long range steric effects on chemical and solvent shifts. 相似文献
76.
77.
We consider triangular arrays of Markov chains that converge weakly to a diffusion process. Local limit theorems for transition
densities are proved.
Received: 28 August 1998 / Revised version: 6 September 1999 / Published online: 14 June 2000 相似文献
78.
Ole Mallow Monther A. Khanfar Moritz Malischewski Pamela Finke Malte Hesse Enno Lork Timo Augenstein Frank Breher Jeffrey R. Harmer Nadezhda V. Vasilieva Andrey Zibarev Artem S. Bogomyakov Konrad Seppelt Jens Beckmann 《Chemical science》2015,6(1):497-504
One-electron oxidation of two series of diaryldichalcogenides (C6F5E)2 (13a–c) and (2,6-Mes2C6H3E)2 (16a–c) was studied (E = S, Se, Te). The reaction of 13a and 13b with AsF5 and SbF5 gave rise to the formation of thermally unstable radical cations [(C6F5S)2]˙+ (14a) and [(C6F5Se)2]˙+ (14b) that were isolated as [Sb2F11]– and [As2F11]– salts, respectively. The reaction of 13c with AsF5 afforded only the product of a Te–C bond cleavage, namely the previously known dication [Te4]2+ that was isolated as [AsF6]– salt. The reaction of (2,6-Mes2C6H3E)2 (16a–c) with [NO][SbF6] provided the corresponding radical cations [(2,6-Mes2C6H3E)2]˙+ (17a–c; E = S, Se, Te) in the form of thermally stable [SbF6]– salts in nearly quantitative yields. The electronic and structural properties of these radical cations were probed by X-ray diffraction analysis, EPR spectroscopy, and density functional theory calculations and other methods. 相似文献
79.
Carsten Knapp Tobias Borrmann Enno Lork Paul G. Watson Wolf-Dieter Stohrer Rüdiger Mews 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4-5):887-890
The bicyclic sulfur-nitrogen heterocycle F3CCN5S3 (1) was investigated as a donor and acceptor toward H+, metal cations, and F?. Whereas the protonated species F3CCN5S3H+ AsF6 ? (2) can be isolated, the product of the reaction with F? is unstable and decomposes among other products to TAS+ F3CCN5S3NC(NH2)CF3 ? (3), which is isolated from this reaction in small amounts. 相似文献
80.