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61.
Carsten Knapp Enno Lork Tobias Borrmann Wolf‐Dieter Stohrer Rüdiger Mews 《无机化学与普通化学杂志》2005,631(10):1885-1892
Attempts to prepare t‐BuCN5S3 and the unexpected Isolation of a covalent Modification of Tetrasulfur‐pentanitrogen Chloride S4N5Cl Attempts to prepare the bicyclic sulfur‐nitrogen heterocycle t‐BuCN5S3 via (NSCl)3 and the corresponding silylated amidinates and amidines failed because of the inaccessibility of the silylated intermediates. Reactions of MN(SiMe3)2 (M = Li, Na) with t‐BuCN did not yield the expected amidinates t‐BuC(NSiMe3)2M, instead the adducts [t‐BuCN·MN(SiMe3)2]2 were isolated. The attempted synthesis of t‐BuCN5S3 from t‐BuCN(SiMe3)2M, prepared in situ from t‐BuLi and Me3SiNCNSiMe3, and (NSCl)3 unexpectedly resulted a mixture of S4N5Cl and S5N6. The crystal structure determination for S4N5Cl showed a new covalent modification of S4N5Cl (monoclinic, P21/c, a = 1005.0(4) pm, b = 1193.5(8) pm, c = 1152.5(6) pm, β = 93.67(3)°), different from the known ionic S4N5Cl (orthorhombic, Pnma, a = 1738.90(10) pm, b = 781.50(10) pm, c = 483.03(5)). The unsuccessful attempts to prepare t‐BuCN5S3, the unexpected formation of S4N5Cl and S5N6, and the bonding properties of the new covalent modification of S4N5Cl are discussed. 相似文献
62.
Opris LM Silvestru A Silvestru C Breunig HJ Lork E 《Dalton transactions (Cambridge, England : 2003)》2004,(21):3575-3585
The cyclostibane R(4)Sb(4)(1)(R = 2-(Me(2)NCH(2))C(6)H(4)) was synthesized by reduction of RSbCl(2) with Mg in THF or with Na in liquid NH(3). The reaction of 1 with [W(CO)(5)(THF)] gives the stibinidene complex RSb[W(CO)(5)](2)(2). RSbCl(2) and (RSbCl)(2)E [E = O (6), E = S (8)] react with KOH or Na(2)S in toluene/water to give the heterocycles (RSbE)(n)[E = O, n= 3 (3); E = S, n= 2 (4)]. The chalcogeno-bridged compounds of the type (RSbCl)(2)E [E = O (6), E = S (8)] were synthesized by reaction of RSbCl(2) with KOH or Na(2)S in toluene/water, but also by reaction of RSbCl(2) with the heterocycles (RSbE)(n). The compounds (RSbI)(2)O (7) and (RSbBr)(2)S (9) were prepared via halogen-exchange reactions between (RSbCl)(2)E and NaI (E = O) or KBr (E = S) or by reactions between RSbI(2) and KOH or RSbBr(2) and Na(2)S. The reaction of cyclo-(RSbS)(2) with W(CO)(5)(THF) in THF results in trapping of the cis isomer in cyclo-(RSbS)(2)[W(CO)(5)](5). The solution behaviour of the compounds was investigated by (1)H and (13)C NMR spectroscopy. The molecular structures of compounds 1-7 and 9 were determined by single-crystal X-ray diffraction. 相似文献
63.
Kolomeitsev AA Bissky G Barten J Kalinovich N Lork E Röschenthaler GV 《Inorganic chemistry》2002,41(23):6118-6124
Hexaalkylguanidinium and 2-(dialkylamino)-1,3-dimethylimidazolinium trimethyldifluorosiliconates, precursors for two stable hexaalkylguanidinium perfluoroalkoxides, were synthesized by treating commercially available bis(dialkylamino)difluoromethane derivatives with (dialkylamino)trimethylsilanes in aprotic media. With hexamethylguanidinium pentafluoroethoxide the introduction of the lipophilic and electronegative C2F5O group was straightforwardly achieved in the case of primary and secondary alkyl triflates to furnish the respective fluorinated ethers. The molecular structures of [(CH2NMe)2C(NEt2)]+[Me3SiF2]- and [C(NMe2)3]+F-*6CH2Cl2 were determined, showing in the latter case a fluoride anion octahedrally coordinated by six methylene chloride molecules via hydrogen bridges with a F...H distance of 205 pm (C...F distance 270.0(3) pm). 相似文献
64.
By oxidation of 3-thioderivatives of 1,2,4-triazine 1a,b 3-alkylsulfonic derivatives 2a,b were obtained. Interaction of the sulfonic derivative 2a with indole leads to 3-oxo-5-indolyl-5-phenyl-as-triazine 4. The sulfone 2a reacts with 1-ethyl-2,6-dimethylquinolinium iodide to give 3-(1-ethyl-6-methyl-1,2-dihydroquinoline-2-methylene)-5-phenyl-1,2,4-triazine 5. The 3-morpholino- 3 and 3-thioderivatives 6, 7a,b of as-triazine were obtained by interaction of the sulfone 2 with morpholine and organic boron-containing thiols. The crystal structure of boron-containing derivative of as-triazine 7b was investigated by X-ray analysis. 相似文献
65.
Shevchenko I Andrushko V Lork E Röschenthaler GV 《Chemical communications (Cambridge, England)》2002,(2):120-121
The oxidation of bis[bis(dialkylamino)phosphinyl]methane 1 with 5,5,5-trifluoro-4-(trifluoromethyl)penta-3-en-2-one 2 unexpectedly gave zwitterionic compound 7 which according to X-ray analysis contains two phosphorus atoms of opposite charge and different coordination number (lambda 4P(+); lambda 6P(-)) with a direct P-H bond at the hexacordinated phosphorus. 相似文献
66.
67.
68.
cis‐trans‐Isomerism in (Me4Sb)2[Ph2Sb2I6] Crystals of cis‐(Me4Sb)2[Ph2Sb2I6] ( 1 a ) are formed by reaction of PhSbI2 and Me4SbI in ethanol/petroleum ether at –7 °C. In ethanol/acetone crystals of trans‐(Me4Sb)2[Ph2Sb2I6] · acetone ( 1 b ) form. The X‐ray crystal structure analyses reveal that both isomers consist of tetrahedral cations and of dimeric anions with the geometry of two edge sharing tetragonal pyramids. The phenyl groups possess apical cis ( 1 a ) or trans ( 1 b ) positions relative to the I2SbI2SbI2 plane. The acetone molecules in 1 b are non coordinating. 相似文献
69.
Dmitri V. Sevenard Enno Lork Kazimir I. Pashkevich Gerd‐Volker Rschenthaler 《Heteroatom Chemistry》2002,13(2):97-107
The reactivity of 2‐polyfluoroacylcycloalkanones and their O‐silylated derivatives towards phosphites and tris(trimethylsilyl)aminoiminophosphine has been investigated. From α‐polyfluoroalkyl substituted phosphonates, generated from tris(trimethylsilyl) phosphite and 1,3‐diketones, the respective phosphonic acids and their salts have been obtained. In one case, upon warming, a phosphonic acid underwent a ring closure to yield an oxaphospholene. 2‐Trifluoroacetylcycloalkanones and diethyl isocyanatophosphite furnished phosphoranes diastereospecifically, via addition of phosphorus at the trifluoroacetyl group and two additional heterocyclizations. Tris(trimethylsilyl)aminoiminophosphine formed very reactive trimethylsilylimino‐1,2λ5σ4‐phospholenes, which added hexafluoroacetone to give spirocyclic 1,3,2λ5σ5‐oxazaphosphetanes. The structures of the new compounds were determined by NMR spectroscopy and X‐ray single crystal analysis. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:97–107, 2002; Published online in Wiley Interscience (www.interscience.wiley.com). DOI 10.1002/hc.10001 相似文献
70.
G. Becker O. Mundt M. Sachs H. J. Breunig E. Lork J. Probst A. Silvestru 《无机化学与普通化学杂志》2001,627(4):699-714
Element–Element Bonds. X. Studies of Chloro(diphenyl)stibane, Tribenzylstibane and Tribenzyldibromostiborane – Molecular Structures and Isotypism Chlorodiphenylstibane ( 1 d ) {P21/c; Z = 4; a = 1191.8(1); b = 853.4(1); c = 1112.0(1) pm; β = 93.60(1)°; –100 ± 2 °C} crystallizes isotypically with a series of homologous (H5C6)2E–X compounds (E = As, X = Cl, Br, I; E = Sb, X = Br, I); the structure type of tribenzylstibane ( 5 d ) {Pbca; Z = 8; a = 832.1(2); b = 2681.3(5) pm; c = 1600.9(3); –100 ± 3 °C} is already known from tribenzylmethanol, ‐silanol and ‐silane. Tribenzyldibromostiborane ( 6 ) {P21/n; Z = 4; a = 938.4(2); b = 2292.4(5); c = 1019.7(2) pm; β = 112.71(1)°; –100 ± 3 °C} does not show an analogous relationship to known structure types. Characteristic mean bond lengths and angles are { 1 d , Sb–Cl 240.9(1), Sb–C 214.0 pm, Cl–Sb–C 93.8°, C–Sb–C 98.6(1)°; 5 d , Sb–C 217.5(3) pm, C–Sb–C 94.9(6)°; 6 , Sb–Br 264.6; Sb–C 217.0(8) pm, Br–Sb–Br 179.4(1)°; C–Sb–C 120°; Br–Sb–C 84.8(2)° to 94.7(2)°}. Stiborane 6 exhibits very weak intermolecular Sb‥Br interactions of 417 pm which, however, affect the molecular conformation in a striking way. 相似文献