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21.
MnSi is a ferromagnetic compound with a Curie temperature of 29 K. Recent theoretical studies predict that 2 ML of MnSi epitaxially grown on Si show a ferromagnetic metallic ground state with spin polarization of about 50%. This would allow the development of spintronic devices based on the injection of spin-polarized current from a ferromagnetic metal into a semiconductor.In this context the possibility of growing in situ MnSi on the Si(1 1 1) surface has been explored. Thermal reaction, crystalline structure and electronic properties of the grown films have been studied in situ by photoemission spectroscopy (PES), X-ray absorption spectroscopy (XAS), and low energy electron diffraction (LEED). Depositing a thin film of Mn on Si(1 1 1) the formation of ordered islands (with dimensions dependent on the amount of deposited Mn) is driven by annealing at selected temperatures, as already observed. Our preliminary studies show that by simultaneously depositing Mn and Si in 1:1 stoichiometry on Si(1 1 1) a large improvement in the homogeneity of the MnSi films is achieved.  相似文献   
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Some results recently published on the o-Ps quenching reactions promoted by FeCl2 and K2Cr2O7 in glycerol aqueous solutions were interpreted by supposing that a significant fraction of o-Ps atoms diffuses by a quantum-mechanical effect or in quasi-free states even at room temperature. It is shown that the results can be interpreted in a different manner, so they cannot be invoked for supporting the hypotheses mentioned above about the mechanism of o-Ps diffusion at room temperature.  相似文献   
24.
Sunto In questo lavoro do una definizione della misura (r − 1)-dimensionale della frontiera orientata di un insieme diBorel contenuto in uno spazio euclideo ad r dimensioni e dimostro alcune fra le più notevoli proprietà di tale misura. Lavoro eseguito nell'Istituto Nazionale per le Applicazioni del Calcolo.  相似文献   
25.
A careful analysis of the rotovibrational spectroscopic data of CH3CN is presented taking into account Fermi and Coriolis interactions. A large majority of the FIR lines obtained by optical pumping is assigned. New values are proposed for some molecular constants and the need of more accurate experimental investigation is pointed out.  相似文献   
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Three new polymeric squarato-bridged manganese complexes {[Mn(H(2)O)(2)(bpe)(sq)].bpe.H(2)O}(n) (1), [Mn(2)(H(2)O)(4)(phen)(2)(sq)(2)](n) (2) and [Mn(2)(H(2)O)(2)(phen)(4)(sq)].(sq).8(H(2)O) (3) [bpe, 1,2-bis(4-pyridyl)ethane; phen, 1,10-phenanthroline; sq, squarate dianion] have been synthesized and characterized by single crystal X-ray diffraction analysis and variable temperature magnetic studies. Complex 1 is a 2D rectangular grid-like structure, achieved through flexible bpe bridging ligands and squarate dianions. On the other hand the use of chelating phen instead of bpe gives rise to a 1D polymeric chain in complex 2 and to a dinuclear entity in 3. In all the three complexes weak interactions play a vital role in stabilizing the solid-state structure. Variable temperature (2-300 K) magnetic studies indicate weak antiferromagnetic coupling between the metal centres in all the complexes.  相似文献   
28.
A series of dinuclear copper(II) complexes has been synthesized with the aim to investigate their applicability as potential structure and function models for the active site of catechol oxidase enzyme. They have been characterized by routine physicochemical techniques as well as by X-ray single-crystal structure analysis: [Cu 2(H 2L2 (2))(OH)(H 2O)(NO 3)](NO 3) 3.2H 2O ( 1), [Cu(HL1 (4))(H 2O)(NO 3)] 2(NO 3) 2.2H 2O ( 2), [Cu(L1 (1))(H 2O)(NO 3)] 2 ( 3), [Cu 2(L2 (3))(OH)(H 2O) 2](NO 3) 2, ( 4) and [Cu 2(L2 (1))(N 3) 3] ( 5) [L1 = 2-formyl-4-methyl-6R-iminomethyl-phenolato and L2 = 2,6-bis(R-iminomethyl)-4-methyl-phenolato; for L1 (1) and L2 (1), R = N-propylmorpholine; for L2 (2), R = N-ethylpiperazine; for L2 (3), R = N-ethylpyrrolidine, and for L1 (4), R = N-ethylmorpholine]. Dinuclear 1 and 4 possess two "end-off" compartmental ligands with exogenous mu-hydroxido and endogenous mu-phenoxido groups leading to intermetallic distances of 2.9794(15) and 2.9435(9) A, respectively; 2 and 3 are formed by two tridentate compartmental ligands where the copper centers are connected by endogenous phenoxido bridges with Cu-Cu separations of 3.0213(13) and 3.0152(15) A, respectively; 5 is built by an end-off compartmental ligand having exogenous mu-azido and endogenous mu-phenoxido groups with a Cu-Cu distance of 3.133(2) A (mean of two independent molecules). The catecholase activity of all of the complexes has been investigated in acetonitrile and methanol medium by UV-vis spectrophotometric study using 3,5-di- tert-butylcatechol (3,5-DTBC) and tetrachlorocatechol (TCC) as substrates. In acetonitrile medium, the conversion of 3,5-DTBC to 3,5-di- tert-butylbenzoquinone (3,5-DTBQ) catalyzed by 1- 5 is observed to proceed via the formation of two enzyme-substrate adducts, ES1 and ES2, detected spectroscopically for the first time. In methanol medium no such enzyme-substrate adduct has been detected, and the 3,5-DTBC to 3,5-DTBQ conversion is observed to be catalyzed by 1- 5 very efficiently. The substrate TCC forms an adduct with 2- 5 without performing further oxidation to TCQ due to the high reduction potential of TCC (in comparison with 3,5-DTBC). But most interestingly, 1 is observed to be effective even in TCC oxidation, a process never reported earlier. Kinetic experiments have been performed to determine initial rate of reactions (3,5-DTBC as substrate, in methanol medium) and the activity sequence is 1 > 5 > 2 = 4 > 3. A treatment on the basis of Michaelis-Menten model has been applied for kinetic study, suggesting that all five complexes exhibit very high turnover number, especially 1, which exhibits turnover number or K cat of 3.24 x 10 (4) (h (-1)), which is approximately 3.5 times higher than the most efficient catalyst reported to date for catecholase activity in methanol medium.  相似文献   
29.
Polymeric networks, {[Co(dpyo)(ox)]}(n) (1), {[Co(dpyo)(fum)(H(2)O)(2)]}(n) (1) and {[Co(dpyo)(tp)(H(2)O)(2)] x [Co(H(2)O)(6)] x (tp) x (H(2)O)}(n) (3) [ox = oxalate dianion, fum = fumarate dianion, tp = terephthalate dianion and dpyo = 4,4'-dipyridyl N,N'-dioxide] have been synthesized and characterized by single crystal X-ray diffraction analyses. The structural determination reveals 1 and 2 are covalent bonded 2D networks of 4,4 topology and of these, complex 2 undergoes a H-bonding scheme resulting in a 3D supramolecular architecture. Complex 3 is a 1D coordination polymer built up by almost collinear hexacoordinated Co(ii), doubly bridged by a tp carboxylate group and a dpyo oxygen, which in combination with lattice [Co(H(2)O)(6)](2+), tp and water molecules shows an unprecedented 3D supramolecular network through H-bonding. In the polymer the dpyo shows novel mu-4,4 bridging mode towards the cobalt ion. Low temperature magnetic interaction reveals antiferromagnetic coupling in all of the complexes.  相似文献   
30.
Two coordination polymers, [Cu(bpp)(H2O)2(ClO4)2]n (1) and {[Cu(bpds)2(ClO4)2] · 1.5(H2O)}n (2) [bpp, 1,3-bis(4-pyridyl)propane and bpds, 4,4′-bipyridyl disulfide] have been synthesized and characterized by X-ray single crystal diffraction study and magnetic measurement. Both the coordination polymers display 1D chains with perchlorate anions acting as pendant ligands. In 1 undulated polymers are built by Cu(H2O)2(ClO4)2 units connected by single bpp and in complex 2 Cu(ClO4)2 fragments are linked by pairs of bpds ligands to form a double-stranded chain. The crystal packing evidences polymers of 1 involved in weak H-bonding interactions leading to a 3D supramolecular network. Magnetic study reveals weak antiferromagnetic interactions in both complexes.  相似文献   
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