Vapoluminescent Behavior and the Single-Crystal-to-Single-Crystal Transformations of Chloroform Solvates of [Au2(μ-1,2-bis(diphenylarsino)ethane)2](AsF6)2

The mono- and di-chloroform solvates of [Au₂(μ-1,2-bis(diphenylarsino)ethane)₂](AsF₆)₂ undergo single-crystal-to-single-crystal transformations that result in gain (over 12 hours) or slow loss (over five years) of only one chloroform molecule. The change in solvation results in changes in the structure and luminescence of the digold cation. The cation consists of a pair of slightly bent As-Au-As units that are connected through the two bridging dpae ligands and by aurophilic interactions with Au⋅⋅⋅Au contacts of 3.05152(15) Å in the disolvate or 2.9570(5) Å in the monosolvate.     

Application of Polysaccharide Microarray Technology for the Serodiagnosis of Burkholderia pseudomallei Infection (Melioidosis) in Humans

Burkholderia pseudomallei is the causative agent of melioidosis, a bacterial infection endemic in tropical regions including southeast Asia and northern Australia. B. pseudomallei contains structurally unique polysaccharides (capsular polysaccharide and O?antigen saccharides of lipopolysaccharide). A polysaccharide microarray platform was developed by immobilizing these polysaccharides onto glass slides. Employing this microarray, we were able to demonstrate the presence of antibodies to these polysaccharide antigens in the sera of melioidosis patients, but not in serum from nonmelioidosis human subjects. The advantages of this polysaccharide microarray technology over the conventional tests for the serodiagnosis of melioidosis are discussed.     

Synthesis and Characterization of Flexible Hydrogel Electrodes for Electrochemical Impedance Measurements of Protective Coatings on Metal Sculptures

A novel conductive anionic hydrogel was synthesized for use as a solid electrolyte for electrochemical impedance spectroscopy (EIS) characterization of the barrier properties of protective coatings on outdoor metalworks, such as bronze sculptures. The AMPS‐co‐PAA hydrogel was soaked in a variety of aqueous salt solutions and characterized by swelling capacity and conductivity in order to determine the most appropriate gel/liquid electrolyte combination for use on culturally significant objects. K₂PIPES‐equilibrated hydrogels were selected as the preferred electrodes for this particular application and were used to measure the impedance of a coated substrate, yielding spectra similar to those from standard liquid cells.     

3He D-state effects in (d, 3He) reactions

The tensor analysing power of the ²⁷Al(d, ³He)²⁶Mg reaction has been measured at E_d = 12.4 MeV. The results are reproduced by predictions of the DWBA including D-state components in the ³He wave function. The magnitude of the tensor analysing power provides information on the asymptotic D-state to S-state ratio in the ³He wave function. The value obtained for ³He is in agreement with the corresponding value for ³H.     

The elastic scattering of polarized 3He by 3He and excitation in the 6Be system

Angular distributions of the polarization in the elastic scattering of ³He by ³He have been measured at eight energies between 18 and 33 MeV, corresponding to excitation of ⁶Be between 20.5 and 28 MeV. The measurements were made using the 33 MeV polarised ³He beam at the University of Birmingham Radial Ridge cyclotron and a small gas target. The data have been analysed in terms of real and complex phase shifts. The deduced phase shift energy dependence cannot be associated with a single isolated level in ⁶Be, however an application of the two-level R-matrix formula reveals some broad L = 3 structures around E_x = 25 MeV.     

Morphogen gradient from a noisy source

We investigate the effect of time-dependent noise on the shape of a morphogen gradient in a developing embryo. Perturbation theory is used to calculate the deviations from deterministic behavior in a simple reaction-diffusion model of robust gradient formation, and the results are confirmed by numerical simulation. It is shown that such deviations can disrupt robustness for sufficiently high noise levels, and the implications of these findings for more complex models of gradient-shaping pathways are discussed.     

Bending Solutions for Inhomogeneous and Laminated Elastic Plates

A procedure has been developed in previous papers for constructing exact solutions of the equations of linear elasticity in a thick plate of inhomogeneous isotropic linearly elastic material in which the elastic moduli depend in any specified manner on a coordinate normal to the plane of the plate. The essential idea is that any solution of the classical thin plate or classical laminate theory equations (which are two-dimensional theories) generates, by straightforward substitutions, a solution of the three-dimensional elasticity equations for the homogeneous material. Recently this theory has been formulated in terms of functions of a complex variable. It was shown that the displacement and stress fields in the inhomogeneous material could be expressed in terms of four complex potentials that are analytic functions of the complex variable ζ = x + iy in the mid-plane of the plate. However, the analysis performed so far applies only to the case of a plate with traction-free upper and lower faces. The present paper extends these solutions to the case where the plate is bent by a pressure distribution applied to a face.     

Investigation of the effect of electron cyclotron heating on runaway generation in the KSTAR tokamak

Wave enhanced runaway generation is expected to play an important role in the conversion of plasma current into runaway current during major disruptions. The fast electrons created by electron cyclotron heating (ECH) were used to study this issue in KSTAR. It is found that the fast electrons driven by ECH can enhance runaway production in the flat top phase with high loop voltage. The runaway current in disruptions was not enhanced by the ECH produced fast electron population due to the strong magnetic fluctuations which inhibited the generation of runaway electrons. It is found that a complete loss of existing REs during thermal quench has occurred in KSTAR limiter configuration discharges.