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71.
Four unsymmetrical vic-dioximes: [L1H2] N-(4-butylphenyl)amino-amphi-glyoxime, [L2H2] N-(4-butylphenyl)amino-anti-glyoxime, [L3H2] N-(4-phenylazophenyl)amino-amphi-glyoxime and [L4H2] N-(4-phenylazophenyl)amino-anti-glyoxime have been prepared from amphi-chloroglyoxime, anti-chloroglyoxime, 4-butylaniline and 4-(phenylazo)aniline respectively. The complexes of these vic-dioximes with NiII, CoII, CuII and CdII ions have been investigated. All are insoluble in common solvents. Their i.r. spectra and elemental analyses are given, together with mass and 1H-n.m.r. spectra of the ligands. 相似文献
72.
Ucar Asuman Findik Mukerrem Kuzu Muslum Pehlivanoglu Suray Sayin Ulku Sayin Zafer Akgemci Emine Guler 《Research on Chemical Intermediates》2021,47(2):533-550
Research on Chemical Intermediates - Metal complexes of thiosemicarbazones have been receiving considerable attention in biological applications such as antimicrobial and anticancer therapies. In... 相似文献
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75.
Emine?Me?e Nurettin?Pirin??iog?lu Irfan?A??kg?z Figen?Binbay 《General Relativity and Gravitation》2009,41(1):87-92
In the post Newtonian limit, a non-relativistic Hamiltonian is derived for scalar fields with quartic self-interaction and
non-minimal coupling to the curvature scalar of the background spacetime. These effects are found to contribute to the non-relativistic
Hamiltonian by adding nonlinearities and by modifying the gravitational Darwin term. As we discuss briefly in the text, the
impact of these novel structures can be sizable in dense media like neutron star core, and can have observable signatures
in phase transitions, for example. 相似文献
76.
Bilge Taner Pervin Deveci Zafer Üstündaǧ Selda Keskin Emine Özcan Ali Osman Solak 《Surface and interface analysis : SIA》2012,44(2):185-191
3‐Aminophenylcalix[4]pyrrole (3APCP) was grafted to a glassy carbon (GC) surface during the electrochemical oxidation process in 0.1 M tetrabutylammoniumtetra‐fluoroborate (TBATFB) containing acetonitrile solution. The presence of a surface film was confirmed electrochemically by comparing voltammograms of dopamine and ferricyanide redox probes at the bare and modified electrodes. Reflection‐absorption infrared spectroscopy (RAIRS), XPS, atomic force microscopy (AFM), ellipsometry and the contact angle measurements were also employed to characterize 3APCP film on GC electrode. RAIRS analysis revealed that calix[4]pyrrole was bonded to the glassy carbon surface via the etheric linkage. The stability of the modified GC electrode was also studied. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
77.
Emine Salamci 《Tetrahedron》2010,66(23):4010-2897
A concise and efficient synthesis of cyclooctane-1,2,3,4-tetraoles, new polyhydroxylated eight-membered carbocycles, is described starting from cis,cis-1,3-cyclooctadiene. Cyclooctene endoperoxide obtained by photooxygenation of cis,cis-1,3-cyclooctadiene was the key compound in the synthesis. Reduction of the endoperoxide with zinc or thiourea followed by acetylation of the hydroxyl group and OsO4/NMO oxidation of the double bond gave (1R(S),2S(R),3R(S),4S(R))-cyclooctane-1,2,3,4-tetraol. Interestingly, epoxidation of cyclooctene-1,4-diol with m-CPBA also afforded trans-epoxy-diol 17. (1R(S),2R(S),3R(S),4S(R))-cyclooctane-1,2,3,4-tetraol was easily obtained by hydrolysis of epoxy-diol 17. 相似文献
78.
The host–guest complexation reactions between 5,11,17,23‐tetra‐tert‐butyl‐25,27‐diethoxycarbonylmethoxy‐26,28‐dimethoxy calix[4]arene (BDDC4) and alkali and alkaline‐earth metal ions were investigated by facilitated ion transfer processes across water/1,2‐dichloroethane microinterface by using steady‐state cyclic voltammetry and differential pulse voltammetry. The obtained facilitated transfers for Li+, Na+, K+, Rb+ and Ca2+ were evaluated under the different experimental conditions, at the excess concentrations of metal ions with respect to BDDC4 and vice versa. The association constants having 1 : 1 stoichiometry for Li+, Na+, K+ and Rb+ in 1,2‐DCE were determined. Also, we demonstrated that BDDC4 can play an important role for the development of highly selective chemical sensor for Ca2+ among alkaline‐metal ions in the concentration range of 0.1–1.0 mM in aqueous solution. 相似文献
79.
Gürbüz N Özcan EÖ Özdemir İ Çetinkaya B Şahin O Büyükgüngör O 《Dalton transactions (Cambridge, England : 2003)》2012,41(8):2330-2339
The reaction of [RuCl(2)(p-cymene](2) with Ag-N-heterocyclic carbene (NHC) complexes yields a series of [(p-cymene)Ru(NHC)] complexes (2a-f). All synthesised compounds were characterized by elemental analysis, NMR spectroscopy and the molecular structure of 2a was determined by X-ray crystallography. All complexes have been tested as catalysts for the transfer hydrogenation of aromatic ketones, showing excellent activity in this reaction. 相似文献
80.
Melis Ulu Dog?ru Neriman Varl?kl? Derya Baykal Güliz K?y Dog?ukan Ta?er Halife ?ag?lar Emine Gündüz 《International Journal of Theoretical Physics》2012,51(5):1545-1554
In this paper, we devote to investigate the energy-momentum problem of higher dimensional black holes in the general theory
of relativity. The energy and momentum complex of M?ller has been used for the calculations. Also, total energy and total
momentum of some special cases for higher dimensional black holes such as Schwarzschild-like black holes, Reissner-Nordstr?m-like
charged black holes, AdS-like black holes, topological black holes, BTZ-like and charged BTZ-like black holes were obtained.
It is invented that the momentum of black holes vanishes everywhere while the energy of black holes are not equal to zero
in higher dimension. Also the results agree with Yang and Radinschi or Vagenas results in three and four dimensional black
holes, respectively (Jang and Radinschi in AIP Conf. Proc. 895, 325, 2007; Vagenas in Mod. Phys. Lett. A 21, 1947, 2006). 相似文献