Preparation of a series of Ru(II) complexes with N-heterocyclic carbene ligands for the catalytic transfer hydrogenation of aromatic ketones

The reaction of [RuCl(2)(p-cymene](2) with Ag-N-heterocyclic carbene (NHC) complexes yields a series of [(p-cymene)Ru(NHC)] complexes (2a-f). All synthesised compounds were characterized by elemental analysis, NMR spectroscopy and the molecular structure of 2a was determined by X-ray crystallography. All complexes have been tested as catalysts for the transfer hydrogenation of aromatic ketones, showing excellent activity in this reaction.     

Energy and Momentum of Higher Dimensional Black Holes

In this paper, we devote to investigate the energy-momentum problem of higher dimensional black holes in the general theory of relativity. The energy and momentum complex of M?ller has been used for the calculations. Also, total energy and total momentum of some special cases for higher dimensional black holes such as Schwarzschild-like black holes, Reissner-Nordstr?m-like charged black holes, AdS-like black holes, topological black holes, BTZ-like and charged BTZ-like black holes were obtained. It is invented that the momentum of black holes vanishes everywhere while the energy of black holes are not equal to zero in higher dimension. Also the results agree with Yang and Radinschi or Vagenas results in three and four dimensional black holes, respectively (Jang and Radinschi in AIP Conf. Proc. 895, 325, 2007; Vagenas in Mod. Phys. Lett. A 21, 1947, 2006).     

Nonlinear Intersubband Transitions in Square and Graded Quantum Wells Modulated by Intense Laser Field

There has been increasing interest, both exper- imentally and theoretically, in the investigation of low-dimensional semiconductor heterostructures due to their intrinsic physical properties and technological applications in electronic and optoelectronic devices. The studies on quantum heterostructures have opened a new field in fundamental physics, and also offer a wide range of potential applications for optoelectronic devices. By varying the profile of a semiconductor quantum well （QW）, both the subband state energies and their wave functions change, and so do various physical properties depending on them.     

A Novel Synthesis of DL-proto-, and DL-vibo-Quercitol via 1, 4-Cyclohexadiene

Photooxygenation of 1, 4-cyclohexadiene 3 followed by reduction with LiAlH₄ or thiourea gave (25/1)-cyclohex-3-ene-triol 7a. trans-Hydroxylation of triol 7a with three different methods afforded both of proto-quercitol la and vibo-quercitol 2a.     

Synthesis,Characterization, and Biological Evaluation of Some Novel Thiosemicarbazones as Possible Antibacterial and Antioxidant Agents

Abstract

The synthesis and characterization of 18 novel thiosemicarbazones have been investigated as part of a research program on development of compounds with antibacterial and antioxidant activities. Among the tested compounds, 2-(4-hydroxybenzylidene)-N-[4-(trifluoromethoxy)phenyl]hydrazine carbothioamide (3g) and 2-(thiophen-2-ylmethylidene)-N-[4-(morpholin-4-yl)phenyl]hydrazine carbothioamide (4b) showed excellent inhibition potency at low concentration (0.5 μg/mL) against Gram-positive pathogens (Enterococcus faecalis and Staphylococcus aureus). All tested compounds were also found to possess antioxidant activity against 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical and 2,2’-azinobis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) radical cation.

[Supplementary materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements for the following free supplemental files: Additional text, tables, and figures.]     

Monte Carlo analyses of multiple backscattering of gamma rays

We have written a Monte Carlo code to simulate the experimental results of a previously reported study. We were able to analyse the energy distributions of photons that reached the detector system after suffering several successive Compton scatterings in the target. We have also investigated how the number of multiply backscattered events depends on the target thickness and the energy of the primary photons.     

Evaluation of Normalization Methods on GeLC-MS/MS Label-Free Spectral Counting Data to Correct for Variation during Proteomic Workflows

Normalization of spectral counts (SpCs) in label-free shotgun proteomic approaches is important to achieve reliable relative quantification. Three different SpC normalization methods, total spectral count (TSpC) normalization, normalized spectral abundance factor (NSAF) normalization, and normalization to selected proteins (NSP) were evaluated based on their ability to correct for day-to-day variation between gel-based sample preparation and chromatographic performance. Three spectral counting data sets obtained from the same biological conidia sample of the rice blast fungus Magnaporthe oryzae were analyzed by 1D gel and liquid chromatography-tandem mass spectrometry (GeLC-MS/MS). Equine myoglobin and chicken ovalbumin were spiked into the protein extracts prior to 1D-SDS- PAGE as internal protein standards for NSP. The correlation between SpCs of the same proteins across the different data sets was investigated. We report that TSpC normalization and NSAF normalization yielded almost ideal slopes of unity for normalized SpC versus average normalized SpC plots, while NSP did not afford effective corrections of the unnormalized data. Furthermore, when utilizing TSpC normalization prior to relative protein quantification, t-testing and fold-change revealed the cutoff limits for determining real biological change to be a function of the absolute number of SpCs. For instance, we observed the variance decreased as the number of SpCs increased, which resulted in a higher propensity for detecting statistically significant, yet artificial, change for highly abundant proteins. Thus, we suggest applying higher confidence level and lower fold-change cutoffs for proteins with higher SpCs, rather than using a single criterion for the entire data set. By choosing appropriate cutoff values to maintain a constant false positive rate across different protein levels (i.e., SpC levels), it is expected this will reduce the overall false negative rate, particularly for proteins with higher SpCs.     

Search for the doubly heavy baryons Ω0bc and Ξ0bc decaying to ∧+cπ-and Ξ+cπ-

The first search for the doubly heavy Ω0bc baryon and a search for the Ξ0bc baryon are performed using pp collision data collected via the LHCb experiment from ...     

Cytotoxic effects,microbiological analysis and inhibitory properties on carbonic anhydrase isozyme activities of 2-hydroxy-5-methoxyacetophenone thiosemicarbazone and its Cu(II), Co(II), Zn(II) and Mn(II) complexes

Research on Chemical Intermediates - Metal complexes of thiosemicarbazones have been receiving considerable attention in biological applications such as antimicrobial and anticancer therapies. In...     

On modeling with multiplicative differential equations

This work is aimed to show that various problems from different fields can be modeled more efficiently using multiplicative calculus, in place of Newtonian calculus. Since multiplicative calculus is still in its infancy, some effort is put to explain its basic principles such as exponential arithmetic, multiplicative calculus, and multiplicative differential equations. Examples from finance, actuarial science, economics, and social sciences are presented with solutions using multiplicative calculus concepts. Based on the encouraging results obtained it is recommended that further research into this field be vested to exploit the applicability of multiplicative calculus in different fields as well as the development of multiplicative calculus concepts.