全文获取类型
收费全文 | 1331篇 |
免费 | 50篇 |
国内免费 | 9篇 |
专业分类
化学 | 888篇 |
晶体学 | 6篇 |
力学 | 37篇 |
数学 | 275篇 |
物理学 | 184篇 |
出版年
2023年 | 7篇 |
2022年 | 23篇 |
2021年 | 29篇 |
2020年 | 32篇 |
2019年 | 26篇 |
2018年 | 19篇 |
2017年 | 14篇 |
2016年 | 54篇 |
2015年 | 29篇 |
2014年 | 46篇 |
2013年 | 74篇 |
2012年 | 97篇 |
2011年 | 98篇 |
2010年 | 66篇 |
2009年 | 39篇 |
2008年 | 86篇 |
2007年 | 65篇 |
2006年 | 59篇 |
2005年 | 63篇 |
2004年 | 64篇 |
2003年 | 43篇 |
2002年 | 54篇 |
2001年 | 19篇 |
2000年 | 15篇 |
1999年 | 13篇 |
1998年 | 15篇 |
1997年 | 18篇 |
1996年 | 16篇 |
1995年 | 13篇 |
1994年 | 9篇 |
1993年 | 8篇 |
1992年 | 9篇 |
1991年 | 8篇 |
1990年 | 9篇 |
1989年 | 5篇 |
1988年 | 8篇 |
1987年 | 6篇 |
1986年 | 21篇 |
1985年 | 14篇 |
1984年 | 11篇 |
1983年 | 7篇 |
1982年 | 5篇 |
1981年 | 5篇 |
1980年 | 8篇 |
1979年 | 6篇 |
1977年 | 4篇 |
1974年 | 3篇 |
1971年 | 7篇 |
1967年 | 5篇 |
1870年 | 2篇 |
排序方式: 共有1390条查询结果,搜索用时 15 毫秒
81.
Investigation of anthropic effects connected with metal ions concentration, organic matter and grain size in Bormida river sediments 总被引:9,自引:0,他引:9
Emilio Marengo Maria Carla Gennaro Elisa Robotti Piero Rossanigo Caterina Rinaudo Manuela Roz-Gastaldi 《Analytica chimica acta》2006,560(1-2):172-183
An investigation on the sediment composition and grain size was carried out along the Bormida river (Piedmont, Northern Italy). The samples were taken both in the riverbed and on its banks. Multivariate statistical exploratory methods permitted to identify possible sources of primary pollution. In particular, principal component analysis (PCA) showed that there are probably at least three anthropogenic main causes of pollution, one connected with Cr, Ni and Sn, the second with cadmium and the last one with mercury. Some correlations were found between heavy metal ion concentrations and organic matter and/or the sediment grain size. Differences between the samples collected in the riverbed and on the banks were identified and the relationships between the principal components and the distance of the samples from the riverbed and from the hot spot represented by the ACNA industrial site were also analyzed. 相似文献
82.
Alberto de Juan Dr. Yann Pouillon Dr. Luisa Ruiz‐González Dr. Almudena Torres‐Pardo Dr. Santiago Casado Prof. Dr. Nazario Martín Prof. Dr. Ángel Rubio Dr. Emilio M. Pérez 《Angewandte Chemie (International ed. in English)》2014,53(21):5394-5400
Extensive research has been devoted to the chemical manipulation of carbon nanotubes. The attachment of molecular fragments through covalent‐bond formation produces kinetically stable products, but implies the saturation of some of the C? C double bonds of the nanotubes. Supramolecular modification maintains the structure of the SWNTs but yields labile species. Herein, we present a strategy for the synthesis of mechanically interlocked derivatives of SWNTs (MINTs). In the key rotaxane‐forming step, we employed macrocycle precursors equipped with two π‐extended tetrathiafulvalene SWNT recognition units and terminated with bisalkenes that were closed around the nanotubes through ring‐closing metathesis (RCM). The mechanically interlocked nature of the derivatives was probed by analytical, spectroscopic, and microscopic techniques, as well as by appropriate control experiments. Individual macrocycles were observed by HR STEM to circumscribe the nanotubes. 相似文献
83.
Karina González‐Segura Paulina Cañete‐Rosales Rodrigo del Rio Claudia Yáñez Nancy F. Ferreyra Gustavo A. Rivas Soledad Bollo 《Electroanalysis》2012,24(12):2317-2323
The electrochemical response of a glassy carbon electrode modified with carbon nanotubes (CNT) dispersed in two solvents, water and DMF, and two polymers, chitosan and Nafion is reported. The films were homogeneous when the dispersing agent was water or DMF. In the case of polymers, the surfaces present areas with different density of CNTs. A more sensitive electrochemical response was obtained when CNTs are dispersed in the solvents. In the case of CNT dispersed with polymers, the nature of the polymer demonstrated to be a critical parameter not only for dispersing the nanotubes but also for the electrochemical activity of the resulting electrodes. 相似文献
84.
Germán Bianchini Mónica Denham Ana Cortés Tomàs Margalef Emilio Luque 《Journal of computational science》2010,1(4):229-237
Several Data-Driven Methods have been developed to try to solve the input parameters uncertainty when considering problems like Wildfires Prediction. In general, these methods operate over a large number of input parameters, and consider the most recent known behavior of wildfires. The purpose of the methods is to find the parameter set that best describes the real situation under consideration. Therefore, it is presumed that the same set of values could be used to predict the immediate future.However, because this kind of prediction is based on a single set of parameters, for those parameters that present a dynamic behavior (e.g. wind direction and speed), the new optimized values are not adequate to make a prediction.In this paper we propose an alternative method developed in a new branch of Data-Driven Prediction, which we called Multiple Overlapping Solution. This method combines statistical concepts and HPC (High Performance Computing) to obtain a higher quality prediction. 相似文献
85.
86.
Abderrahim Jourani Emilio Vilches 《Journal of Optimization Theory and Applications》2017,173(1):91-116
The existence and the convergence (up to a subsequence) of the Moreau-Yosida regularization for the state-dependent sweeping process with nonregular (subsmooth and positively alpha-far) sets are established. Then, by a reparametrization technique, the existence of solutions for bounded variation continuous state-dependent sweeping processes with nonregular (subsmooth and positively alpha-far) sets is proved. An application to vector hysteresis is discussed, where it is shown that the Play operator with positively alpha-far sets is well defined for bounded variation continuous inputs. 相似文献
87.
88.
Freezing the Dynamic Gap for Selectivity: Motion‐Based Design of Inhibitors of the Shikimate Kinase Enzyme 下载免费PDF全文
Verónica Prado Dr. Emilio Lence Paul Thompson Prof. Alastair R. Hawkins Prof. Concepción González‐Bello 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(50):17988-18000
Shikimate kinase (SK), the fifth enzyme of the aromatic amino acid biosynthesis, is a recognized target for antibiotic drug discovery. The potential of the distinct dynamic apolar gap, which isolates the natural substrate from the solvent environment for catalysis, and the motion of Mycobacterium tuberculosis and Helicobacter pylori SK enzymes, which was observed by molecular dynamics simulations, was explored for inhibition selectivity. The results of the biochemical and computational studies reveal that the incorporation of bulky groups at position C5 of 5‐aminoshikimic acid and the natural substrate enhances the selectivity for the H. pylori enzyme due to key motion differences in the shikimic acid binding domain (mainly helix α5). These studies show that the less‐exploited motion‐based design approach not only is an alternative strategy for the development of competitive inhibitors, but could also be a way to achieve selectivity against a particular enzyme among its homologues. 相似文献
89.
Miscible blends of poly(ethylene oxide) with brush copolymers of poly(vinyl alcohol)‐graft‐poly(l‐lactide) 下载免费PDF全文
Ainhoa Lejardi Jose‐Ramon Sarasua Agustin Etxeberria Emilio Meaurio 《Journal of Polymer Science.Polymer Physics》2016,54(13):1217-1226
Even though poly(ethylene oxide) (PEO) is immiscible with both poly(l ‐lactide) (PLLA) and poly(vinyl alcohol) (PVA), this article shows a working route to obtain miscible blends based on these polymers. The miscibility of these polymers has been analyzed using the solubility parameter approach to choose the proper ratios of the constituents of the blend. Then, PVA has been grafted with l ‐lactide (LLA) through ring‐opening polymerization to obtain a poly(vinyl alcohol)‐graft‐poly(l ‐lactide) (PVA‐g‐PLLA) brush copolymer with 82 mol % LLA according to 1H and 13C NMR spectroscopies. PEO has been blended with the PVA‐g‐PLLA brush copolymer and the miscibility of the system has been analyzed by DSC, FTIR, OM, and SEM. The particular architecture of the blends results in DSC traces lacking clearly distinguishable glass transitions that have been explained considering self‐concentration effects (Lodge and McLeish) and the associated concentration fluctuations. Fortunately, the FTIR analysis is conclusive regarding the miscibility and the specific interactions in these systems. Melting point depression analysis suggests that interactions of intermediate strength and PLOM and SEM reveal homogeneous morphologies for the PEO/PVA‐g‐PLLA blends. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1217–1226 相似文献
90.
Teresa Bermúdez Antonio Martinón Emilio Negrín 《Integral Equations and Operator Theory》2010,68(3):301-312
We give a characterization of m-isometric operators on a separable Hilbert space. Moreover, we characterize the unilateral weighted shift operators which
are m-isometries. 相似文献