Studies on terbium activated yttrium based tantalate phosphors

Terbium activated yttrium niobium tantalate phosphors were prepared by solid-state reaction and were characterized by photoluminescence measurements, X-ray diffraction and scanning electron microscopy. Photoluminescence (PL) of Y_0.95Tb_0.05Ta_1?xNb_xO₄ phosphors (x = 0–1) are influenced by the host-lattice composition, degree of crystalline order and particle morphology and size. The effect of the morpho-structural properties on PL characteristics of Y(Ta,Nb)O₄:Tb powders is reported.     

Muonium adduct radicals from vinyl-aromatic compounds

During irradiation of liquid samples of 1-vinylimidazole, 2-vinylnaphthalene, 2-vinylpyridine, 4-vinylpyridine and 1,1-diphenylethene with positive muons, radicals of the type MuCH₂ĊHAr (Ar=the appropriate aromatic group), and the MuCH₂ĊPh₂ radical were observed by transverse field μSR; the muon hyperfine couplings are considered in the context of the effectiveness of the aryl groups in delocalising the unpaired electron.     

Quantum well shape modification using vacancy generation and rapid thermal annealing

The effect of rapid thermal annealing (RTA) on the shapes of GaAs/AlGaAs quantum wells (QWs) has been investigated by monitoring exciton energies using low temperature photoluminescence and photoluminescence excitation spectroscopies. After RTA, large changes in exciton energies were observed only in regions of the samples in which excess surface vacancies were generated, either by capping with a thin layer of SiO₂ or by low-energy ion implantation. These changes were interpreted as resulting from modifications of the shapes of the as-grown QWs from abrupt or square to gradual (rounded) due to enhanced interdiffusion of well/barrier atoms. For single QWs there was an increase in exciton energy whose magnitude depended on the width of the well, its distance from the surface of the wafer, the annealing temperature and the total number of surface vacancies available. From studies of coupled QWs, there was clear evidence of asymmetry in the heterostructure after RTA. Although both techniques of vacancy generation yield substantial QW shape modifications, the ion implantation technique has the advantages of being highly reproducible and of being compatible with any material system.     

μSR Investigation of ethyl radicals adsorbed on silica

SR spectra of the ethyl radical adsorbed on porous silica were observed in transverse and in longitudinal magnetic fields in the temperature range 190–298 K. The line widths reflect the dynamic partial averaging of the hyperfine anisotropy due to reorientation and surface diffusion.     

Effects of coherence on the degree of polarization in a young interference pattern

Recent predictions concerning the relationship between the degree of polarization at a typical point of a Young interference pattern and the degree of coherence of the electromagnetic field at the pinholes are tested by a simple experiment. In particular, it is shown that light that is completely unpolarized at the pinholes can become partially polarized across the fringe pattern.     

Interference law for coherent stochastic electromagnetic beams

Two-beam interference law for the superposition of stochastic, spatially coherent, electromagnetic beams is derived. Only a single phase is found to enter the interference law, in spite of the vector nature of the problem. The meaning of the phase is elucidated.     

Influence of (phospho)lipases on properties of mica supported phospholipid layers

The effect of enzymes: lipase from Candida cylindracea (L_Cc), phospholipase A₂ from hog pancreas (PLA₂) and phospholipase C from Bacillus cereus (PLC) to modulate wetting properties of solid supported phospholipid bilayers was studied via advancing and receding contact angle measurements of water, formamide and diiodomethane, and calculation of the surface free energy and its components from van Oss et al. (LWAB) and contact angle hysteresis (CAH) approaches. Simultaneously, topography of the studied layers was determined by Atomic Force Microscopy (AFM). The investigated lipid bilayers were transferred on mica plates from subphase of pure water by means of Langmuir-Blodgett and Langmuir-Schaefer techniques. The investigated phospolipid layers were: saturated DPPC (1,2-dipalmitoyl-sn-glycero-3-phosphocholine), unsaturated DOPC (1,2-dioleoyl-sn-glycero-3-phosphocholine), and their mixture DPPC/DOPC. The obtained results revealed that the lipid membrane degradation by the enzymes caused increase in its surface free energy due to the amphiphilic hydrolysis products, which may accumulate in the lipid bilayer. In result activity of the enzymes may increase and then break down the bilayer structure takes place. It is likely that after dissolution of the hydrolysis reaction products in the bulk phase, patches of bare mica surface are accessible, which contribute to the apparent surface free energy changes. Comparison of AFM images and the free energy changes of the layers gives better insight into changes of their properties. The observed gradual increase in the layer surface free energy allows controlling of the hydrolysis process to obtain the surfaces of defined properties.     

Directionality of Gaussian Schell-model beams propagating in atmospheric turbulence

It is known that some partially coherent Gaussian Shell-model beams may generate, in free space, the same angular distribution of radiant intensity as a fully coherent laser beam. We show that this result also holds even if the beams propagate in atmospheric turbulence, irrespective of the particular model of turbulence used. The result is illustrated by an example.     

Effects of spatial coherence on near-field spectra

Expressions are derived for the spectrum of the field generated by a planar, homogeneous, secondary source of any spectral distribution and of any state of spatial coherence. It is shown that the state of coherence affects the contributions of the homogeneous as well as the evanescent waves of the emitted field. The near-field spectra are studied in detail. The analysis is illustrated by examples.     

Spatial coherence properties of monochromatic electromagnetic beams and of laser modes

It is shown that, contrary to common belief, monochromatic light beams are, in general, not spatially completely coherent, i.e., they will, in general, not produce fringes of unit visibility in a Young's double pinhole interference experiment. We cite experiments with laser modes which confirm this result.