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101.
The paper considers various aspects of statistical quality control by means of sample data received on a ternary ordinal scale. A new method for evaluating quality level and dispersion, free of any latent numerical scale assumptions, is proposed. The emphasis is on working with large samples, which enable the statistical analysis, estimation and control by the use of approximate analytical expressions of these measures to be considerably simplified. Two complementary studies demonstrate the usage of the proposed approach. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
102.
Emil Wolf 《Optics Communications》2011,284(22):5240-5241
Two-beam interference law for the superposition of stochastic, spatially coherent, electromagnetic beams is derived. Only a single phase is found to enter the interference law, in spite of the vector nature of the problem. The meaning of the phase is elucidated. 相似文献
103.
The present work analyses computationally the flow inside wire enameling dies within the framework of the lubrication theory approximation. Non-Newtonian flow behavior and heat transfer are accounted for as well. It is shown that the developed approach most accurately predicts the momentum and heat fluxes along the wire. As such it is proven as a reliable and computationally efficient tool for the design of flow optimized die shapes. (© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
104.
Nitroxide‐mediated polymerization was used as a model system for preparing styrenic monolithic materials with significant mesopore contents in different mold formats, with the aim of assessing the validity of pore characterization of capillary monoliths by analysis of parallel bulk polymerized precursor solution. Capillary monoliths were prepared in 250 μm id fused silica tubes (quadruplicate samples, in total 17 m), and the batch polymerizations were carried out in parallel in 100 μL microvials and regular 2 mL glass vials, both in quintuplicate. The monoliths recovered from the molds were characterized for their meso‐ and macroporous properties by nitrogen sorptiometry (three repeated runs on each sample), followed by a single analysis by mercury intrusion porosimetry. A total of 14 monolith samples were thus analyzed. A Grubbs' test identified one regular vial sample as an outlier in the sorptiometric surface area measurements, and data from this sample were consequently excluded from the pore size calculations, which are based on the same nitrogen sorption data, and also from the mercury intrusion data set. The remaining data were subjected to single factor analyses of variance analyses to test if the porous properties of the capillary monoliths were different from those of the bulk monoliths prepared in parallel. Significant differences were found between all three formats both in their meso‐ and macroporous properties. When the dimension was shrunk from conventional vial to capillary size, the specific surface area decreased from 52.2±4.7 to 34.6±1.7 m2/g. This decrease in specific surface area was accompanied by a significant shift in median diameter of the through‐pores, from 310±3.9 to 544±13 nm. None of these differences were obvious from the scanning electron micrographs that were acquired for each sample type. The common practice of determining the mesopore characteristics from analysis of samples prepared by parallel bulk polymerization and looking for changes in the macropore structure by visual assessment of SEMs are therefore both rather questionable, at least for monoliths of the kind used in this study. 相似文献
105.
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107.
Some results of the extraction of strontium and yttrium from soil samples by concentrated nitric acid are described. The concentration of Sr and Y in the solid was determined by XRF method. The results obtained allowed to elaborate the conditions of acid leaching and to propose an analytical procedure for the determination of 90Sr in samples without their total dissolution. 相似文献
108.
Emil Byström Anna Nordborg Fredrik Limé Ngoc Phuoc Dinh Knut Irgum 《Journal of separation science》2010,33(11):1563-1570
A combined surface activation and “grafting to” strategy was developed to convert divinylbenzene particles into weak cation exchangers suitable for protein separation. The initial activation step was based on plasma modification with bromoform, which rendered the particles amenable to further reaction with nucleophiles by introducing Br to a surface content of 11.2 atom‐%, as determined by X‐ray photoelectron spectroscopy. Grafting of thiol‐terminated glydicyl methacrylate telomers to freshly plasma activated surfaces was accomplished without the use of added initiator, and the grafting was verified both by reduction in bromine content and the appearance of sulfur‐carbon linkages, showing that the surface grafts were covalently bonded. Following grafting the attached glydicyl methacrylate telomer tentacles were further modified by a two‐step procedure involving hydrolysis to 2,3‐hydroxypropyl groups and conversion of hydroxyl groups to carboxylate functionality by succinic anhydride. The final material was capable of baseline separating four model proteins in 3 min by gradient cation exchange chromatography in a fully aqueous eluent. 相似文献
109.
Emil Manev Roumen Tsekov Boryan Radoev 《Journal of Dispersion Science and Technology》2013,34(6-7):769-788
The effect of thickness non-homogeneity on the drainage of microscopic horizontal foam films was studied experimentally and theoretically. Quasi-static and asymmetrical distribution of thickness irregularities over the film surface was established in the experiment. This type of dimpling was modelled theoretically and employed to derive a new equation for the film thinning. It differs from the theoretical expressions known from the literature and is in better agreement with the experimentally determined functional dependence of thinning rate on film size. 相似文献
110.