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Emil C. Buruiana Tinca Buruiana Georgeta Strat Mitachi Strat 《Journal of polymer science. Part A, Polymer chemistry》2005,43(17):3945-3956
Hydrophilic ionic polyurethanes with 4‐chloromethylphenylcarbamoyl‐1‐oxymethylpyrene located on the quaternary ammonium structure from a polymer based on poly(ethylene glycol), isophorone diisocyanate, and N‐methyldiethanolamine were prepared by a quaternization reaction, in which the amount of pyrene covalently attached to the polymeric backbone ranged from 1.14 to 19.82 mmol of fluorophore/100 g of polymer. It was interesting to compare the photoluminescence of the pyrene polyurethane carrying a few mole percent of pyrene moieties with that of a third polymer resulting from its subsequent quaternization with benzyl chloride up to a concentration of ionic groups as in the latter (quaternization degree = 14.15%). The process of excimer formation between the pyrene molecules attached to the ionic polyurethane was investigated in tetrahydrofuran (THF), dimethylformamide, film, and THF/H2O to illustrate the expected differences in the polymer behavior compared with that of the starting pyrene derivative. The formation of aggregates or core–shell micelles was sustained by the fluorescence data, which indicated the existence of pyrene units in the ground state of the molecule, giving rise thus to an explanation for the high excimer‐to‐monomer intensity ratio. The fluorescence decay of pyrene polyurethanes in the presence of various concentrations of nitrobenzene used as a quencher was analyzed too when the fluorescence quenching in the polymer solution normally followed Stern–Volmer kinetics. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 3945–3956, 2005 相似文献
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Dynamics of Fluorescent Dyes Attached to G‐Quadruplex DNA and their Effect on FRET Experiments
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Siri Søndergaard Dr. Mikayel Aznauryan Emil K. Haustrup Prof. Birgit Schiøtt Prof. Victoria Birkedal Prof. Ben Corry 《Chemphyschem》2015,16(12):2562-2570
FRET spectroscopy is a promising approach for investigating the dynamics of G‐quadruplex DNA folds and improving the targeting of G‐quadruplexes by potential anticancer compounds. To better interpret such experiments, classical and replica‐exchange molecular dynamics simulations and fluorescence‐lifetime measurements are used to understand the behavior of a range of Cy3‐based dyes attached to the 3′ end of G‐quadruplex DNA. The simulations revealed that the dyes interact extensively with the G‐quadruplex. Identification of preferred dye positions relative to the G‐quadruplex in the simulations allows the impact of dye–DNA interactions on FRET results to be determined. All the dyes show significant deviations from the common approximation of being freely rotating and not interacting with the host, but one of the Cy3 dye analogues is slightly closer to this case. 相似文献
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Regioselective Synthesis of Polyheterohalogenated Naphthalenes via the Benzannulation of Haloalkynes
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Dr. Dan Lehnherr Joaquin M. Alzola Dr. Emil B. Lobkovsky Prof. Dr. William R. Dichtel 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(50):18122-18127
Independent control of halide substitution at six of the seven naphthalene positions of 2‐arylnaphthalenes is achieved through the regioselective benzannulation of chloro‐, bromo‐, and iodoalkynes. The modularity of this approach is demonstrated through the preparation of 44 polyheterohalogenated naphthalene products, most of which are difficult to access through known naphthalene syntheses. The outstanding regioselectivity of the reaction is both predictable and proven unambiguously by single‐crystal X‐ray diffraction for many examples. This synthetic method enables the rapid preparation of complex aromatic systems poised for further derivatization using established cross‐coupling methods. The power and versatility of this approach makes substituted naphthalenes highly attractive building blocks for new organic materials and diversity‐oriented synthesis. 相似文献