首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   684篇
  免费   26篇
  国内免费   3篇
化学   437篇
力学   13篇
数学   120篇
物理学   143篇
  2023年   11篇
  2022年   18篇
  2021年   32篇
  2020年   11篇
  2019年   16篇
  2018年   26篇
  2017年   9篇
  2016年   38篇
  2015年   22篇
  2014年   29篇
  2013年   47篇
  2012年   50篇
  2011年   46篇
  2010年   33篇
  2009年   29篇
  2008年   47篇
  2007年   40篇
  2006年   32篇
  2005年   22篇
  2004年   28篇
  2003年   30篇
  2002年   17篇
  2001年   7篇
  2000年   8篇
  1999年   5篇
  1998年   4篇
  1997年   6篇
  1996年   4篇
  1994年   2篇
  1993年   2篇
  1992年   4篇
  1990年   3篇
  1989年   1篇
  1988年   2篇
  1986年   5篇
  1985年   3篇
  1984年   5篇
  1983年   1篇
  1981年   4篇
  1980年   1篇
  1979年   1篇
  1975年   1篇
  1973年   1篇
  1971年   1篇
  1968年   1篇
  1960年   1篇
  1948年   1篇
  1943年   2篇
  1935年   1篇
  1873年   1篇
排序方式: 共有713条查询结果,搜索用时 46 毫秒
61.
We investigate the degradation path of MAPbI3 (MA=methylammonium) films over flat TiO2 substrates at room temperature by means of X‐ray diffraction, spectroscopic ellipsometry, X‐ray photoelectron spectroscopy, and high‐resolution transmission electron microscopy. The degradation dynamics is found to be similar in air and under vacuum conditions, which leads to the conclusion that the occurrence of intrinsic thermodynamic mechanisms is not necessarily linked to humidity. The process has an early stage, which drives the starting tetragonal lattice in the direction of a cubic atomic arrangement. This early stage is followed by a phase change towards PbI2. We describe how this degradation product is structurally coupled with the original MAPbI3 lattice through the orientation of its constituent PbI6 octahedra. Our results suggest a slight octahedral rearrangement after volatilization of HI+CH3NH2 or MAI, with a relatively low energy cost. Our experiments also clarify why reducing the interfaces and internal defects in the perovskite lattice enhances the stability of the material.  相似文献   
62.
The aim of this work was to develop a new method to determine the mercury (Hg) concentrations in phosphate rock using a dedicated analytical instrument (the DMA80 Tricell by Milestone) that employs an integrated sequence of thermal decomposition followed by catalyst conversion, amalgamation and atomic absorption spectrophotometry. However, this instrument underestimates Hg concentrations when phosphorite and apatite rocks are investigated with a classic thermal decomposition treatment that complies with US EPA method 7473.  相似文献   
63.
In this work, the capabilities of solid phase microextraction were exploited in a fully optimized SPME-GC-QqQ-MS analytical approach for hydrazine assay. A rapid and easy method was obtained by a simple derivatization reaction with propyl chloroformate and pyridine carried out directly in water samples, followed by automated SPME analysis in the same vial without further sample handling. The affinity of the different derivatized compounds obtained towards five commercially available SPME coatings was evaluated, in order to achieve the best extraction efficiency. GC analyses were carried out using a GC-QqQ-MS instrument in selected reaction monitoring (SRM) acquisition mode which has allowed the achievement of high specificity by selecting appropriate precursor–product ion couples improving the capability in analyte identification. The multivariate approach of experimental design was crucial in order to optimize derivatization reaction, SPME process and tandem mass spectrometry parameters. Accuracy of the proposed protocol, tested at 60, 200 and 800 ng L−1, provided satisfactory values (114.2%, 83.6% and 98.6%, respectively), whereas precision (RSD%) at the same concentration levels were of 10.9%, 7.9% and 7.7% respectively. Limit of detection and quantification of 4.4 and 8.3 ng L−1 were obtained. The reliable application of the proposed protocol to real drinking water samples confirmed its capability to be used as analytical tool for routine analyses.  相似文献   
64.
An interesting and surprising rearrangement was observed during the reaction of 4-N-benzyl piperazinone derivatives with Lawesson’s reagent as a thionating agent. Investigation into the possible mechanism responsible for these results is reported herein.  相似文献   
65.
A fast analytical method has been developed for the determination of nine amino acids, together with serotonin, in wine samples of different origin and vintage. The method is based on capillary electrophoresis coupled to laser-induced fluorescence detection. Separation was obtained by using a fused-silica capillary (75?μm id, 74.0?cm total length, 60.0?cm length to detector) and a background electrolyte composed of carbonate buffer (20?mM, pH 9.2), applying a 20?kV voltage. Direct hydrodynamic injection of wine samples was made after an original microwave-assisted derivatisation step with 5-(4,6-dichlorotriazinyl)aminofluorescein. Fluorescence was induced by an Ar-Ion laser, exciting at 488?nm. Good linearity (r(2) >0.9990) was obtained for all considered analytes and sensitivity was also good, with limits of detection in the 7-50?ng/mL range. The method was successfully applied for the analysis of commercial Italian wines and thus seems to be suitable for the determination of the relevant amino acids and serotonin, providing good results in terms of accuracy and precision, together with the advantage of a very fast, microwave-assisted derivatisation procedure. Future applications of the method are planned to check for wine adulterations and commercial frauds.  相似文献   
66.
The esterification reaction between carboxylic acids and alcohols has been used as the source of water for the hydrolysis-condensation reactions of difunctional and trifunctional organosilanes. Diphenylsilanediol (DPDO) has been reacted with methacryloxypropyltrimethoxysilane (MPTMS) and glycidoxypropyltrimethoxysilane (GPTMS) and the obtained products have been characterized by vibrational spectroscopy (FT-IR, FT-Raman) nuclear magnetic resonance (NMR) and gel permeation chromatography. The relation between water availability from the in situ water production process (ISWP) and silsesquioxanes morphology has been evaluated in the case of DPDO/MPTMS mixtures, changing molecular features of acids and alcohols. These measurements have shown that the pK of the carboxylic acid used in the esterification reaction has a valuable influence on the silanes cross-linking ability. Acids with low pK values and heteroatoms substituents favor the silane hydrolysis and allow the growth of high molecular weight species. Using acetic acid/ethanol mixture leads to the best results for DPDO/MPTMS reaction, with a narrow distribution of silsesquioxane species. Under the same conditions, the reaction of DPDO with GPTMS produces polymeric species and only avoiding the presence of the difunctional precursor allows to limiting the silsesquioxanes species growth.  相似文献   
67.
The stabilizing action of C(α)-tetrasubstituted α-amino acids inserted into a sequence of short peptides allowed for the first time the preparation of water-soluble nanoparticles of different materials coated with a helix-structured undecapeptide. This peptide coating strongly favors nanoparticle uptake by human immune system cells.  相似文献   
68.
Langmuir-Schaefer (LS) films of copper(II) tetrakis-(isoprpoxy-carbonyl)-phthalocyanine (TiPCuPc) have been deposited onto various solid supports. Its floating film have been characterized at the air-water interface by means of Brewster Angle Microscopy and Langmuir curves. Vibrational modes of multilayer transferred LS film have been studied by Raman spectroscopy and the optical parameters (refractive index n and extinction coefficient k) have been determined in the visible range of the electromagnetic spectrum. Linearly polarized light absorbance measurements have been performed at room temperature in the 400-800 nm spectral range and the average orientation of the phthalocyanine rings have been estimated. Transmission electron microscopy has been also used to characterize the morphological properties of the LS film and a close packed arrangement of the deposited molecules has been observed.  相似文献   
69.
The morphology of water ice in the interstellar medium is still an open question. Although accretion of gaseous water could not be the only possible origin of the observed icy mantles covering dust grains in cold molecular clouds, it is well known that water accreted from the gas phase on surfaces kept at 10 K forms ice films that exhibit a very high porosity. It is also known that in the dark clouds H(2) formation occurs on the icy surface of dust grains and that part of the energy (4.48 eV) released when adsorbed atoms react to form H(2) is deposited in the ice. The experimental study described in the present work focuses on how relevant changes of the ice morphology result from atomic hydrogen exposure and subsequent recombination. Using the temperature-programmed desorption (TPD) technique and a method of inversion analysis of TPD spectra, we show that there is an exponential decrease in the porosity of the amorphous water ice sample following D-atom irradiation. This decrease is inversely proportional to the thickness of the ice and has a value of ?(0) = 2 × 10(16) D-atoms cm(-2) per layer of H(2)O. We also use a model which confirms that the binding sites on the porous ice are destroyed regardless of their energy depth, and that the reduction of the porosity corresponds in fact to a reduction of the effective area. This reduction appears to be compatible with the fraction of D(2) formation energy transferred to the porous ice network. Under interstellar conditions, this effect is likely to be efficient and, together with other compaction processes, provides a good argument to believe that interstellar ice is amorphous and non-porous.  相似文献   
70.
Dry and hydrated poly(vinyl alcohol) (PVA) gels with 55% (a‐PVA) and 61% (s‐PVA) syndiotacticity and related PVA/lactyl chitosan (LC) blends have been investigated with 129Xe and cross‐polarization/magic‐angle‐spinning 13C NMR techniques. Although the dry gels exhibit two broad 129Xe resonances in the slow‐to‐intermediate exchange limit, both hydrated gels show three resonances. The corresponding dry blends exhibit two signals, the chemical shifts and line widths of which change with respect to those of pure PVA, whereas one (a‐PVA/LC) or two (s‐PVA/LC) signals appear in the spectra of the hydrated blends. A comparative analysis of the data demonstrates that LC rearranges the domains of the polymeric matrix in both the dry and hydrated blends according to the syndiotacticity of the PVA chains. Information on the molecular motions of the amorphous and swollen polymeric domains in the kilohertz range has been obtained from an analysis of the spin‐lattice relaxation times. These data indicate that the dynamics and arrangement of the PVA chains in the gels are strongly affected by their tacticity and the addition of the copolymer LC. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3123–3131, 2003  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号