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51.
Classic Briggs-Rauscher oscillators use malonic acid (MA) as a substrate. The first organic product is iodomalonic acid. Iodomalonic acid (IMA) can serve as a substrate also; thus, the first product in that case is diiodomalonic acid (I(2)MA). Nonoscillating iodination kinetics can be followed by absorbance at 462 nm in acidic KIO(3) so long as IMA is in substantial excess over [I(2)]. At 25 °C, simulations lead to the two most important rate laws, and related rate constant estimates are reported. I(2)MA eventually decomposes by unknown processes, but I(2), O(2), H(2)O(2), and Mn(2+) speed up that decomposition, liberating most of the iodine back to the solution. Resorcinol is an effective inhibitor of oscillations both in MA oscillators and in IMA oscillators. Response of an IMA oscillator to varying amounts of resorcinol is shown herein and is similar to that for MA-based oscillators. The inhibitory effect of resorcinol is diminished by addition of IMA to a MA-based oscillator. The iodination reaction between IMA and resorcinol is too slow (0.043 M(-1) s(-1)) to account for the decreased inhibitory effectiveness of resorcinol. Rather, the decomposition of I(2)MA is responsible for the inhibition decrease. 相似文献
52.
We study the coupling of massive scalar fields to matter in orbit around rotating black holes. It is generally expected that orbiting bodies will lose energy in gravitational waves, slowly inspiraling into the black hole. Instead, we show that the coupling of the field to matter leads to a surprising effect: because of superradiance, matter can hover into "floating orbits" for which the net gravitational energy loss at infinity is entirely provided by the black hole's rotational energy. Orbiting bodies remain floating until they extract sufficient angular momentum from the black hole, or until perturbations or nonlinear effects disrupt the orbit. For slowly rotating and nonrotating black holes floating orbits are unlikely to exist, but resonances at orbital frequencies corresponding to quasibound states of the scalar field can speed up the inspiral, so that the orbiting body sinks. These effects could be a smoking gun of deviations from general relativity. 相似文献
53.
França EJ Andrade CG Furlaneto-Maia L Serpa R Oliveira MT Quesada RM Furlaneto MC 《Micron (Oxford, England : 1993)》2011,42(7):726-732
Candida tropicalis has been identified as one of the most prevalent pathogenic yeast species of the Candida-non-albicans (CNA) group. Study of switching in C. tropicalis has not been the subject of extensive research. Therefore, we investigated switching event and characterized the ultrastructural architecture of different phenotypes and biofilm produced in a C. tropicalis clinical strain. Cells switched heritably, reversibly, and at a high frequency between four phenotypes readily distinguishable by the shape of colonies formed on agar at 25°C. SEM analysis was used to verify the architecture of whole Candida colonies at ultrastructural level. The smooth phenotype (parental phenotype) colony showed a hemispherical shape character, while the semi-smooth was characterized by the presence of shallow marginal depressions. The ring and rough phenotypes exhibited more complex architecture and were characterized by the presence of deep central and peripheral depressions areas. The biofilm-forming ability varied among the switch phenotypes. After 12h incubation, the smooth phenotype formed less biofilm compared to the other phenotypes (P<0.05). The electron microscopy analysis revealed that filamentation (pseudohyphae) was associated with ring and rough colonies. The ultrastructural analysis allowed the observation of the arrangement of individual cells within the colonies. At the deep central and peripheral depressions areas of the ring and rough colonies extracellular material was seen in different arrangements. The data presented here open new avenues to study a possible role for extracellular material in the formation and maintenance of the architecture of switch phenotypes in C. tropicalis. It is therefore essential that more strains be investigated to determine the biological significance of extracellular material in C. tropicalis phenotypic switching phenomenon. 相似文献
54.
In this paper we study the reverse mathematics of two theorems by Bonnet about partial orders. These results concern the structure and cardinality of the collection of initial intervals. The first theorem states that a partial order has no infinite antichains if and only if its initial intervals are finite unions of ideals. The second one asserts that a countable partial order is scattered and does not contain infinite antichains if and only if it has countably many initial intervals. We show that the left to right directions of these theorems are equivalent to ACA0 and ATR0, respectively. On the other hand, the opposite directions are both provable in WKL0, but not in RCA0. We also prove the equivalence with ACA0 of the following result of Erdös and Tarski: a partial order with no infinite strong antichains has no arbitrarily large finite strong antichains. 相似文献
55.
Emanuele Raviolo 《Annali di Matematica Pura ed Applicata》2014,193(2):551-559
Given a generic curve of genus $g\ge 4$ and a smooth point $L\in W_{g-1}^{1}(C)$ , whose linear system is base-point free, we consider the Abel–Jacobi normal function associated with $L^{\otimes 2}\otimes \omega _{C}^{-1}$ , when $(C,L)$ varies in moduli. We prove that its infinitesimal invariant reconstructs the couple $(C,L)$ . When $g=4$ , we obtain the generic Torelli theorem proved by Griffiths. 相似文献
56.
Fabio Fenili Clara Rigamonti Alberto Bossi Paolo Ferruti Amedea Manfredi Stefano Maiorana Clara Baldoli Silvia Cauteruccio Emanuela Licandro Elisabetta Ranucci 《Journal of polymer science. Part A, Polymer chemistry》2010,48(21):4704-4710
A tetrathia‐[7]‐helicene bearing in the 2 and 13 positions cyanovinyl groups was used as comonomer in the Michael‐type polyaddition reaction with N,N′‐bis(β‐mercaptoethyl)piperazine. This led to a new polymer bearing tetrathia‐[7]‐helicene units regularly distributed along the polymer backbone, which may be regarded as the first example of a new family of potentially useful nonlinear optical materials. All products were structurally characterized by 1H and 13C NMR spectroscopy. Differential scanning calorimetry characterizations revealed the presence, in both monomeric and polymeric helicenes, of glass‐transition like temperatures, associated to some conformational variation of the helicene units. The optical properties, the film formation and the morphology of the polymer‐containing tetratia‐[7]‐helicenes were also investigated. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献
57.
Conformationally restricted analogues of β-methylaspartic acid were easily prepared starting from chiral N-protected trans-3-amino-4-methoxycarbonyl pyrrolidin-2-ones. The key step of the synthesis was the methylation reaction at C-4, proceeding with high diastereoselection syn to the protected amino group lying at C-3 of the pyrrolidin-2-one ring. 相似文献
58.
Silvia Bonettini Emanuele Galligani Valeria Ruggiero 《Computational Optimization and Applications》2007,37(1):1-34
This paper deals with the solution of nonlinear programming problems arising from elliptic control problems by an interior
point scheme. At each step of the scheme, we have to solve a large scale symmetric and indefinite system; inner iterative
solvers, with an adaptive stopping rule, can be used in order to avoid unnecessary inner iterations, especially when the current
outer iterate is far from the solution.
In this work, we analyse the method of multipliers and the preconditioned conjugate gradient method as inner solvers for interior
point schemes. We discuss the convergence of the whole approach, the implementation details and report the results of numerical
experimentation on a set of large scale test problems arising from the discretization of elliptic control problems. A comparison
with other interior point codes is also reported.
This research was supported by the Italian Ministry for Education, University and Research (MIUR) projects: FIRB Project:
“Parallel Nonlinear Numerical Optimization PN
2
O” (grant n. RBAU01JYPN, ) and COFIN/PRIN04 Project “Numerical Methods and Mathematical Software for Applications” (grant n. 2004012559, ). 相似文献
59.
Emanuele Galligani 《Annali dell'Universita di Ferrara》2002,48(1):99-117
Sunto L’applicazione di noti metodi che utilizzano funzioni di tipo blending per la costruzione di funzioni bivariate C1 per l’interpolazione di dati, richiede la conoscenza delle derivate parziali del primo ordine ai vertici di una triangolazione
sottostante. In questo lavoro consideriamo il metodo proposto da Nielson, che consiste nel calcolare stime delle derivate
parziali del primo ordine minimizzando un opportuno funzionale quadratico, caratterizzato da parametri di tensione non negativi.
Scopo del lavoro è l’analisi di alcune proprietà particolari di questo funzionale per la costruzione di algoritmi efficienti
e robusti per la determinazione delle stime suddette delle derivate quando si ha a che fare con insiemi di dati di grandi
dimensioni.
Abstract
The application of widely known blending methods for constructingC
1 bivariate functions interpolating scattered data requires the knowledge of the partial derivatives of first order at the
vertices of an underlying triangulation. In this paper we consider the method proposed by Nielson that consists in computing
estimates of the first order partial derivatives by minimizing an appropriate quadratic functional, characterized by nonnegative
tension parameters. The aim of the paper is to analyse some peculiar properties of this functional in order to construct robust
and efficient algorithms for determining the above estimates of the derivatives when we are concerned with extremely large
data sets.
相似文献
60.
Mariagrazia Bianchi David Chillag Mark L. Lewis Emanuele Pacifici 《Proceedings of the American Mathematical Society》2007,135(3):671-676
Let be a finite group, and write for the set of degrees of irreducible characters of . We define to be the graph whose vertex set is , and there is an edge between and if . We prove that if is a complete graph, then is a solvable group.