Line-by-line calculations of thermal infrared radiation representative for global condition: CFC-12 as an example

We estimate a current direct radiative forcing due to CFC-12 of 0.18 Wm^-2, which is likely to be the peak radiative forcing for CFC-12. Global measurements of CFC-12 show at present an almost negligible trend for CFC-12 and measurement in an industrialized region show evidence that the peak concentration is reached. It is expected that concentration of CFC-12 in industrialized regions begins to decline 1-3 years before the global concentration.Our radiative forcing calculations are based on a line-by-line model appropriate for simulation of global mean radiative forcing, including clouds and stratospheric temperature adjustment. The radiative forcing of 0.33 Wm^-2/ppbv is close to earlier published results for this compound. New spectroscopic measurements for CFC-12 are performed and compared to previously published results.     

Cost-Effective Migration from Sub-Lambda to Wavelength-Based Metro Networks

This article will discuss the importance of hybrid coexistence of sub-lambda grooming with wavelength-based services for driving down costs and maximizing the use of metro bandwidth, as well as enabling next-generation lambda-based services. The article will also address migration to all optical metro networks.     

Synthesis and catalytic properties of microemulsion-derived cerium oxide nanoparticles

The synthesis of cerium dioxide nanoparticles using an inverse microemulsion technique and precipitation method was investigated. Cerium hydroxide nanoparticles were synthesized by adding diluted ammonia to n-heptane–surfactant–cerium nitrate system. The micelle and particle size in the range of 5–12 nm were controlled by varying the molar water to surfactant ratio and analyzed by dynamic light scattering (DLS), small angle X-ray scattering (SAXS) and high-resolution transmission electron microscopy (HRTEM). Cerium hydroxide nanoparticles were isolated and subsequently treated at 100–600 °C to obtain nanoscale ceria. Crystallite sizes of cerium dioxide in the range of 6–16 nm were estimated by Scherrer analysis by X-ray diffraction (XRD) and HRTEM. The catalytic activity of particles annealed at 400 and 600 °C in soot combustion reactions was characterized by temperature-programmed oxidation (TPO) indicating a size-dependant activity. Crystallite sizes and catalytic stability of elevated ceria systems were tested in second combustion cycles.