How Different Snacks Produce a Distinct Effect in Salivary Protein Composition

Saliva secretion changes in response to different stimulation. Studies performed in animals and humans suggest that dietary constituents may influence saliva composition, although the dynamics of these changes, and how they are specific for each type of food, are little known. The objective of the present study was to access the short-term effects of different foods in salivation and salivary protein composition. Twelve participants were tested for four snacks (yoghurt, bread, apple and walnuts). Non-stimulated saliva was collected before and at 0′, 5′ and 30′ after each snack intake. Flow rate, total protein, alpha-amylase enzymatic activity and salivary protein profile were analyzed. Yoghurt and apple were the snacks resulting in higher salivary changes, with higher increases in flow rate and alpha-amylase activity immediately after intake. The expression levels of immunoglobulin chains decreased after the intake of all snacks, whereas cystatins and one pink band (proline-rich proteins—PRPs) increased only after yoghurt intake. Walnut’s snack was the one resulting in lower changes, probably due to lower amounts eaten. Even so, it resulted in the increase in one PRPs band. In conclusion, changes in saliva composition varies with foods, with variable changes in proteins related to oral food processing and perception.     

Effect of multiperforated plates on the acoustic modes in combustors

The analytical model derived by Howe assessing the acoustic effect of perforated plates has been implemented in a 3D Helmholtz solver. This solver allows one to compute the acoustic modes of industrial chambers taking into account the multiperforated plates present for the cooling of the walls. An academic test case consisting of two coaxial cylinders, with the inner one being perforated is used to validate the implementation in the general purpose AVSP code. This case is also used to show the effects of the presence of the plates. In particular, the sensitivity of the acoustic damping to the bias flow speed will be studied. A maximum absorption speed is shown, and the behaviour towards an infinite speed will be illustrated by the academic case. Computations are also conducted in the case of an industrial helicopter chamber. The value of the maximum absorption speed is discussed to explain why the modes are in fact not much absorbed by the perforated plates, and that the frequencies are the same as for walls. To cite this article: E. Gullaud et al., C. R. Mecanique 337 (2009).     

A two‐phase adaptive finite element method for solid–fluid coupling in complex geometries

In this paper we present a method to solve the Navier–Stokes equations in complex geometries, such as porous sands, using a finite‐element solver but without the complexity of meshing the porous space. The method is based on treating the solid boundaries as a second fluid and solving a set of equations similar to those used for multi‐fluid flow. When combined with anisotropic mesh adaptivity, it is possible to resolve complex geometries starting with an arbitrary coarse mesh. The approach is validated by comparing simulation results with available data in three test cases. In the first we simulate the flow past a cylinder. The second test case compares the pressure drop in flow through random packs of spheres with the Ergun equation. In the last case simulation results are compared with experimental data on the flow past a simplified vehicle model (Ahmed body) at high Reynolds number using large‐eddy simulation (LES). Results are in good agreement with all three reference models. Copyright © 2010 John Wiley & Sons, Ltd.     

Characterization of Commercial Polyvinylbutyrals

Several analyses have been carried out to thoroughly characterize five commercial polyvinyl butyral films supplied by various manufacturers. Model compounds (PVB and plasticizers) having the highest purity available were also used as reference. FT-IR and ¹H- and ¹³C-NMR spectroscopy were used to ascertain the structure of the investigated ter-polymer, as well that of the incorporated additives (mainly the plasticizer). The ratio between these components was also determined. The chemical compositions of these PVBs were similar, and two different plasticizers were identified. The glass transition temperature (T _g ) was deduced from dynamic mechanical analyses (DMA) and found to be very similar for all the investigated films. Size exclusion chromatography (SEC) was also used to study the molecular weight distribution. The analyses were performed using several detectors, and they revealed that PVBs presented similar distributions with molecular weights ranging from 250,000 to 300,000 g/mol.     

Activity behaviour of electrolyte solutions: Evaluation of temperature effects by means of the quasi-random lattice model

The paper presents some applications of the Moggia–Bianco (quasi-random lattice) model for the calculation of mean activity and osmotic coefficients of electrolyte solutions, with emphasis on temperature effects. Aqueous uni-univalent and uni-divalent electrolytes from 0 °C to 100 °C are considered. Results show that the model is in general applicable over wide ranges of concentrations and temperatures, despite its dependence on a unique fitting parameter (which is, sometimes, experimentally known).Some theoretical aspects of the model are investigated. Hydration diameters are evaluated for uni-univalent systems. Concerning uni-divalent systems, charge-asymmetry effects are accounted for more rigorously than in previous works, starting from a better assessment of the relationship between the behaviour of the electrolyte at very low concentrations and the behaviour occurring at high concentrations.     

Headspace-trap gas chromatography–mass spectrometry for determination of sulphur mustard and related compounds in soil

Methods for trace determination of sulphur mustard (HD) and some related cyclic sulphur compounds in soil samples have been developed using headspace-trap in combination with gas chromatography–mass spectrometry (GC–MS). Two quite different types of soil were employed in the method optimisation (sandy loam and silty clay loam). Prior to analysis, water saturated with sodium chloride was added to the samples, at a water to soil ratio of 1:1. A detection limit of 3 ng/g was achieved for HD, while the cyclic sulphur compounds 1,4-thioxane, 1,3-dithiolane and 1,4-dithiane could be detected at 0.2–0.7 ng/g. The methods were validated in the concentration range from the limit of quantification (LOQ) to hundred times LOQ. The within assay precision at fifty times LOQ was 6.9–7.3% relative standard deviation (RSD) for determination of the cyclic sulphur compounds, and 15% RSD for determination of HD. Recoveries were in the range of 43–60% from the two soil types. As the technique requires very little sample preparation, the total time for sample handling and analysis was less than 1 h. The technique was successfully employed for the determination of cyclic sulphur compounds in a sediment sample from an old dumping site for chemical munitions, known to contain HD degradation products.