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21.
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De Cock LJ De Wever O Hammad H Lambrecht BN Vanderleyden E Dubruel P De Vos F Vervaet C Remon JP De Geest BG 《Chemical communications (Cambridge, England)》2012,48(29):3512-3514
Here we present a facile method to fabricate microporous hydrogel scaffolds that can be functionalized with a chemokine gradient. These scaffolds allow studying cellular responses in a 3D environment. 相似文献
23.
Maxwell D. Cummings Tse‐I Lin Lili Hu Abdellah Tahri David McGowan Katie Amssoms Stefaan Last Benoit Devogelaere Marie‐Claude Rouan Leen Vijgen Jan Martin Berke Pascale Dehertogh Els Fransen Erna Cleiren Liesbet vanderHelm Gregory Fanning Kristof VanEmelen Origne Nyanguile Kenny Simmen Pierre Raboisson Sandrine Vendeville 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2012,124(19):4715-4718
24.
The Discrete Element Method (DEM) is useful for modelling granular flow. The accuracy of DEM modelling is dependent upon the model parameter values used. Determining these values remains one of the main challenges. In this study a method for determining the parameters of cohesionless granular material is presented. The particle size and density were directly measured and modelled. The particle shapes were modelled using two to four spheres clumped together. The remaining unknown parameter values were determined using confined compression tests and angle of repose tests. This was done by conducting laboratory experiments followed by equivalent numerical experiments and iteratively changing the parameters until the laboratory results were replicated. The modelling results of the confined compression tests were mainly influenced by the particle stiffness. The modelling results of the angle of repose tests were dependent on both the particle stiffness and the particle friction coefficient. From these observations, the confined compression test could be used to determine the particle stiffness and with the stiffness known, the angle of repose test could be used to determine the particle friction coefficient. Usually DEM codes do not solve the equations of motion for so-called walls (non-granular structural elements). However, in this study a dynamic model of a dragline bucket is developed and implemented in a commercial DEM code which allows the dynamics of the walls to be modelled. The DEM modelling of large systems of particles is still a challenge and procedures to simplify and speed up the modelling of dragline bucket filling are presented. Using the calibrated parameters, numerical results of bucket filling are compared to experimental results. The model accurately predicted the orientation of the bucket. The model also accurately predicted the drag force over the first third of the drag, but predicted drag forces too high for the subsequent part of the drag. 相似文献
25.
The dynamics of an irrotational compressible flow is considered in several space dimensions both theoretically and by numerical experiments. First we derive the nonlinear scalar wave equation (9) describing sound waves of small amplitude and small dissipation. The associated weak-turbulence equations in the limit of zero dissipation are solved by exact stationary power laws for the spectrum. But the numerical solutions of the inviscid equation (9) show the tendency of breaking down after a finite time, leading to shock spectra instead of the weak-turbulence spectra. This shows that an asymptotic analysis of cumulants does not account for intermittency effects.Finally it is argued that for the inviscid case no other closure of the hierarchy can take intermittency into account. 相似文献
26.
De Ruyck H Daeseleire E De Ridder H Van Renterghem R 《Journal of chromatography. A》2002,976(1-2):181-194
A liquid chromatographic-tandem mass spectrometric multiresidue method for the simultaneous quantitative determination of the tetrahydroimidazole, levamisole and the benzimidazoles thiabendazole, oxfendazole, oxibendazole, albendazole, fenbendazole, febantel and triclabendazole in milk has been developed and validated. The anthelmintic residues were extracted with ethyl acetate. The liquid chromatographic separation was performed on a reversed-phase C18 column with gradient elution. The analytes were detected by tandem quadrupole mass spectrometry after positive electrospray ionisation by multiple reaction monitoring. The confirmatory method is very sensitive and each component can be detected at a residue level lower than 1 microgram/l. The method is validated according to the revised European Union requirements and all parameters were found conform the criteria. The evaluated parameters were linearity, specificity, stability, recovery, precision (repeatability and within-laboratory reproducibility) and analytical limits (detection limit, decision limit and detection capability). This analytical method is applied in the Belgian monitoring programme for classical anthelmintic veterinary drugs in raw farm cow's milk. 相似文献
27.
Bosma G Pathmamanoharan C de Hoog EH Kegel WK van Blaaderen A Lekkerkerker HN 《Journal of colloid and interface science》2002,245(2):292-300
We report a single step procedure to prepare monodisperse colloidal poly(methyl)methacrylate (PMMA) particles where fluorescent dyes are incorporated into the polymer network. The particles are sterically stabilized against flocculation by poly(12-hydroxystearic acid). The fluorescent dyes are RITC (rhodamine isothiocyanate)-aminostyrene (RAS) and 4-methylaminoethylmethacrylate-7-nitrobenzo-2-oxa-1,3-diazol (NBD-MAEM), which are prepared from (commercially available) RITC and 4-chloro-7-nitrobenzo-2-oxa-1,3-diazol (NBD-Cl), respectively, as starting materials. The particles can be grown larger with nonfluorescent PMMA. Examples of the usefulness of these model particles in colloid science are given. 相似文献
28.
29.
Tom Breugelmans Els Tourwé Yves Van Ingelgem Jan Wielant Tom Hauffman René Hausbrand Rik Pintelon Annick Hubin 《Electrochemistry communications》2010,12(1):2-5
In this work, odd random phase multisine Electrochemical Impedance Spectroscopy (ORP-EIS) was used as a detection method for the onset of corrosion of coated steel. The possibility to use ORP-EIS as a rapid-screening test for corrosion was investigated. It is concluded that the detection of a non-linear behavior combined with a non-stationary behavior during the onset of corrosion can be used as a criterion in a rapid-screening test for corrosion of coated steel. 相似文献
30.
This paper reports 261 substituent increments for the 1H? NMR. chemical shifts (solvent: CDCl3) of the 18- and 19-methyl protons of 9β, 10α(retro)-steroids relative to 5β,9β,10α,-androstane. The increments were calculated by a least-squares procedure from 1334 spectra of 759 different steroids. 相似文献