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91.
Lipton AS Heck RW Sears JA Ellis PD 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2004,168(1):66-74
Solid-state NMR spectroscopy of half-integer quadrupolar nuclides has received a lot of interest recently with the advent of new methodologies and higher magnetic fields. We present here the extension of our previous low temperature method to an 18.8T system. This new probe entailed a total redesign including a cross coil and variable capacitors that are operational at cryogenic temperatures. The limitations to sensitivity are also discussed; including a new diode network, the utilization of a cryogenic band pass filter, and the consequences of the RF profiles of the coil. Further, details of the spectroscopy of quadrupolar nuclei in a protein are discussed, such as the observation of the outer transitions and how to distinguish them from the desired +/-1/2 transition. 相似文献
92.
We describe an algorithm for the dominating set problem with time complexity O((4g+40)kn2) for graphs of bounded genus g1, where k is the size of the set. It has previously been shown that this problem is fixed parameter tractable for planar graphs. We give a simpler proof for the previous O(8kn2) result for planar graphs. Our method is a refinement of the earlier techniques. 相似文献
93.
Piotr H. Chankowski John Ellis Stefan Pokorski Martti Raidal Krzysztof Turzy
ski 《Nuclear Physics B》2004,690(3):279-301
We present predictions for flavour-violating charged-lepton decays induced by the seesaw mechanism implemented within the constrained minimal supersymmetric standard model (CMSSM) with universal input soft supersymmetry breaking terms. We assume that one heavy singlet neutrino almost decouples from the seesaw mechanism, as suggested by the pattern of light neutrino masses and mixing angles. This is suggested independently by sneutrino inflation with a low reheating temperature, TRH107 GeV, so as to avoid overproducing gravitinos. This requirement further fixes the mass of the weakly-coupled sneutrino, whose decays may lead to leptogenesis. We find that BR(μ→eγ)10−13 but BR(τ→μγ)10−9 in the bulk of the acceptable parameter space, apart from a few isolated points. The ratio BR(μ→eγ)/BR(τ→eγ) depends on only one complex parameter, and is particularly interesting to compare with experiment. 相似文献
94.
Curran SA Ellis AV Vijayaraghavan A Ajayan PM 《The Journal of chemical physics》2004,120(10):4886-4889
Spectroscopic analysis and atomic force microscopy (AFM) phase imaging studies show self-assembly of phenosafranin (PSF) to multiwalled carbon nanotubes (MWNTs). The shift in absorption spectra is associated with charge transfer of valence electrons from PSF to electron accepting sites on the MWNTs. The Raman-active disorder modes are used to fingerprint PSF attachment to MWNTs via defect states. AFM phase imaging was used to obtain a molecular topographic visual confirmation of PSF attached to the MWNT. 相似文献
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Electron crystallography as a structural determination technique has grown dramatically in use over recent years. Improvements in microscopes, equipment, practical techniques, computation facilities and image processing methods are reflected in the increasing number of near-atomic resolution structures that have been published.In this review we shall summarize the techniques involved in structure determination of soluble proteins using electron crystallography. Many soluble protein structures have been investigated in this manner over the past two decades. Here we present several examples where a variety of approaches have been used to gradually increase the information obtained. 相似文献
98.
We argue that quantum-gravitational fluctuations in the space-time background give the vacuum non-trivial optical properties that include diffusion and consequent uncertainties in the arrival times of photons, causing stochastic fluctuations in the velocity of light in vacuo. Our proposal is motivated within a Liouville string formulation of quantum gravity that also suggests a frequency-dependent refractive index of the particle vacuum. We construct an explicit realization by treating photon propagation through quantum excitations of D-brane fluctuations in the space-time foam. These are described by higher-genus string effects, that lead to stochastic fluctuations in couplings, and hence in the velocity of light. We discuss the possibilities of constraining or measuring photon diffusion in vacuo via -ray observations of distant astrophysical sources. 相似文献
99.
Keating KA Myers JD Pelton JG Bair RA Wemmer DE Ellis PD 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2000,143(1):172-183
We have developed a "virtual NMR facility" (VNMRF) to enhance access to the NMR spectrometers in Pacific Northwest National Laboratory's Environmental Molecular Sciences Laboratory (EMSL). We use the term virtual facility to describe a real NMR facility made accessible via the Internet. The VNMRF combines secure remote operation of the EMSL's NMR spectrometers over the Internet with real-time videoconferencing, remotely controlled laboratory cameras, real-time computer display sharing, a Web-based electronic laboratory notebook, and other capabilities. Remote VNMRF users can see and converse with EMSL researchers, directly and securely control the EMSL spectrometers, and collaboratively analyze results. A customized Electronic Laboratory Notebook allows interactive Web-based access to group notes, experimental parameters, proposed molecular structures, and other aspects of a research project. This paper describes our experience developing a VNMRF and details the specific capabilities available through the EMSL VNMRF. We show how the VNMRF has evolved during a test project and present an evaluation of its impact in the EMSL and its potential as a model for other scientific facilities. All Collaboratory software used in the VNMRF is freely available from www.emsl.pnl.gov:2080/docs/collab. 相似文献
100.