Barrier effect and coupled transport in the electrodialysis of metal complexonate solutions

The electrodialysis of an aqueous solution of an alkaline earth complex with ethylenediaminetetraacetic acid (EDTA) was studied in a wide range of current densities. The curve of the complexonate flow across an anionite membrane versus current density has three characteristic sections. The first section corresponds to a linear increase in the flow as a function of current density, the second to a decrease in the flow and decomposition of the complex (barrier effect), and the third to an increase in the complexonate flow due to the transport coupled with the flow of hydroxyl ions formed in the dissociation of water molecules at the interface of the solution and the anionite membrane. Conditions for complete separation of the singly and doubly charged cations were found.     

The synthesis of dihydrouridine diphosphate glucose

Summary We have carried out the synthesis of dihydrouridine diphosphate glucose.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 914–8915 May, 1965 Original article submitted August 1, 1964     

Photonic-crystal properties of a 1D longitudinally magnetized periodic structure

Features of propagation of circularly polarized waves in a plane-layer periodic longitudinally magnetized ferromagnet—dielectric structure are studied. Dispersion relations and reflection coefficients are obtained, and frequency dependences of the Bloch wavenumber and reflection coefficients are constructed for natural waves of the periodic structure under investigation. The dependences of the polarization plane rotation angle in the polar Kerr effect on the frequency and the ratio of the thicknesses of layers over a period are constructed for various numbers of periods in the structure.     

Comparison theorems for symplectic systems of difference equations

In the present paper, we prove comparison theorems for symplectic systems of difference equations, which generalize difference analogs of canonical systems of differential equations. We obtain general relations between the number of focal points of conjoined bases of two symplectic systems with matrices W _i and $ \hat W_i $ \hat W_i as well as their corollaries, which generalize well-known comparison theorems for Hamiltonian difference systems. We consider applications of comparison theorems to spectral theory and in the theory of transformations. We obtain a formula for the number of eigenvalues λ of a symplectic boundary value problem on the interval (λ ₁, λ ₂]. For an arbitrary symplectic transformation, we prove a relationship between the numbers of focal points of the conjoined bases of the original and transformed systems. In the case of a constant transformation, we prove a theorem that generalizes the well-known reciprocity principle for discrete Hamiltonian systems.     

Defect mode suppression in a photonic crystal with a magnetic defect in the ferromagnetic resonance region

The specific features of the transmission and reflection spectra of a one-dimensional photonic crystal structure with a magnetically active layer placed between dielectric Bragg mirrors have been investigated. If the magnetic resonance frequency coincides with the frequency of the defect mode in one of the photonic bands, the defect mode in the photonic crystal can be completely suppressed, which makes it possible to effectively control the spectrum of such a structure by an external magnetic field.     

Effect of Electrode Material on Electrodeposition of Tungsten Oxide

Influence exerted by the nature of an electrode-substrate on the electrochemical deposition of tungsten oxides from a metastable acid solution of isopolytungstate was studied. As substrates for obtaining tungsten oxide deposits served metallic electrodes made of gold and platinum, films of mixed indium-tin oxide on glass (ITO-electrodes) and also glassy carbon electrodes and glassy carbon electrodes coated with films of conducting polymers: polyaniline, polypyrrole, and poly-3,4-ethylenedioxythiophene. It was shown that the nature of a substrate noticeably affects the electrochemical properties of tungsten oxide deposits. These differences are attributed to the adsorption of hydrogen on platinum in the range of the deposition potentials of tungsten oxide and to the chemical interaction of polytungstate ions with the thiophene sulfur of the polymer.

     

Microgravimetric study of electrochemical properties of PEDOT/WO3 composite films in diluted sulfuric acid

Journal of Solid State Electrochemistry - Poly-3,4-ethylenedioxythiophene composite films with tungsten oxide (PEDOT/WO3) were obtained by potentiodynamic deposition of tungsten oxide from acidic...