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991.
992.
993.
Dipl.‐Chem. Michaela Ruppert Dr. Fabian Spänig Dr. Mateusz Wielopolski Christof M. Jäger Prof. Dr. Walter Bauer Prof. Dr. Timothy Clark Prof. Dr. Andreas Hirsch Prof. Dr. Dirk M. Guldi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(35):10797-10807
We have realized for the first time a series of truly water‐soluble and tightly coupled porphyrin/C60 electron‐donor–acceptor conjugates in which the charge separation and charge recombination dynamics are controlled by modifying the nature of the dendrimer and/or the choice of the central metal atom. 相似文献
994.
995.
J. Tillmans P. Hirsch W. Hirsch F. Siebert J. Jackisch H. Dick A. Szent-Györgi und S. S. Silva 《Fresenius' Journal of Analytical Chemistry》1933,92(5-6):214-218
Ohne Zusammenfassung 相似文献
996.
Joachim Allouche David Lantiat Monika Kuemmel Marco Faustini Christel Laberty Corrinne Chanéac Elisabeth Tronc Cédric Boissière Lionel Nicole Clément Sanchez David Grosso 《Journal of Sol-Gel Science and Technology》2010,53(3):551-554
ZrO2 Inorganic NanoPatterns have been prepared on conductive electrodes by the direct block copolymer templating method associated with sol–gel dip-coating followed by thermal treatment. They have then been successfully utilised to direct the co-electrodeposition of FePt nanoparticles into the 2D well-ordered arrays of nanoelectrodes with controlled dimension and periodicity. By this method, the FePt nanodomains are confined and stabilised into the well-ordered cavities of the ZrO2 membrane. While this system constitutes the first steps towards high-density magnetic storage media, the present fully bottom-up method can be easily scaled up and generalised to infinite nanocomposite combinations. 相似文献
997.
Elisabeth Mansfield Aparna Kar Stephanie A. Hooker 《Analytical and bioanalytical chemistry》2010,396(3):1071-1077
Carbon nanotubes exhibit a range of chemistries, including mixtures of different nanotube diameters, lengths, and chiralities
coupled with various concentrations of metallic and non-nanotube-carbon impurities. The performance of a given material for
a specific application depends on the chemistry, which is dictated in large part by the manufacturing process. Here, thermogravimetric
analysis is utilized as a bulk characterization method for determining nanotube quality after manufacturing. The application
of thermogravimetric analysis for quantifying basic nanotube chemistry is described (e.g., carbon-to-metal content, homogeneity).
In addition, extension of the method to analyze specific nanotube properties (i.e., length and diameter) is reported. Results
indicate that thermogravimetric analysis is sufficiently sensitive to enable quality control at both the macro-scale (carbon-to-metal
ratio) and nano-scale (single-walled to multi-walled) and can detect subtle modifications in manufacturing processes. 相似文献
998.
J. Tillmans P. Hirsch und E. Reinshagen 《Fresenius' Journal of Analytical Chemistry》1929,76(7-8):315-316
Ohne Zusammenfassung 相似文献
999.
1000.
Raja Shahid Ashraf Elisabeth Klemm 《Journal of polymer science. Part A, Polymer chemistry》2005,43(24):6445-6454
Low‐band‐gap π‐conjugated polymers composed of π‐excessive thiophene and π‐deficient benzothiadiazole and quinoxaline units were prepared in high yields by a polycondensation method using palladium cross‐coupling reactions of alkylthiophene diacetylenes, 4,7‐dibromo‐2,1,3‐benzothiadiazole, and 5,8‐dibromo‐2,3‐dipyridine‐2‐ylquinoxaline. The copolymers were characterized by NMR, IR, UV, gel permeation chromatography, and elemental analysis. High‐molecular‐weight (weight‐average molecular weight up to 82,600 g/mol), thermostable, soluble, and film‐forming materials were obtained. The polymers were photoluminescent in chloroform and showed metallic luster in the solid state. The absorption and emission in solution and in the solid state of the polymers revealed that the polymers generated a π‐stacked structure in the solid state, and the polymer molecules in the film were ordered. Thin films of poly[3‐dodecylthiophen‐2,5‐diylethynylene‐(benzo[1,2,5]thiadiazole‐4,7‐diyl)ethynylene] ( P‐1 ), poly[3,4‐di dodecylthiophen‐2,5‐diylethynylene‐(benzo[1,2,5]thiadiazole‐4,7‐diyl)ethynylene] ( P‐2 ), poly[3‐dodecylthiophene‐2,5‐diylethynylene‐(2,3‐dipyridine‐2‐ylquinoxaline‐5,8‐diyl)ethynylene] ( P‐3 ), and poly[3,4‐didodecylthiophene‐2,5‐diylethynylene‐(2,3‐dipyridine‐2‐ylquinoxaline‐5,8‐diyl)‐ethynylene] ( P‐4 ) exhibited an optical band gap of ~1.85–2.08 eV. The highest occupied molecular orbital and lowest unoccupied molecular orbital levels of the polymers were determined from electrochemical measurements. In the absorption and emission spectra of these polymers in chloroform/methanol mixtures, all the polymers revealed solvatochromic effects, which were related to the formation of aggregates, as confirmed by temperature‐dependence absorption investigations. The absorption spectra of P‐2 and P‐4 at different temperatures also revealed significant effects of the structure on the molecular interactions. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 6445–6454, 2005 相似文献