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101.
102.
Vinyl polymerized norbornene has some useful properties such as good mechanical strength, optical transparency and heat resistance. Several transition metal complexes have been described in the literature as active catalysts for the vinyl polymerization of norbornene. We now report the use of three types of nickel(II) complexes with N‐heterocyclic carbene (NHC) ligands in the catalytic vinyl polymerization of norbornene under a range of conditions. Specifically, two nickel complexes bearing a chelating bis(NHC) ligand, two nickel complexes bearing two chelating anionic N‐donor functionalized NHC ligands as well as one diiodidonickel(II) complex with two monodentate NHC ligands were tested. The solid‐state structure of bis(1,3‐dimethylimidazol‐2‐ylidene)diiodidonickel(II), as determined by X‐ray crystallography, is presented. The highest polymerization activity of 2.6 × 107 g (mol cat)?1 h?1 was observed using the latter nickel complex as catalyst, activated by methylaluminoxane. The norbornene polymers thus obtained are of high molecular weight but with rather low polydispersity. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
103.
Elisabeth Kallin Hans Lönn Thomas Norberg Mikael Elofsson 《Journal of carbohydrate chemistry》2013,32(4):597-611
Abstract Reducing oligosaccharides were converted in good yields into the corresponding primary glycosylamines by treatment with aqueous ammonium bicarbonate. The glycosylamines were then acryloylated and the obtained oligosaccharide N-acryloyl glycosylamines were copolymerized with acrylamide. High molecular weight, linear copolymers were obtained, which were useful as antigens in immunoassays. 相似文献
104.
Herein, the iron‐catalyzed reduction of a variety of alkynes with silanes as a reductant has been examined. With a straightforward catalyst system composed of diiron nonacarbonyl and tributyl phosphane, excellent yields and chemoselectivities (>99 %) were obtained for the formation of the corresponding alkenes. After studying the reaction conditions, and the scope and limitations of the reaction, several attempts were undertaken to shed light on the reaction mechanism. 相似文献
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Elisabeth Kapatsina 《Nachrichten aus der Chemie》2016,64(10):1022-1022
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Thomas Heuser Elisabeth Weyandt Dr. Andreas Walther 《Angewandte Chemie (International ed. in English)》2015,54(45):13258-13262
Switchable self‐assemblies respond to external stimuli with a transition between near‐equilibrium states. Although being a key to present‐day advanced materials, these systems respond rather passively, and do not display autonomous dynamics. For autonomous behavior, approaches must be found to orchestrate the time domain of self‐assemblies, which would lead to new generations of dynamic and self‐regulating materials. Herein, we demonstrate catalytic control of the time domain of pH‐responsive peptide hydrogelators in a closed system. We program transient acidic pH states by combining a fast acidic activator with the slow, enzymatic, feedback‐driven generation of a base (dormant deactivator). This transient state can be programmed over orders of magnitude in time. It is coupled to dipeptides to create autonomously self‐regulating, dynamic gels with programmed lifetimes, which are used for fluidic guidance, burst release, and self‐erasing rapid prototyping. 相似文献
110.
Oxidized low-density lipoproteins (OxLDLs) like malondialdehyde-modified low-density lipoprotein (MDA-LDL) play a major role in atherosclerosis and have been proposed as useful biomarkers for oxidative stress. In this study, gold-nanoparticles (GNPs) were functionalized via distinct chemistries with anti-MDA-LDL antibodies (Abs) for selective recognition and capture of MDA-LDL from biological matrices. The study focused on optimization of binding affinities and saturation capacities of the antiMDA-LDL-Ab-GNP bioconjugate by exploring distinct random and oriented immobilization approaches, such as (i) direct adsorptive attachment of Abs on the GNP surface, (ii) covalent bonding by amide coupling of Abs to carboxy-terminated-pegylated GNPs, (iii) oriented immobilization via oxidized carbohydrate moiety of the Ab on hydrazide-derivatized GNPs and (iv) cysteine-tagged protein A (cProtA)-bonded GNPs. Depending on immobilization chemistry, up to 3 antibodies per GNP could be immobilized as determined by ELISA. The highest binding capacity was achieved with the GNP-cProtA-Ab bioconjugate which yielded a saturation capacity of 2.24 ± 0.04 μg mL−1 GNP suspension for MDA-LDL with an affinity Kd of 5.25 ± 0.11 × 10−10 M. The GNP-cProtA-antiMDA-LDL bioconjugate revealed high specificity for MDA-LDL over copper(II)-oxidized LDL as well as native human LDL. This clearly demonstrates the usefulness of the new GNP-Ab bioconjugates for specific extraction of MDA-LDL from plasma samples as biomarkers of oxidative stress. Their combination as specific immunoextraction nanomaterials with analysis by LC–MS/MS allows sensitive and selective detection of MDA-LDL in complex samples. 相似文献