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Selenoacetals derived from 1,3-propanediselenol and 1,2-ethanediselenol are much less prone to be cleaved by butyllithiums than their open chain analogues. The stereochemistry of the products resulting from these reactions as well as from the cleavage of the C---Se bond under radical conditions is disclosed.  相似文献   
34.
Magnetic susceptibilities play a very important part in NMR spectra, but their values are not always known; here, the authors give a method for the measurement of paramagnetic susceptibilities and suggest an explanation about linear dependence of magnetic susceptibility vs. observed shift.  相似文献   
35.
When R is a fuzzy relation between the elements of a finite set X, the fuzzy subsets A of X such that R·A = A (max-min composition) are called eigen fuzzy sets. In this paper we describe algorithms for the determination of the greatest eigen fuzzy set associated with a given fuzzy relation, thinking of medical diagnosis applications.  相似文献   
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Stannyl and silyl alkylselenides have been efficiently transformed to the corresponding alkylselenolates on reaction with butyllithiums. Other conditions proved to be limited.  相似文献   
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[structure: see text] Apoptolidin (1) exhibits potent and highly selective apoptosis inducing activity against sensitive cancer cell lines and is hypothesized to act by inhibition of mitochondrial F(0)F(1)-ATP synthase. A series of apoptolidin derivatives, including a new intermolecular Diels-Alder adduct, were analyzed for antiproliferative activity in E1A-transformed rat fibroblasts. Potent F(0)F(1)-ATPase inhibition was not a sufficient determinant of antiproliferative activity for several analogues, suggesting the existence of a secondary biological target or more complex mode of action for apoptolidin.  相似文献   
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We present a new iterative reconstruction algorithm to improve the algebraic reconstruction technique (ART) for the Single-Photon Emission Computed Tomography. Our method is a generalization of the Kaczmarz iterative algorithm for solving linear systems of equations and introduces exact and implicit attenuation correction derived from the attenuated Radon transform operator at each step of the algorithm. The performances of the presented algorithm have been tested upon various numerical experiments in presence of both strongly non-uniform attenuation and incomplete measurements data. We also tested the ability of our algorithm to handle moderate noisy data. Simulation studies demonstrate that the proposed method has a significant improvement in the quality of reconstructed images over ART. Moreover, convergence speed was improved and stability was established, facing noisy data, once we incorporate filtration procedure in our algorithm.  相似文献   
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This paper provides a simple approach for the consideration of quadratic BSDEs with bounded terminal conditions. Using solely probabilistic arguments, we retrieve the existence and uniqueness result derived via PDE-based methods by Kobylanski (2000) [14]. This approach is related to the study of quadratic BSDEs presented by Tevzadze (2008) [19]. Our argumentation, as in Tevzadze (2008) [19], highly relies on the theory of BMO martingales which was used for the first time for BSDEs by Hu et al. (2005) [12]. However, we avoid in our method any fixed point argument and use Malliavin calculus to overcome the difficulty. Our new scheme of proof allows also to extend the class of quadratic BSDEs, for which there exists a unique solution: we incorporate delayed quadratic BSDEs, whose driver depends on the recent past of the YY component of the solution. When the delay vanishes, we verify that the solution of a delayed quadratic BSDE converges to the solution of the corresponding classical non-delayed quadratic BSDE.  相似文献   
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