Immobilized ruthenium complexes and aspects of their reactivity

Methodologies for the immobilization and characterization of ruthenium complexes into/onto functionalized silica gel, zeolites, polymers, dendrimers, sol–gel, nano and microparticles are described. The corresponding spectroscopic, electrochemical, and photochemical properties as well as chemical reactivities are used for their characterization and study. Comparison between the reactivities of immobilized and in solution species is presented. Some biological applications are also described.     

Solution of Set-Covering and Set-Partitioning Problems Using Assignment Relaxations

Graph theoretic relaxations are used to design tree search algorithms for set-covering and set-partitioning problems. In this paper two assignment relaxations for the set-covering and set-partitioning problems are presented and a tree search method is developed which makes use of these relaxations. Computational experience of processing a collection of test problems is reported.     

Méthode particulaire anisotropeAnisotropic particle method

A particle method has been used to simulate the vorticity transport in a two-dimensional flow of an incompressible inviscid fluid. In this method, not only the location and the circulation of the particle are used but also the moments of the internal vorticity. The transport equation for these moments has been derived from the vorticity transport equation. The method has been compared to the usual particle method as well as to Teng's elliptic vortex model. The test case is that of the evolution of two circular patches of vorticity already used by Teng. To cite this article: A. Beaudoin et al., C. R. Mecanique 330 (2002) 51–56     

Changes in the morphology of interstellar ice analogues after hydrogen atom exposure

The morphology of water ice in the interstellar medium is still an open question. Although accretion of gaseous water could not be the only possible origin of the observed icy mantles covering dust grains in cold molecular clouds, it is well known that water accreted from the gas phase on surfaces kept at 10 K forms ice films that exhibit a very high porosity. It is also known that in the dark clouds H(2) formation occurs on the icy surface of dust grains and that part of the energy (4.48 eV) released when adsorbed atoms react to form H(2) is deposited in the ice. The experimental study described in the present work focuses on how relevant changes of the ice morphology result from atomic hydrogen exposure and subsequent recombination. Using the temperature-programmed desorption (TPD) technique and a method of inversion analysis of TPD spectra, we show that there is an exponential decrease in the porosity of the amorphous water ice sample following D-atom irradiation. This decrease is inversely proportional to the thickness of the ice and has a value of ?(0) = 2 × 10(16) D-atoms cm(-2) per layer of H(2)O. We also use a model which confirms that the binding sites on the porous ice are destroyed regardless of their energy depth, and that the reduction of the porosity corresponds in fact to a reduction of the effective area. This reduction appears to be compatible with the fraction of D(2) formation energy transferred to the porous ice network. Under interstellar conditions, this effect is likely to be efficient and, together with other compaction processes, provides a good argument to believe that interstellar ice is amorphous and non-porous.     

|\epsilon|-Near-zero materials in the near-infrared

We consider a mixture of metal-coated quantum dots dispersed in a polymer matrix and, using a modified version of the standard Maxwell-Garnett mixing rule, we prove that the mixture parameters (particles radius, quantum dots gain, etc.) can be chosen so that the effective medium permittivity has an absolute value very close to zero in the near-infrared, i.e. $|{\rm Re}(\epsilon)| \ll 1$ and $|{\rm Im}(\epsilon)| \ll 1$ at the same near-infrared wavelength. Resorting to full-wave simulations, we investigate the accuracy of the effective medium predictions and we relate their discrepancy with rigorous numerical results to the fact that $|\epsilon| \ll 1$ is a critical requirement. We show that a simple method for reducing this discrepancy, and hence for achieving a prescribed and very small value of $|\epsilon|, $ consists in a subsequent fine-tuning of the nanoparticles volume filling fraction.     

Sur des familles remarquables d'hypersurfaces isoparamétriques dans les espaces sphériques

Sans résumé     

Sur les représentations linéaires des groupes clos

Sans résumé