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11.
12.
For the first time, a novel, straightforward and inexpensive route for immobilization of metals in Schiff base complex form is reported applying 2,4‐toluenediisocyanate as a precursor of primary amine group. A nickel(II) Schiff base complex supported on nano‐TiO2 was designed and synthesized as an effective heterogeneous nanocatalyst for organic reactions, and well characterized using various techniques such as Fourier transform infrared spectroscopy, field emission scanning electron microscopy, transmission electron microscopy, X‐ray diffraction, energy‐dispersive X‐ray analysis and thermogravimetric analysis. The catalytic efficiency of the complex was evaluated in selective oxidation of sulfide to sulfoxide by hydrogen peroxide as an oxidant under solvent‐free conditions at room temperature, which successfully resulted in high yield and high conversion of products. Effective factors including solvent type, oxidant and catalyst amount were also optimized. The catalyst shows outstanding reusability and could be impressively recovered for six consecutive cycles without significant change of its catalytic efficiency. 相似文献
13.
Razieh Fazaeli Hamid Aliyan Elham Naderi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(6):745-754
Abstract The immobilization of heteropoly acids (HPAs) into the Al-functionalized KIT-6 mesoporous molecular sieve has been carried out to see the effect of Al-KIT-6 as a host matrix on the HPA activities. These modified mesoporous molecular sieves are effective catalysts for the Hosomi–Sakurai three-component coupling reaction via condensation of aldehydes, silyl ethers, and allylsilanes. Supplemental materials are available for this paper. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file. 相似文献
14.
Niloofar Seydi Behnam Mahdavi Sogand Paydarfard Akram Zangeneh Mohammad Mahdi Zangeneh Fariba Najafi Ali R. Jalalvand Elham Pirabbasi 《应用有机金属化学》2019,33(9)
In recent decades, nanotechnology is growing rapidly owing to its widespread application in science and industry. The aim of the experiment was chemical characterization and evaluation of cytotoxicity, antioxidant, antibacterial, antifungal, and cutaneous wound healing activities of titanium nanoparticles using aqueous extract of Ziziphora clinopodioides Lam leaves (TiNPs@Ziziphora). These nanoparticles were characterized by fourier transformed infrared spectroscopy (FT‐IR), field emission scanning electron microscopy (FE‐SEM), energy dispersive X‐ray spectroscopy (EDS), and UV–visible spectroscopy. The synthesized TiNPs@Ziziphora had great cell viability dose‐dependently (Investigating the effect of the plant on human umbilical vein endothelial cells (HUVECs) cell line) and revealed this method was nontoxic. Then, 2,2‐diphenyl‐1‐picrylhydrazyl (DPPH) free radical scavenging test was done to assess the antioxidant properties, which indicated similar antioxidant potentials for TiNPs@Ziziphora and butylated hydroxytoluene. Agar diffusion tests were applied to determine the antibacterial and antifungal characteristics. Minimum Inhibitory Concentration (MIC), Minimum Bactericidal Concentration (MBC), and Minimum Fungicidal Concentration (MFC) were specified by macro‐broth dilution assay. The data were analyzed by SPSS 21 software (Duncan post‐hoc test). TiNPs@Ziziphora indicated higher antibacterial and antifungal effects than all standard antibiotics (p ≤ 0.01). Also, TiNPs@Ziziphora inhibited the growth of all bacteria at 2‐16 mg/ml concentrations and removed them at 2‐32 mg/ml concentrations (p ≤ 0.01). In case of antifungal properties of TiNPs@Ziziphora, they prevented the growth of all fungi at 2‐8 mg/ml concentrations and destroyed them at 2‐16 mg/ml concentrations (p ≤ 0.01). In vivo experiment, after creating the cutaneous wound, the rats were randomly divided into six groups: untreated control, treatment with Eucerin basal ointment, treatment with 3% tetracycline ointment, treatment with 0.2% TiO2 ointment, treatment with 0.2% Z. clinopodioides ointment, and treatment with 0.2% TiNPs@Ziziphora ointment. These groups were treated for 10 days. For histopathological and biochemical analysis of the healing trend, a 3 × 3 cm section was prepared from all dermal thicknesses at day 10. Use of TiNPs@Ziziphora ointment in the treatment groups substantially reduced (p ≤ 0.01) the wound area, total cells, neutrophil, and lymphocyte and remarkably raised (p ≤ 0.01) the wound contracture, hydroxyl proline, hexosamine, hexuronic acid, fibrocyte, and fibrocytes/fibroblast rate compared to other groups. In conclusion, the results revealed the useful non‐cytotoxic, antioxidant, antibacterial, antifungal, and cutaneous wound healing effects of TiNPs@Ziziphora. 相似文献
15.
A 2D hole‐type hexagonal lattice photonic crystal is utilized, herein, to detect the refractive index change of the material infiltrated into the designed circular sensing area which also resembles a ring resonator. The accuracy of the detection process is enhanced considering the simultaneous shift of the resonance wavelengths and the intensity modulation which occur in two separate spectral regions. The presented structure has the ability to detect liquids, material concentrations in fluids and gases having refractive indices in the range of n = 1–2 with sensitivity and quality factor of 61 nm/RIU and 3000, respectively, for resonance‐wavelength‐shift‐based operation. The detection range of n = 1–1.4 with the sensitivity of S = 0.69 NI/RIU is achieved for the intensity‐based measurement and the results show good linearity in the operating range. 相似文献
16.
Mohammad Yousefi Elham Noori Davood Ghanbari Masoud Salavati-Niasari Tahereh Gholami 《Journal of Cluster Science》2014,25(2):397-408
In this work, poly vinyl alcohol–ZnO nanocomposites were synthesized via two different in situ and ex-situ methods. In ex-situ, at first zinc oxide nanostructures were synthesized by one-step precipitation reaction between zinc acetate and sodium hydroxide. The effect of different surfactants such as poly vinyl pyrrolidone, poly vinyl alcohol and poly ethylene glycol on the morphology of ZnO nanostructures was investigated. Nanostructures were characterized by X-ray diffraction, scanning electron microscopy. The influence of ZnO nanostructures on the flame retardancy of the poly vinyl alcohol matrix was studied using underwriter laboratories UL-94 analysis. 相似文献
17.
Atieh Khosravi Mohammad Reza Khani Elham Dejban Goy Babak Shokri 《Plasma Chemistry and Plasma Processing》2018,38(2):365-378
In present paper, an atmospheric-pressure low-temperature plasma treatment of pyrolysis fuel oil (PFO) was investigated in dielectric barrier discharge plasma torch reactor. The effect of the applied voltage and the volume of feedstock, as the main parameters, on the cracking of PFO were studied. By increasing the applied voltage from 10 to 16 kV, the production rate of hydrocarbons containing methane, ethylene, acetylene, propane, propylene, and C4 rise 18 times. In this case, the production rate of hydrogen increases by approximately 14 times and reaches 7.27 × 10?3 mol/min for 16 kV. In the feedstock volume investigation, based on limitation of reactor volume, the production rate of hydrocarbons decreased from 0.44 × 10?3 to 0.15 × 10?3 mol/min by increasing volume of feedstock from 1 to 5 cc. 相似文献
18.
Mahdi Tohidian Mohadeseh Nouri Elham Jaafarnia Amir Hossein Haghighi 《Journal of Macromolecular Science: Physics》2015,54(1):17-31
The preparation and characterization of a new type of nanocomposite polyelectrolyte membrane, based on DuPont Nafion/imidazole-modified nanosilica (Im-Si), for direct methanol fuel cell applications is described. Related to the interactions between the protonated imidazole groups, grafted on the surface of nanosilica, and negatively charged sulfonic acid groups of Nafion, new electrostatic interactions can be formed in the interface of Nafion and Im-Si which result in both lower methanol permeability and also higher proton conductivity. Physical characteristics of these manufactured nanocomposite membranes were investigated by scanning electron microscopy, thermogravimetry analysis, differential scanning calorimetry, Fourier transform infrared spectroscopy, water uptake, methanol permeability, and ion-exchange capacity, as well as proton conductivity. The Nafion/Im-Si membranes showed higher proton conductivity, lower methanol permeability and, as a consequence, higher selectivity parameter in comparison to the neat Nafion or Nafion/silica membranes. The obtained results indicated that the Nafion/Im-Si membranes could be utilized as promising polyelectrolyte membranes for direct methanol fuel cell applications. 相似文献
19.
Kobra Zarei Elham Teymori Kamalodin Kor 《International journal of environmental analytical chemistry》2013,93(14-15):1407-1421
In this work, a glassy carbon electrode (GCE) modified with poly (diphenylamine)/multi-walled carbon nanotubes-β-cyclodextrin (PDPA/MWCNT-β-CD) film was constructed and used for the determination of 4-nitrophenol (4-NP). Diphenylamine was successfully electropolymerised onto MWCNT-β-CD-modified GCE by cyclic voltammetry in monomer solution and 5 mol L?1 H2SO4. The surface morphology of PDPA/MWCNT-β-CD film was characterised using scanning electron microscopy and electrochemical impedance spectroscopy. After adsorption of 4-NP on PDPA/MWCNT-β-CD at 0.2 V for 150 s, it showed a well-defined reduction peak in phosphate buffer solution at pH = 7. The PDPA/MWCNT-β-CD film enhanced the reduction peak current due to the complex formation between β-CD and 4-NP, presence of conductive polymer film as electron transfer mediator and also ability of MWCNTs for strong adsorptive and catalytic effect. Peak current increased linearly with 4-NP concentration in the range of 0.1 to 13.9 µg L?1. The detection limit was obtained as 0.02 µg L?1, which is better than other reported detection limits for the determination of 4-NP. The results showed that modified electrode has good sensitivity and selectivity. This sensor was used for the determination of 4-NP in water samples. 相似文献
20.
Mohamed M. Hassan Elham S. Othman Mohamed Abass 《Research on Chemical Intermediates》2013,39(3):1209-1225
3-Acetyl-4-methylthioquinolin-2(1H)-one (3) has been prepared and its reactivity towards treatment with different reagents, dilute sulfuric acid, aqueous sodium hydroxide, and hydrogen peroxide, is described. The reactions of compound 3 with benzylamine, benzaldehyde, DMF-DMA, Vilsmeier-Haack reagent, 2-chloro-3-formyl-pyridopyrimidone and malononitrile have been carried out under convenient conditions. Compound 3 underwent heterocyclization reactions with some binucleophiles, hydrazine, hydroxylamine, urea, thiourea, semicarbazide, and thiosemicarbazide, furnishing some known five, six, and seven heterocyclic annellated quinolines. All the new compounds have been characterized using different spectral and analytical tools. 相似文献