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101.
Heck and oxidative boron Heck reactions employing Pd(II) supported amphiphilized polyethyleneimine‐functionalized MCM‐41 (MCM‐41@aPEI‐Pd) as an efficient and recyclable nanocatalyst 下载免费PDF全文
Fatemeh Ashori Alireza Samzadeh‐Kermani Hosein Hamadi Mohammad Reza Ganjali Hamideh Aghahosseini Ali Ramazani Mehdi Khoobi Elham Gholibegloo 《应用有机金属化学》2018,32(3)
A novel nanocatalyst was developed based on covalent surface functionalization of MCM‐41 with polyethyleneimine (PEI) using [3‐(2,3‐Epoxypropoxy)propyl] trimethoxysilane (EPO) as a cross‐linker. Amine functional groups on the surface of MCM‐41 were then conjugated with iodododecane to render an amphiphilic property to the catalyst. Palladium (II) was finally immobilized onto the MCM‐41@PEI‐dodecane and the resulted MCM‐41@aPEI‐Pd nanocatalyst was characterized by FT‐IR, TEM, ICP‐AES and XPS. Our designed nanocatalyst with a distinguished core‐shell structure and Pd2+ ions as catalytic centers was explored as an efficient and recyclable catalyst for Heck and oxidative boron Heck coupling reactions. In Heck coupling reaction, the catalytic activity of MCM‐41@aPEI‐Pd in the presence of triethylamine as base led to very high yields and selectivity. Meanwhile, the MCM‐41@aPEI‐Pd as the first semi‐heterogeneous palladium catalyst was examined in the C‐4 regioselective arylation of coumarin via the direct C‐H activation and the moderate to excellent yields were obtained toward different functional groups. Leaching test indicated the high stability of palladium on the surface of MCM‐41@aPEI‐Pd as it could be recycled for several runs without significant loss of its catalytic activity. 相似文献
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Foad Kazemi Ali Reza Kiasat Elham Fadavipoor 《Phosphorus, sulfur, and silicon and the related elements》2013,188(2):433-436
A simple convenient procedure for dehydration of aldoximes has been developed using silica gel/thionyl chloride in heterogeneous conditions. The method has been found to be effective for a wide range of aromatic oximes. 相似文献
105.
Hosseinirad Elham Hormozi Faramarz 《Journal of Thermal Analysis and Calorimetry》2019,135(3):1849-1861
Journal of Thermal Analysis and Calorimetry - In the present work, different passive methods have been numerically investigated to improve the thermal performance in a miniature channel. The heat... 相似文献
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Ahmad Shaabani Abbas Rahmati Elham Farhangi Ali Hossein Rezayan 《Monatshefte für Chemie / Chemical Monthly》2007,35(1):615-618
A novel class of 3,4-dihydrobenzimidazo[2,1-b]quinazolin-1(2H)-ones was synthesized in very short reaction times with good yields in the presence of 3-butyl-1-methyl imidazolium bromide
as a room temperature ionic liquid at 120°C. The ionic liquid can be recycled for subsequent reactions without any loss of
efficiency. 相似文献
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Using DFT methods, the electronic properties and the first hyperpolarizabilities of porphyrin‐like porous C24N24 fullerene decorated with (Li3O)n = (1–5) have been systematically investigated. It is found that Li3O molecules can effectively be adsorbed over N4 cavities of C24N24 with high interaction energies. This interaction is found to narrow the HOMO‐LUMO gap and work function values of C24N24. Thus its electronic properties are strongly sensitive to interaction with the Li3O molecules. Indeed, compared with the sole parent C24N24 fullerene, (Li3O)n = (1–5)@C24N24 possess large first hyperpolarizabilities (β0 ). Obviously, the Li3O superalkali chemisorbed over C24N24 fullerene exhibit not only excellent stability but also large first hyperpolarizability. Therefore, they are expected to be potential innovative candidates for excellent electro‐optical materials. 相似文献
110.
This note makes a correction to the paper “Top local cohomology modules and Gorenstein injectivity with respect to a semidualizing module”. 相似文献