Lithium storage mechanisms and effect of partial cobalt substitution in manganese carbonate electrodes

A promising group of inorganic salts recently emerged for the negative electrode of advanced lithium-ion batteries. Manganese carbonate combines low weight and significant lithium storage properties. Electron paramagnetic resonance (EPR) and magnetic measurements are used to study the environment of manganese ions during cycling in lithium test cells. To observe reversible lithium storage into manganese carbonate, preparation by a reverse micelles method is used. The resulting nanostructuration favors a capacitive lithium storage mechanism in manganese carbonate with good rate performance. Partial substitution of cobalt by manganese improves cycling efficiency at high rates.     

Inversive congruential generator over a Galois ring of dimension <Emphasis Type="Italic">p</Emphasis><Superscript><Emphasis Type="Italic">l</Emphasis></Superscript>

We consider the construction of of an inversive congruential generator over a Galois ring of odd dimension p ^l , whichwas proposed by Solé and Zinoviev for p = 2. Using the estimates of trigonometric sums on the sequences of pseudorandom numbers, we obtain the estimates of a discrepant function, a generated sequence of pseudorandom numbers, and the associated sequence of two-dimensional “overlapping” points.     

Cluster Expansion in the Canonical Ensemble

We consider a system of particles confined in a box ${\Lambda \subset \mathbb{R}^d}$ interacting via a tempered and stable pair potential. We prove the validity of the cluster expansion for the canonical partition function in the high temperature - low density regime. The convergence is uniform in the volume and in the thermodynamic limit it reproduces Mayer??s virial expansion providing an alternative and more direct derivation which avoids the deep combinatorial issues present in the original proof.     

Canonical forms for positive discrete-time linear control systems

In this paper, the properties of reachability, controllability and essential reachability of positive discrete-time linear control systems are studied. These properties are characterized in terms of the directed graph of the state matrix. From these characterizations canonical forms of those properties are deduced.     

Synthesis and Stereochemistry of Novel Dibrominated 1,5-Dioxaspiro[5.5]undecane Derivatives

Summary.  The synthesis and stereochemistry of new dibrominated spiro-1,3-dioxane derivatives are reported. Investigations by means of NMR methods and single crystal X-ray diffraction for two compounds revealed the high regio- and diastereoselectivity of the bromination reaction of some new spiro-1,3-dioxanes and the asymmetric induction of the chiral carbon atom located in the spiro skeleton. Received July 13, 1999. Accepted October 21, 1999     

A variational approach to chaotic dynamics in periodically forced nonlinear oscillators

We prove that a class of problems containing the classical periodically forced pendulum equation displays the main features of chaotic dynamics. The approach is based on the construction of multibump type heteroclinic solutions to periodic orbits by the use of global variational methods.     

Sandwich Complexes Based on the “All‐Metal” Al42‐ Aromatic Ring.

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.     

Inverse homogenization with diagonal Padé approximants

The paper formulates inverse homogenization problem as a problem of recovery of Markov function using diagonal Padé approximants. Inverse homogenization or de-homogenization problem is a problem of deriving information about the micro-geometry of composite material from its effective properties. The approach is based on reconstruction of the spectral measure in the analytic Stieltjes representation of the effective tensor of two-component composite. This representation relates the n-point correlation functions of the microstructure to the moments of the spectral measure, which contains all information about the microgeometry. The problem of identification of the spectral function from effective measurements in an interval of frequency has a unique solution. The problem is formulated as an optimization problem which results in diagonal Padé approximation and exact formulas for the moments of the measure. The reconstructed spectral function can be used to evaluate geometric parameters of the structure and to compute other effective parameters of the same composite; this gives solution to the problem of coupling of different effective properties of a two-component composite material with random microstructure. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Multifunctional Thermally Reversible Nanostructured Thermosetting Materials Based on Block Copolymers Dispersed Liquid Crystal

Thermally reversible nanostructured thermosetting materials are prepared for the first time by modification of an epoxy resin with 5 wt.‐% of an amphiphilic polystyrene‐block‐poly(ethylene oxide) block copolymer (PSEO) and 30 wt.‐% of a low‐molecular‐weight liquid crystal, 4′‐(hexyl)‐4‐biphenylcarbonitrile (HBC). The epoxy system modified with 5 wt.‐% PSEO amphiphilic copolymer self‐assembles into spherical microdomains with a size distribution between 32 and 45 nm in diameter. Under the same conditions, the modification of an epoxy system with 5 wt.‐% PSEO and 30 wt.‐% HBC leads to a micro‐phase separated PS‐rich domains embedded in a HBC phase. The morphology of this nanostructured thermosetting system consists in a higher amount of spherical microdomains of PSEO/HBC with the size distribution between 40 and 75 nm in diameter. This implies that the separation of the PS‐rich phase provokes the separation of the liquid crystal and allows one to obtain a novel thermally switchable smart material.