全文获取类型
收费全文 | 5537篇 |
免费 | 218篇 |
国内免费 | 17篇 |
专业分类
化学 | 4217篇 |
晶体学 | 25篇 |
力学 | 64篇 |
数学 | 764篇 |
物理学 | 702篇 |
出版年
2023年 | 44篇 |
2022年 | 77篇 |
2021年 | 214篇 |
2020年 | 135篇 |
2019年 | 160篇 |
2018年 | 140篇 |
2017年 | 113篇 |
2016年 | 217篇 |
2015年 | 196篇 |
2014年 | 184篇 |
2013年 | 392篇 |
2012年 | 400篇 |
2011年 | 414篇 |
2010年 | 263篇 |
2009年 | 228篇 |
2008年 | 314篇 |
2007年 | 370篇 |
2006年 | 312篇 |
2005年 | 266篇 |
2004年 | 222篇 |
2003年 | 192篇 |
2002年 | 157篇 |
2001年 | 75篇 |
2000年 | 74篇 |
1999年 | 65篇 |
1998年 | 59篇 |
1997年 | 41篇 |
1996年 | 42篇 |
1995年 | 40篇 |
1994年 | 34篇 |
1993年 | 28篇 |
1992年 | 28篇 |
1991年 | 22篇 |
1990年 | 16篇 |
1989年 | 8篇 |
1988年 | 12篇 |
1987年 | 10篇 |
1986年 | 6篇 |
1985年 | 16篇 |
1984年 | 33篇 |
1983年 | 11篇 |
1982年 | 15篇 |
1981年 | 19篇 |
1980年 | 8篇 |
1979年 | 7篇 |
1978年 | 16篇 |
1977年 | 10篇 |
1976年 | 11篇 |
1975年 | 8篇 |
1974年 | 6篇 |
排序方式: 共有5772条查询结果,搜索用时 31 毫秒
21.
Elena Yu. FursovaVictor I. Ovcharenko Galina V. RomanenkoEugene V. Tretyakov 《Tetrahedron letters》2003,44(34):6397-6399
Reduction of nitronyl nitroxides using hexamethylenetetramine is a very convenient method for preparing the corresponding imino nitroxides and 2-imidazoline N-oxides. 相似文献
22.
M. Kveder R. Rakoš M. Gavella V. Lipovac G. Pifat S. Pečar M. Schara 《Applied magnetic resonance》2004,27(1-2):77-86
The perturbation of the physical state of cell membranes triggered by an external oxidative stimulus has been studied with sperm cells which were chosen as a model system. Electron paramagnetic resonance (EPR) spectroscopy was applied and three different nitroxides bearing a paramagnetic group on the 5th, 7th and 13th carbon of the stearic acid acyl chain were used to probe different regions of the membrane. The theoretical simulations of the experimental spectra indicate distinct domains in the intact cell plasma membrane where local steric constraints impose different degrees of motional averaging experienced by the reporter group. Upon the external oxidative stimulus the spectral changes were proportional to the accumulated oxidation products and were detected only for the reporter group residing close to the lipid-water interface. The EPR spectra reveal that the motion of the reporter group has slowed down in the oxidized cells and that the oxidatively modified membrane shows up as a more rigid structure as compared with the native state. The results also indicate that the oxidation-induced spectral changes are supressed in the presence of gangliosides. 相似文献
23.
In this paper we face the problem of stowing a containership, referred to as the Master Bay Plan Problem (MBPP); this problem
is difficult to solve due to its combinatorial nature and the constraints related to both the ship and the containers. We
present a decomposition approach that allows us to assign a priori the bays of a containership to the set of containers to
be loaded according to their final destination, such that different portions of the ship are independently considered for
the stowage. Then, we find the optimal solution of each subset of bays by using a 0/1 Linear Programming model. Finally, we
check the global ship stability of the overall stowage plan and look for its feasibility by using an exchange algorithm which
is based on local search techniques. The validation of the proposed approach is performed with some real life test cases.
This work has been developed within the research area: “The harbour as a logistic node” of the Italian Centre of Excellence
on Integrated Logistics (CIELI) of the University of Genoa, Italy 相似文献
24.
This paper addresses the problem of determining stowage plans for containers in a ship, that is the so-called master bay plan problem (MBPP). 相似文献
25.
The “true detection limit” CL,true was measured by a method proposed by Boumans et al. for 10 prominent lines of La, Ce, Pr, Nd and Sm, the most abundant rare
earth elements (REEs) in geological samples. It is demonstrated how spectral interferences can increase of CL,true. The spectra were excited in an argon arc plasma jet with evaporation powders of five complex natural samples. The data show
that there is a significant increase of CL,true in real samples containing large concentrations of such elements as Ti, Zr, Cr, Nb, Ta and REEs emitting complex spectra.
Received: 17 June 1997 / Revised: 20 October 1997 / Accepted: 26 October 1997 相似文献
26.
Some Landau's type inequalities for infinitesimal generators 总被引:3,自引:0,他引:3
Summary Lett T(t) be a strongly continuous contraction semigroup on a complex Banach space and letA be its infinitesimal generator. We prove that, forx D(A
3), the following inequalities hold true: Ax3 243/8 x2A
3
x, A
2
x 24 xA
3
x2. Ift T(t) is a contraction group (resp. cosine function) we get the analogous but better inequalities with constants 9/8 and 3 (resp. 81/40 and 72/25) instead of 243/8 and 24. We consider also uniformly bounded semigroups, groups and cosine functions. 相似文献
27.
Elena Prestini 《Monatshefte für Mathematik》1988,105(3):207-216
LetfL
p(
n
),n2, be a radial function and letS
Rf be the spherical partial sums operator. We prove that if
thenS
Rf(x)f(x) a.e. asR. The result is false for
and
\frac{{2n}}{{n + 1}}$$
" align="middle" border="0">
.Partially supported by M.P.I. 相似文献
28.
Comparison of different fibers for the solid-phase microextraction of phthalate esters from water 总被引:3,自引:0,他引:3
Solid-phase microextraction (SPME) coupled to gas chromatography-mass spectrometry (GC-MS) has been applied to determine six phthalate esters and one adipate ester in water. The SPME parameters were optimized for several commercially available fibers. A 65-microm polydimethylsiloxane-divinylbenzene (PDMS-DVB) was the fiber selected and was applied to analysis of water from the Ebro river and the industrial port of Tarragona. The studied compounds were found at concentrations ranging from 0.4 microg l(-1) for di-n-butyl phthalate ester (DnBP) to 3.2 microg l(-1) for bis(2-ethylhexyl) phthalate ester (DEHP). The linear range for real samples was from 0.1 to 10 microg l(-1) for most phthalates, and the limits of detection of the method were between 3 and 30 ng l(-1). Repeatability and reproducibility between days (n = 5) for 1 microg l(-1) samples were below 13 and 18%, respectively. 相似文献
29.
J. J. LaBrecque Z. A. De Benzo E. Marcano C. A. Peña 《Journal of Radioanalytical and Nuclear Chemistry》1984,84(2):407-413
The comparison of an ambient temperature mercuric iodide spectrometer (HgI2) with a conventional cooled Si(Li) spectrometer is presented for the determination of niobium in Venezuelan laterites in the laboratory. The energy resolution of the HgI2 spectrometer was only about 590 eV (FWHM) at 5.9 keV compared to about 150 eV for the conventional Si(Li) spectrometer. The efficiency was about 5 times lower in the region of the NbK
peak as compared to the Si(Li) detector. Even though its energy resolution and efficiency is much poorer than the conventional Si(Li), the results it produced for the determination of niobium were acceptable for use in the exploration and exploitation of a niobium-rich deposit such as Cerro Impacto, Estado Bolívar, Venezuela. 相似文献
30.
The degradation process of TEOS-PDMS Ormosils containing different amounts of γ -APS has been studied by means of DTA, TG, FTIR and 29Si-NMR measurements. It has been found that the amount of γ -APS improved the thermal properties of Ormosil materials. The increase in γ -APS content causes the increment on the decomposition temperatures and activation energies of the studied Ormosils. These results have been attributed to the favourable effect of γ -APS in the copolymerisation reaction between TEOS and PDMS molecules. 29Si-NMR analyses have shown that the incorporation of γ -APS increases the concentration of D(Q) units in the Ormosil structure, i.e., increases the number of TEOS molecules bonded to PDMS ones. Initial decomposition temperature (IDT), temperature of maximum weight loss rate (Tmax), integral procedure decomposition temperature (IPDT) and activation energy values (E) were calculated from different equations which described the degradation of these materials. Addition of 10 wt% γ -APS produced an increase of 63∘C in the IDT and of 115 and 110∘C, respectively, for Tmax and IPDT (up to 478 and 610∘C) compared to the free γ -APS Ormosil. Activation energy values also rise up to 69.4 kJ⋅ mol−1 by introducing 10 wt% of γ -APS. 相似文献