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51.
The effect of the addition of some tetrazolic type organic compounds: 1-phenyl-5-mercapto-1,2,3,4-tetrazole (PMT), 1,2,3,4-tetrazole (TTZ), 5-amino-1,2,3,4-tetrazole (AT) and 1-phenyl-1,2,3,4-tetrazole (PT) on the corrosion of brass in nitric acid is studied by weight loss, polarisation and electrochemical impedance spectroscopy (EIS) measurements. The explored methods gave almost similar results. Results obtained reveal that PMT is the best inhibitor and the inhibition efficiency (E%) follows the sequence: PMT > PT > AT > TTZ. Polarization measurements also indicated that tetrazoles acted as mixed-type inhibitors without changing the mechanism of the hydrogen evolution reaction. Partial π-charge on atoms has been calculated. Correlation between the highest occupied molecular orbital energy EHOMO and inhibition efficiencies was sought. The adsorption of PMT on the brass surface followed the Langmuir isotherm. Effect of temperature is also studied in the (25-50 °C) range.  相似文献   
52.
In this paper we characterize the output feedback stabilization of some coupled systems with and without delay. The proof of the main result uses the method introduced in Haraux (Port. Math., 46:245–258, 1989), which consists of reducing the exponential decay of the closed loop system to an observability inequality of its corresponding conservative adjoint system.  相似文献   
53.
The vapour pressures of (sec-butylamine + water), (cyclohexylamine + water) binary mixtures, and of pure sec-butylamine and cyclohexylamine components were measured by means of two static devices at temperatures between 293 (or 273) K and 363 K. The data were correlated with the Antoine equation. From these data, excess Gibbs functions (GE) were calculated for several constant temperatures and fitted to a fourth-order Redlich–Kister equation using the Barker’s method. The (cyclohexylamine + water) system shows positive azeotropic behaviour for all investigated temperatures. The two binary mixtures exhibit positive deviations in GE for all investigated temperatures over the whole composition range.  相似文献   
54.
We consider an optimal control where the state-control relation is given by a quasi-variational inequality, namely a generalized obstacle problem. We give an existence result for solutions to such a problem. The main tool is a stability result, based on the Mosco-convergence theory, that gives the weak closeness of the control-to-state operator. We end the paper with some examples.  相似文献   
55.
In this paper we consider scheduling tasks on a multiprocessor system, taking into account communication delays. We propose a new Mixed Integer Program (MIP) formulation that drastically reduces both the number of variables and the number of constraints, when compared to the best mathematical programming formulations from the literature. In addition, we propose pre-processing procedures that generates cuts and bounds on all variables, reducing the solution space of the problem as well. Cuts are obtained by using forward and backward critical path method from project management field, while the upper bound is derived from the new greedy heuristic. Computational experience shows advantages of our approach.  相似文献   
56.
57.
The present paper is the lead article in a three‐part series on anisotropic mesh adaptation and its applications to structured and unstructured meshes. A flexible approach is proposed and tested on two‐dimensional, inviscid and viscous, finite volume and finite element flow solvers, over a wide range of speeds. The directional properties of an interpolation‐based error estimate, extracted from the Hessian of the solution, are used to control the size and orientation of mesh edges. The approach is encapsulated into an edge‐based anisotropic mesh optimization methodology (MOM), which uses a judicious sequence of four local operations: refinement, coarsening, edge swapping and point movement, to equi‐distribute the error estimate along all edges, without any recourse to remeshing. The mesh adaptation convergence of the MOM loop is carefully studied for a wide variety of test cases. The mesh optimization generic coupling of MOM with finite volume and finite element flow solvers is shown to yield the same final mesh no matter what the starting point is. It is also shown that on such optimized meshes, the need for computational fluid dynamics (CFD) stabilization artifices, such as upwinding or artificial viscosity, are drastically reduced, if not altogether eliminated, in most well‐posed formulations. These two conclusions can be considered significant steps towards mesh‐independent and solver‐independent CFD. The structure of the three‐part series is thus, 1, general principles; 2, methodology and applications to structured and unstructured grids; 3, applications to three‐dimensional flows. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   
58.
This Note is devoted to the study of the consistency of a stochastic algorithm having for object the estimates of a parameter under strong mixing assumption. To cite this article: A. Ait Saidi, A. Dahmani, C. R. Acad. Sci. Paris, Ser. I 340 (2005).  相似文献   
59.
The paper is devoted to studying the lower semicontinuity of vector-valued mappings. The main object under consideration is the lower limit. We first introduce a new definition of an adequate concept of lower and upper level sets and establish some of their topological and geometrical properties. A characterization of semicontinuity for vector-valued mappings is thereafter presented. Then, we define a concept of vector lower limit, proving its lower semicontinuity, and furnishing in this way a concept of lower semicontinuous regularization for mappings taking their values in a complete lattice. The results obtained in the present work subsume the standard ones when the target space is finite dimensional. In particular, we recapture the scalar case with a new flexible proof. In addition, extensions of usual operations of lower and upper limits for vector-valued mappings are explored. The main result is finally applied to obtain a continuous D.C. decomposition of continuous D.C. mappings. Dedicated to Alex Rubinov in honor of his 65th birthday  相似文献   
60.
We propose in this work, a simple method to calculate the bit error rate (BER) performance of a direct sequence code division multiple access (DS/CDMA) system over a Rayleigh multipath fading with power control error for both coherent and noncoherent reception, the RAKE structure receivers under consideration employ despreading sequences weighted (WDS) by exponential chip weighting waveforms. Numerical results show that the proposed approach reduce complexity and time of BER’s computing, then its performance does not undergo any degradation.  相似文献   
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