Synthesis and physico-chemical studies on transition metal complexes of symmetric bis-Schiff base ligands

Transition Metal Chemistry - A new series of symmetric bis-Schiff bases derived from 1,2-diaminoethane with bis-salicylaldehyde (H2L1) and/or bis-o-hydroxyacetophenone (H2L2) have been prepared....     

Syntheses and reactions of some fluorinated dienes,cyclobutenes and furans

There are many reports¹ of the pyrolysis of fluorinated organic compounds, including the defluorination of cyclic fluorocarbons over iron to give aromatic compounds. Extending this technique we have investigated the flow pyrolysis of some readily accessible unsaturated fluorocarbons, such as I, II, and III, and found these to be synthetically

useful routes to fluorinated dienes, cyclobutenes, and furans. Pyrolyses were carried out using a nitrogen flow over platinum, iron or caesium fluoride heated at 430–700°. The various products can all be rationalized in terms of intermediate allylic radicals, and the solid substrate influences which allylic radicals are formed.We are also investigating the chemistry of those now accessible compounds, such as IV, V, and VI, and some of the preliminary results are described.

For example the fluoride ion induced dimerisation of IV gave two major products VII and VIII via a particular interesting mechanism.

     

ChemInform Abstract: The Ground-State Potential Energy Surface of Diazene

has been studied by using a complete active space MCSCF wave function generated by distributing eight electrons among eight orbitals.