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981.
I. Najeh N. Ben Mansour H. Dahman A. Alyamani L. El Mir 《Journal of Physics and Chemistry of Solids》2012,73(6):707-712
Structural, electrical and morphological properties of electrical conducting nanoporous carbon structures, prepared at different pyrolysis temperatures by sol–gel method, were investigated. The effect of the measurement temperature on the electrical properties of the obtained sample pyrolysed at 675 °C was studied. The imaginary and real parts of the sample impedance versus frequency, in the range of 40 Hz–100 MHz, are investigated. The Nyquist diagrams were used to identify an equivalent circuit and the fundamental parameters of the circuit are determined at different temperatures with the aim to study the contributions of the grains and boundary grains to the conductivity. 相似文献
982.
This paper describes the optical, thermal, and electrical properties of an important nonpolar dielectric liquid, transformer oil. Applying dual laser (He–Ne and Argon laser of wavelengths 632.8 and 514.5 nm, respectively), and the Mach–Zehnder interferometric technique, the refractive indices and its temperature gradients are determined. Using Maxwell's and Cauchy's equations, the following optical, thermal, and electrical properties are calculated: optical and dielectric dispersion, optical permittivity and its thermal coefficient, thermal coefficient of volume expansion, specific refraction, specific dispersivity, characteristic impedance, electric susceptibility, and the variation of Cauchy's emperical constants with temperature. Additionally, different physical phenomena are studied as functions of wavelength and temperature. 相似文献
983.
M Oćwieja Z Adamczyk M Morga E Bielańska A Węgrzynowicz 《Journal of colloid and interface science》2012,380(1):51-59
In this research, a simple, green and effective strategy was developed to produce long-term stable oil in water emulsion from soy protein and soy polysaccharide. Soy protein and soy polysaccharide formed dispersible complexes at pH around 3.25 aqueous solution through electrostatic and hydrophobic interactions. A high pressure homogenization produced the protein/polysaccharide complex emulsion having a droplet size about 250 nm. A heat treatment of the emulsion resulted in the protein denaturation, forming irreversible oil-water interfacial films composed of soy protein/soy polysaccharide complexes. The droplets of the emulsion were characterized by dynamic light scattering, ζ-potential, transmission electron microscopy, polysaccharide digestion via pectinase, and confocal laser scanning microscopy observation via dual fluorescence probes. As a result of the polysaccharide being fixed on the droplet surface, the emulsions exhibited long-term stability in the media containing pH values of 2-8 and 0.2 mol/L NaCl. The stable soy protein/soy polysaccharide complex emulsion is a suitable food-grade delivery system in which lipophilic bioactive compounds can be encapsulated. 相似文献
984.
Wael A. El‐Sayed Omar M. Ali Merfat S. Faheem Ibrahim F. Zied Adel A.‐H. Abdel‐Rahman 《Journal of heterocyclic chemistry》2012,49(3):607-612
New [1,2,4‐oxadiazolyl]methyl‐3H‐[1,2,3]triazolo[4,5‐d]pyrimidin derivatives were synthesized starting from N′‐Hydroxy‐1‐naphthimidamide. The N‐substituted acyclic nucleoside analogs as well as the substituted glycosides were also prepared by reaction with the corresponding reagents. The antimicrobial results indicated that most of the tested compounds exhibited moderate to high antimicrobial activity whereas few compounds were found to exhibit little or no activity against the tested microorganisms. 相似文献
985.
Ahmed M. El‐Saghier Embarak F. Alwedi Naglaa M. Fawzy 《Journal of heterocyclic chemistry》2012,49(3):664-668
2‐Phenyl‐4‐benzylidene‐5(4H)‐oxazolones ( 1a‐e) were used as versatile starting materials for the synthesis of fused compounds such as: 4H‐3,1‐benoxazin‐4‐ones (2a,b), imidazo[4,3‐b]benzimidazoles (3,4), imidazo[1,5‐b]1,2,4‐triazoles (5a,b), and 7 . 相似文献
986.
Adel A.‐H. Abdel‐Rahman Wael A. El‐Sayed El‐Sayed G. Zaki Asem A. Mohamed Ahmed A. Fadda 《Journal of heterocyclic chemistry》2012,49(1):93-101
A number of new [(pyrazol‐4‐yl)methylene]hydrazono‐2,3‐dihydrothiazole derivatives, their sugar hydrazones and N‐glycosides were synthesized. Furthermore, N‐substituted oxygenated alkyl and hydroxyl derivatives and 1,3,4,‐oxadiazoline acyclic nucleoside analogs were prepared. The newly synthesized compounds were tested for their antimicrobial activities and showed moderate to high inhibition activities. J. Heterocyclic Chem., (2012). 相似文献
987.
Wafaa S. Hamama Hamada G. El‐Gohary Mamdouh Soliman Hanfi H. Zoorob 《Journal of heterocyclic chemistry》2012,49(3):543-554
This research work describes the synthesis and biological properties of some novel isolated or fused heterocyclic ring systems with pyrazole, for example; enaminones containing pyrazolone ring photochromic functional unit, 4‐[(4‐chlorophenylamino)methylene]‐3‐methyl‐1‐phenyl‐1H‐pyrazol‐5(4H)‐one (3) and some analogous derivatives 4, 9, and 10, also as pyrazolo[3,4‐b]pyridine, pyrazolo[3,4‐b]quinoline, pyrazolo[3′,4′:4,5]thieno[2,3‐c]pyrazoline and pyrazolo[3,4‐c]pyrazole were synthesized and characterized. Newly synthesized compounds were characterized by IR, 1H NMR, 13C NMR, mass spectral data and quantum mechanical calculations. Selected products were tested for their antibacterial and antitumor agents. 相似文献
988.
Khalil Al Mamari Hamid Ennajih Hafid Zouihri Rachid Bouhfid Seik Weng Ng El Mokhtar Essassi 《Tetrahedron letters》2012,53(18):2328-2331
The 1,3-dipolar cycloaddition of 1-allyl-5-haloisatin derivatives as dipolarophiles with the azomethine ylides generated in situ from N-allylisatin and l-proline to furnish novel dispiro-oxindoles has been investigated. The structures and relative stereochemistry of both types of cycloadducts were confirmed by single crystal X-ray diffraction, 1H and 13C NMR spectroscopy and mass spectrometry. 相似文献
989.
Aleksandra Tyl El?bieta Che?mecka Magdalena Jab?ońska Maria Nowak Joachim Kusz Karol Pasterny Roman Wrzalik 《Structural chemistry》2012,23(2):325-332
The X-ray structure, synthesis, theoretical calculation and IR spectra of 1-naphthaleneacrylic acid are reported. The titled
compound crystallizes in the monoclinic C 2/c space group with unit cell parameters: a = 14.556(3), b = 5.1332(10), c = 26.832(5) ?, β = 97.02(3)°, V = 1989.8(7) ?3, Z = 8 and form typical centrosymmetric hydrogen-bonded dimers. Theoretical calculations of 1-naphthylacrylic acid isolated
molecule and hydrogen-bonded dimer have been carried out using density functional theory at the B3LYP level. For optimized
structures the vibrational spectra have been then calculated and compared with experimental IR spectrum. The assignment and
characterization of theoretical vibrational spectra were based on the potential energy distribution analysis. This comparison
has shown that the theoretical spectrum for the dimer structure is in good agreement with the experimental one. Structural
comparisons with naphthalene, and with some substituted 2-propenoic acids have shown influence of the substituent on conformation
of the naphthalene ring or 2-propenoic moiety. 相似文献
990.
We present pseudo-potential calculations of geometrical structures of stable isomers of LiAr
n
clusters with both an electronic ground state and excited states of the lithium atom. The Li atom is perturbed by argon atoms
in LiAr
n
clusters. Its electronic structure obtained as the eigenfunctions of a single-electron operator describing the electron in
the field of a Li+Ar
n
core, the Li+ and Ar atoms are replaced by pseudo-potentials. These pseudo-potentials include core-polarization operators to account for
the polarization and correlation of the inert core with the valence Lithium electron [J Chem Phys 116, 1839 1]. The geometry optimization of the ground and excited states of LiAr
n
(n = 1–12) clusters is carried out via the Basin-Hopping method of Wales et al. [J Phys Chem 101, 5111 2; J Chem Phys 285, 1368 3]. The geometries of the ground and ionic states of LiAr
n
clusters were used to determine the energy of the high excited states of the neutral LiAr
n
clusters. The variation of the excited state energies of LiAr
n
clusters as a function of the number of argon atoms shows an approximate Rydberg character, corresponding to the picture
of an excited electron surrounding an ionic cluster core, is already reached for the 3s state. The result of optical transitions calculations shows that the absorption spectral features are sensitive to isomer
structure. It is clearly the case for transitions close to the 2p levels of Li which are distorted by the cluster environment. 相似文献