Quantum Discord for Information Transmission Using Coherent States

We suggest theoretically the possibility to transmit information through a decohering quantum channel employing Glauber’s coherent states. In fact, we study the dynamics of quantum correlations of two-mode entangled bipartite coherent states in the presence of the amplitude damping effect. In addition, we examine the quantum correlations based on quantum discord, which is a powerful key source in quantum information processing.     

Theoretical diagnostic and prediction of physical properties of quaternary InGaAsP compound using artificial neural networks optimized by the Levenberg Maquardt algorithm

The quaternaries \(In_{1 - x} Ga_{x} As_{y} P_{1 - y}\) are the main promising elements for the fabrication of optoelectronic devices. The adjustment of their physical parameters is assumed by the change of the molar fraction \(x\) and \(y\). These parameters can be affected by the variation of temperature and pressure. To make the theoretical diagnosis of these materials, it is fundamental to know the energy gap ‘\(\varvec{E}_{\varvec{g}}\)’ and the lattice parameter ‘\(a\)’, over a wide range of chemical compositions \(0 \le x \le 0.47\) and \(0 \le y \le 1\), at different temperatures and pressures. We show that by using the Artificial Neural Network method optimized by the Levenberg Maquardt algorithm ANN-LM, it is possible to obtain results very close to the experiment. The scatter plot and error calculation show that the ANN-LM model provides more accurate values of the lattice parameter than those calculated by Vegard’s law. On the other hand, the energy gap values \(Eg (x, y, T)\) estimated, using the ANN-LM model, proved to be close to the experimental values that those calculated by the empirical equations. In addition, the ANN-LM method allowed us to estimate with great accuracy the values of the energy gap at different temperatures and pressures \(Eg (P, T)\). Our work provides crucial information on the physical properties of the quaternary without the use of approximations, and without taking into account the hypothesis of a perfect agreement between \(InGaAsP\) and \(InP\) substrate.     

The effect of increasing the excitation level of the sodium atom on the structure of the NaArn polyatomic exciplexes

In this work, the geometrical structures, the formation energies, and electronic states of the Na(ms)Ar_n polyatomic exciplexes with m = 3-6 and n = 2-5 are studied by using a quantum-classical method. The interaction potential between an electronically excited sodium atom and argon atoms are calculated by using a one-electron model involving electron-Ar and electron-Na⁺ pseudopotentials, in which the Hamiltonian is diagonalized at every optimization step in the Basin Hopping algorithm. The relationship between the position of the electronically excited levels and the cluster geometry is investigated as a function of the excitation level and of the spatial extension of the excited electron orbital. We show that the equilibrium structures of the ground state Na(3s)Ar_n and those of the electronically excited states Na(4s)Ar_n, Na(5s)Ar_n, and Na(6s)Ar_n are significantly different. As a result of the detailed examination of the relationships between the geometrical structure and density distribution of the Na valence electron of the Na^∗Ar_n with n = 2-5 polyatomic exciplexes, we can see that for the Na(4s)Ar_n polyatomic exciplexes, the two extreme geometries, neutral Na(3s)Ar_n and ionic Na⁺Ar_n compete. It appears that none of them is the actual one. For Na(5s)Ar_n and Na(6s)Ar_n the valence electron is very weakly bound to the ionic core and described by a more diffused orbital so that the geometry and the formation energies of this excited state called Rydberg states converge towards those of the ionic cores.     

A Spectrophotometric Method for the Determination of Buclizine Hydrochloride Using the Charge-Transfer Spectrum of Buclizine-Iodine Complex

Abstract

A simple and sensitive spectrophotometric method is described for the determination of buclizine hydrochloride in bulk and tablets form. The method is based on the formation of charge-transfer complex between buclizine, as n-donor, and iodine, as Δ acceptor, which measured spectrophotometrically at 295 and 355 nm. A Job's plot indicated a 1:1 complex between the drug and iodine and Beer's law was obeyed in a concentration range of 4–30 μg ml^?1. A more detailed investigation of the complex was made with respect to its association constant and the free energy change. The method is simple and sensitive and has been applied successfully to the analysis of laboratory-made tablets without any interference from the tablet excipients. To validate the method, the results obtained were compared statistically with a newly developed uv-derivative spectrophotometric method. The charge-transfer method was favored due to its higher sensitivity, cheap coast and available equipments.     

New method for strength improvement of silica optical fibers

The reliability and the expected lifetime of optical fibers used in telecommunication technologies are closely related to the chemical environment action on the silica network. To ensure the long-term mechanical strength of the optical fibers, a polymer coating was applied onto the fiber surface during fiber fabrication. This external coating is vital to ensure a long optical fiber lifetime. Its protective action includes several functions, such as to protect glass fiber from any external damage, to limit chemical attack, in particular that of water, and finally to ensure fatigue protection and bending insensitivity, especially during handling and in-service installation. Since the mechanical strength of the fiber is controlled by its surface characteristics, we propose a new method for increasing fiber strength.The silica optical fibers used were 125 μm in diameter, with a 62.5 μm thick epoxy-acrylate coating. Fibers were rolled up around two similar cylinders. Using a screw, these cylinders moved away from one another and thus subjected the fibers to stretching. Submitted to this mechanical loading, the distended fibers were plunged into hot water at 65 or 85 °C and aged for several days. Then, the fibers were removed from the water and various weights were suspended on the fiber ends. Thus, the fibers were subjected to a tensile loading in static fatigue for several days. Just before fiber rupture, the fibers were unloaded and subjected to dynamic tensile tests at different velocities.Result analysis proved that the aging in hot water increased the fiber strength. The Weibull's diagram study shows a bimodal dispersion of defects on the fiber surface and the important role of polymer coating.     

The use of Omega Chrome Fast Blue 2G in the microdetermination of some metals

Summary Omega Chrome Fast Blue 2G has been found to be a suitable indicator for the detection of the equivalence point of calcium, magnesium and manganese in the presence of cadmium, nickel, and aluminium, when they are masked by the addition of cyanide or triethanolamine. It is also a suitable indicator for the back titration of aluminium using calcium or magnesium as a back titrant.This dye has also been found to be a suitable reagent for the colorimetric determination of calcium, magnesium, manganese and thorium.     

A thermometric study of the dissolution of copper in acid solutions

The dissolution of Cu in solutions of HNO₃ of different concentrations has been studied by the thermometric method. Starting from the initial temperature, T_i, the temperature—time curves exhibit an induction period followed by a rapid rise in temperature to a maximum value, T_m, attained t min after the start of the reaction. T_m increases and t decreases with increase of the acid concentration, M. ΔT (i.e.T_m ? T_i) and the reaction number (R.N. = (T_m ? T_i)/t) vary with M according to: ΔT = k(M ? M₀) and R.N. = A₁Mⁿ, where k, M₀, A₁ and n are constants.The effect of varying concentrations of HCl, H₂SO₄ and H₃PO₄ on the R.N. of Cu in 3.5 M HNO₃ was examined. Small amounts of these acids lower the R.N. (inhibition) due to the displacement of an active species on the surface of the metal by the anion of the acid. Larger additions of the acids accelerate dissolution. The concentration at which the added acid changes from corrosion-inhibitor to accelerator varies as HCl < H₂SO₄ < H₃PO₄. This sequence is considered to parallel the strength of adsorption of the respective anions. The results of experiments with salt additions confirm this view; all salts act only as dissolution-retardants. Calculations pertaining to the effect of the various ions on the R.N. support the conclusion that the dissolution of Cu in HNO₃ is autocatalytic in nature, and depends on the [H⁺]/[NO₃^?] ratio.Cu does not dissolve in air-free, cold HCl. Attack takes place, however, in the presence of KNO₃. Under these conditions attack is of the pitting- rather than the general type. The temperature rises suddenly after an incubation period, which decreases in length with increase of the amount of the added salt.Proof of the involvement of HNO₂ in the autocatalytic cycle of Cu dissolution in HNO₃ is obtained from the results of urea additions to the solution.     

Kinetics of calcium phosphate reduction by carbon

A fundamental study was made on the reduction of calcium phosphate by carbon. The mechanism of reduction was presented on applying different additions. Both silica and alumina increased the extent of reduction but with variable rates. The activation energies were calculated on the basis of first-order reactions. The phases formed during reduction were investigated by X-ray analysis.     

Comparative study of metomega chrome blue BBL, calcon, eriochrome blue S.E. and omega chrome black blue G as indicators in the complexometric titration of calcium and magnesium

Conclusion It can be concluded that for the determination of calcium and magnesium in mixtures two separate titrations are to be done in case of Calcon, Erio SE, BBG. Total calcium and magnesium was determined first and then calcium in a separate titration. Magnesium is found by differences whereas in the case of BBL, the mixture was first titrated for its calcium content, then the solution is made acidic with hydrochloric acid and then alkaline with ammonia buffer solution pH 10 and magnesium is determined in the same sample.It is also noticed that Erio SE can work in sodium hydroxide or potassium hydroxid medium as well as in diethyl amine; but its drawback is the red hue which can be overcome by the addition of a green component, whereas BBL is spoilt in sodium hydroxide or potassium hydroxide medium.In comparing the first 3 indicators (Calcon, Erio SE, BBG) we find that BBG is the best one in the titration of calcium and magnesium using either EDTA on Complexion IV, and its endpoint has no red hue as that found in Erio SE; also the recovery of calcium is quantitative in any ratio of magnesium.

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Vergleichende Untersuchung von Metomega Chromblau BBL, Calcon, EriochromblauS.E.und Omega-ChromschwarzblauG als Inidicatoren bei der komplexometrischen Bestimmung von Calcium und Magnesium