Individual extraction constants of some dicarbollylcobaltate anions in the water-nitrobenzene system

Individual extraction constants of nine dicarbollylcobaltate anions in the two-phase water-nitrobenzene system were determined radiometrically assuming that the changes of Gibbs energy of the transfer of the tetraphenylarsonium cation, Ph₄As⁺, and of the tetraphenylborate anion, BPh ₄ ^– , from the aqueous into the nitrobenzene phase are equal. The constants obtained by this method were correlated with Hansch's constants of hydrophobity.     

Oxygen incorporation in polyethylene implanted with 150 keV Sb+ ions

Samples of polyethylene (PE) loaded with carbon black up to 8 wt.% and implanted with 150 keV Sb⁺ ions to the doses from 2×10¹³–2×10¹⁵ cm^–2 were studied using standard Rutherford Back Scattering (RBS) technique. On the PE samples implanted to the doses above 2×10¹⁴ cm^–2, a considerable surface carbonization is observed. The measured parameters of the Sb depth profile are compared with theoretical TRIM estimations. The projected range is by 25% lower than the theoretical one and the range straggling is about twice of that predicted. The differences are explained by stepwise polymer degradation during the ion bombardment. Strong oxidation of the ion implanted polymers is also observed. The oxygen depth profiles from the sample surface up to the depth comparable with Sb⁺ ion range evolve from nearly uniform one for low ion doses to highly non-uniform one for doses above 1×10¹⁵ cm^–2. The total oxygen content in the sample surface layer 300 nm thick reaches a maximum for the doses of (1–2)×10¹⁴ cm^–2.On leave from Belorussian State University, 220050 Minsk, Belarus.The authors thank the member of electrostatic accelerator group at INP for help during RBS measurements. The work was partly (V.H. and J.K.) supported by the Internal Grant Agency of the Academy of Sciences of Czech Republic under the grant No. 14805 and by the Internal Grant Agency of the Ministry of Education of Czech Republic under the grant No. 1002 (V.., V.R., V.H. and J.K.). In the final stage, the work was also supported by the Grant Agency of Czech Republic under the grant No. 202/93/0121.     

On the toroidal distributions

The so called toroidal distributions were obtained using the method previously employed to derive the other decompositions of the electric type transition operator used in literature. Some aspects of toroidal distributions are discussed. The condition is given which has to be imposed on the decomposition generating function in order that the Siegert's theorem holds.