Synthesis and characterisation of coating polyurethane cationomers containing fluorine built-in hard urethane segments

Polyurethane cationomers were synthesised in the reaction of 4,4’-methylenebis(phenyl isocyanate) with polyoxyethylene glycol (M?= 2,000) or poly(tetrafluoroethyleneoxide-co-difluoromethylene oxide) α,ω-diisocyanate and N-methyl diethanolamine. Amine segments were built-in to the urethane-isocyanate prepolymer in the reaction with 1-bromobutane or formic acid, and then they were converted to alkylammonium cations. The obtained isocyanate prepolymers were then extended in the aqueous medium that yielded stable aqueous dispersions which were applied on the surfaces of test poly(tetrafluoroethylene) plates. After evaporation of water, the dispersions formed thin polymer coatings. ¹H, ¹³C NMR and IR spectral methods were employed to confirm chemical structures of synthesised cationomers. Based on ¹H NMR and IR spectra, the factors κ and α were calculated, which represented the polarity level of the obtained cationomers. The DSC, wide angle X-ray scattering and atom force microscopy methods were employed for the microstructural assessment of the obtained materials. Changes were discussed in the surface free energy and its components, as calculated independently according to the method suggested by van Oss–Good, in relation to chemical and physical structures of cationomers as well as morphology of coating surfaces obtained from those cationomers. Fluorine incorporated into cationomers (about 30%) contributed to lower surface free energy values, down to about 15 mJ/m². That was caused by gradual weakening of long-range interactions within which the highest share is taken by dispersion interactions.     

Σ- atoms and the ΣN interaction

It is shown that among four models of the Nijmegen baryon-baryon interaction only model F --which leads to a repulsive potential felt by the Σ hyperon inside the nucleus-- is consistent both with the analysis of Σ^- atoms and of the (K ^-,π) reactions. The Nijmegen models are used to determine the strong complex single-particle (s.p.) potential of Σ^-, and to calculate the strong-interaction shifts and widths of the lowest observed levels of Σ^- atoms. The results obtained with model F are in best agreement with the experimental data. Received: 15 January 2002 / Accepted: 14 March 2002     

Direct evaluation of baryon numbers of empty chiral bags

Goldstone and Jaffe proved using very general arguments that for a chiral bag surrounded by a Skyrme soliton, the baryon number of the Dirac vacuum inside the bag exactly cancels the (known) baryon number of the soliton outside. Their analysis applies to massless quarks. In order to obtain a formalism easier to generalize to massive quarks, we rederive the result for spherical bags by solving the Dirac equations for the inside of the bag and explicitly performing the required summations over the energy levels.     

Microscopic quadrupole and hexadecapole moments of rare earth nuclei

The theoretical calculations of multipole moments of even-even rare earth nuclei are presented. The potential energy surface is evaluated by the shell correction method. The condition ensuring the equality of the density distribution of the macroscopic liquid droplet part of the potential energy and the density generated by the single particle potential is added. A single particle Nilsson potential is used. New, less stiff potential surfaces versusε ₄ are obtained while the multipole moments calculated at the equilibrium deformations agree well with experimental data.     

Total and differential cross-sections for the pp\rightarrow pp\eta^\prime reaction near threshold

The -meson production in the reaction has been studied at excess energies of Q = 26.5, 32.5 and 46.6 MeV using the internal beam facility COSY-11 at the cooler synchrotron COSY. The total cross-sections as well as one angular distribution for the highest Q-value are presented. The excitation function of the near-threshold data can be described by a pure s-wave phase space distribution with the inclusion of the proton-proton final-state interaction and Coulomb effects. The obtained angular distribution of the -mesons is also consistent with pure s-wave production.Received: 11 August 2003, Revised: 14 November 2003, Published online: 6 April 2004PACS: 13.60.Le Meson production - 13.75.-n Hadron-induced low- and intermediate-energy reactions and scattering (energy GeV) - 13.85.Lg Total cross-sections - 25.40.-h Nucleon-induced reactions     

Michael addition to a chiral non-racemic 2-phosphono-2,3-didehydrothiolane S-oxide

The Michael addition of selected sulfur and nitrogen nucleophiles to a chiral non-racemic 2-phosphono-2,3-didehydrothiolane S-oxide is fully diastereoselective. The enantiomeric excesses of the adducts obtained could be determined by ³¹P NMR spectroscopy using (R)-(+)-tert-butyl(phenyl)phosphinothioic acid as a chiral solvating agent. The addition of thiophenol was monitored by ³¹P NMR spectroscopy which made it possible to observe the formation and evolution of the kinetic and thermodynamic adducts in the reaction mixture. The structures of both enantiomeric thiophenol adducts have been determined by X-ray analysis.     

Attenuation of high energy multi-hadron systems leptoproduced in nuclear matter

Attenuation of groups of high energy particles leptoproduced in nuclear matter is calculated in terms of parameters describing strongly interacting systems at the early stages of particle production: formation time of hadrons and cross-section for the intermediate state to interact inside the nucleus. It is argued that measurements of attenuation of multihadron systems can remove some ambiguities in determining these parameters.     

Thermal Decomposition of Triazine Herbicides. I. 1,2-(4-chloro-6-ethylamino-1,3,5-triazin-2-ylamino)-2-methylpropionitrile (cyanazine)

Cyanazine was taken as an example for investigations under the influence of different conditions on thermal decomposition of triazine herbicides. DSC measurements were carried out under atmospheric pressure and hermetically closed, under pressure 1.3 kPa. The influence of the pressure on the constant reaction rate of decomposition of cyanazine was discussed. It was also proved that the predicted reaction constant rates from isothermal and non-isothermal measurements are consistent. This revised version was published online in August 2006 with corrections to the Cover Date.