Concept of epitaxial silicon structures for edge illuminated solar cells

A new concept of edge illuminated solar cells (EISC) based on silicon epitaxial technique has been proposed. In this kind of photovoltaic (PV) devices, sun-light illuminates directly a p-n junction through the edge of the structure which is perpendicular to junction surface. The main motivation of the presented work is preparation of a working model of an edge-illuminated silicon epitaxial solar cell sufficient to cooperation with a luminescent solar concentrator (LSC) consisted of a polymer foil doped with a luminescent material. The technological processes affecting the cell I–V characteristic and PV parameters are considered.     

High-numerical-aperture microlens shape measurement with digital holographic microscopy

In this Letter, we introduce an algorithm that overcomes limitations in shape measurement by holographic microscopic methods in cases of micro-optical elements with high NA, such as microlenses. The presented algorithm provides a simple method for shape reconstruction from interferometrically measured phase. The algorithm is based on the analysis of local ray transition through the measured object. We develop algorithms for holographic configurations working in transmission and reflection. The accuracy of the developed algorithms is proved by experiments and extensive simulations. We present an experiment in a holographic Mach-Zehnder configuration where we have measured and successfully reconstructed the height distribution of spherical and cylindrical microlenses with NA up to 0.3.     

Secure sets and their expansion in cubic graphs

Consider a graph whose vertices play the role of members of the opposing groups. The edge between two vertices means that these vertices may defend or attack each other. At one time, any attacker may attack only one vertex. Similarly, any defender fights for itself or helps exactly one of its neighbours. If we have a set of defenders that can repel any attack, then we say that the set is secure. Moreover, it is strong if it is also prepared for a raid of one additional foe who can strike anywhere. We show that almost any cubic graph of order n has a minimum strong secure set of cardinality less or equal to n/2 + 1. Moreover, we examine the possibility of an expansion of secure sets and strong secure sets.     

Reprint of: Application of micro-thin-layer chromatography as a simple fractionation tool for fast screening of raw extracts derived from complex biological,pharmaceutical and environmental samples

The main goal of present paper is to demonstrate the separation and detection capability of micro-TLC technique involving simple one step liquid extraction protocols of complex materials without multi-steps sample pre-purification. In the present studies target components (cyanobacteria pigments, lipids and fullerenes) were isolated from heavy loading complex matrices including spirulina dried cells, birds’ feathers and fatty oils as well as soot samples derived from biomass fuel and fossils-fired home heating systems. In each case isocratic separation protocol involving less that 1 mL of one component or binary mixture mobile phases can be completed within time of 5–8 min. Sensitive detection of components of interest was performed via fluorescence or staining techniques using iodine or phosphomolybdic acid. Described methodology can be applied for fast fractionation or screening of whole range of target substances as well as chemo-taxonomic studies and fingerprinting of complex mixtures, which are present in raw biological or environmental samples.     

Assessment of coal and ash environmental impact with the use of gamma- and X-ray spectrometry

Gamma-ray spectrometry (GS), energy dispersive X-ray fluorescence (EDXRF) analysis methods and wavelength dispersive X-ray fluorescence (WDXRF) were applied for the studies of some coal components, e.g., sulphur, light and heavy metal element concentrations and naturally occurring radioactive isotope contents. Hundred fifty coal samples originating mostly from eight different coal mines from Upper Silesian Coal Basin and 150 samples of ash obtained from these coal samples in laboratory by total combustion at final temperature of 820°C, were analyzed. Such comparitive analyses can be helpful in selection of most suitable kind of coal for burning in electrical power and heat plants to minimize the environmental pollution.     

The complexity of some acyclic improper colourings

In this paper we will consider acyclic bipartition of the vertices of graphs, where acyclic means that the edges whose endpoints are in different parts of the partition induce a forest. We will require that the vertices belonging to the same partition induce graphs from particular class. We will search for acyclic bipartitions of cubic and subcubic graphs.     

Topotecan dynamics,tautomerism and reactivity—1H/13C NMR and ESI MS study

Topotecan (TPT) is in clinical use as an antitumor agent, hycamtin^?. Because of this, it requires both biologically and chemically useful information to be available. TPT acts by binding to the covalent complex formed by nicked DNA and topoisomerase I. This has a poisonous effect since inserted into the single‐strand nick and TPT inhibits its religation. We used NMR to trace TPT dynamics, tautomerism and solvolysis products in various solvents and conditions. Chemical stability was assessed in methanol and DMSO as compared to water, and the regioselectivity of the N‐ and O‐methylation was studied using various alkylating agents. The reaction products of quaternization of the nitrogen atom and methylation of the oxygen atom were characterized by means of ESI MS, ¹H/¹³C‐HMBC and ‐HSQCAD NMR. We have focused on the NMR characterization of TPT with an anticipation that its aggregation, tumbling properties and the intramolecular dipolar interactions will be a common feature for other compounds described in this article. These features can also be useful in tracing the interactions of this class of topoisomerase I (TopoI) poisons with DNA. Moreover, the results explained shed light on the recently disclosed problem of lack of stability of TPT in the heart tissue homogenate samples using the analytical assays developed for this class of compounds carried out in the presence of methanol. Copyright © 2010 John Wiley & Sons, Ltd.