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31.
The response of giant magnetoresistance (GMR) devices depends critically on the film microstructure, with parameters such
as layer thickness and interfacial abruptness being crucial. This paper presents results obtained using high resolution electron
microscopy (HREM), chemical mapping and atom probe microanalysis. Local variations in the magnetic properties are induced
by the microstructure and also when the films are patterned to form small elements. These lead to changes in the magnetization
reversal mechanism. Some results of the studies of the magnetization reversal carried out using in situ in Lorentz transmission electron microscopy (LTEM) magnetizing experiments are also included. 相似文献
32.
33.
Wigglesworth TJ Teixeira F Axthelm F Eisler S Csaba NS Merkle HP Meier W Diederich F 《Organic & biomolecular chemistry》2008,6(11):1905-1911
A series of block copolymers containing a dendronised cationic block for efficient DNA binding and a poly(ethylene glycol) block for encapsulation of the complex were synthesised in a modular fashion using a combination of click chemistry and ring-opening metathesis polymerisation. DNA binding experiments, investigated using gel electrophoresis, dynamic light scattering and transmission electron microscopy, showed that all polymers prepared in this study strongly complex DNA and self-assemble into polyion complex micelles with apparent hydrodynamic radii ranging from 20-120 nm at physiological pH (7.4). The in vitro transfection efficiency and toxicity of these potential non-viral vectors were also evaluated in HeLadouble dagger cells using plasmid DNA encoding for green fluorescent protein as the reporter gene. 相似文献
34.
We consider a chain of free electrons with periodically switched dimerization and study the entanglement entropy of a segment with the remainder of the system. We show that it evolves in a stepwise manner towards a value proportional to the length of the segment and displays in general slow oscillations. For particular quench periods and full dimerization an explicit solution is given. Relations to equilibrium lattice models are pointed out. 相似文献
35.
36.
Shi Shun AL Chernick ET Eisler S Tykwinski RR 《The Journal of organic chemistry》2003,68(4):1339-1347
Unsymmetrically substituted 1,3-butadiynes and 1,3,5-hexatriynes are synthesized in four steps from commercially available aldehydes or carboxylic acids. The key step in this process involves a Fritsch-Buttenberg-Wiechell rearrangement, in which an alkylidene carbenoid intermediate subsequently rearranges to the desired polyyne. This rearrangement proceeds under mild conditions, and it is tolerant of a range of functionalities. In general, the procedurally facile formation of the dibromoolefinic precursors, in combination with the effectiveness of the rearrangement step, makes this procedure an attractive alternative to traditional methods for di- and triyne synthesis that utilize palladium or copper catalysis. 相似文献
37.
The reactions of mercury(II) halides with the tetraphosphinitoresorcinarene complexes [P4M5X5], where M=Cu or Ag, X=Cl, Br, or I, and P4=(PhCH2CH2CHC6H2)4(O2CR)4(OPPh2)4 with R=C6H11, 4-C6H4Me, C4H3S, OCH2CCH, or OCH2Ph, have been studied. The reactions of the complexes with HgX2 when M=Ag and X=Cl or Br occur with elimination of silver(I) halide and formation of [P4Ag2X(HgX3)], but when M=Ag and X=I, the complexes [P4Ag4I5(HgI)] are formed. When M=Cu and X=I, the products were the remarkable capsule complexes [(P4Cu2I)2(Hg2X6)]. When M=Ag and X=I, the reaction with both CuI and HgI2 gave the complexes [P4Cu2I(Hg2I5)]. Many of these complexes are structurally characterized as containing mercurate anions weakly bonded to cationic tetraphosphinitoresorcinarene complexes of copper(I) or silver(I) in an unusual form of host-guest interaction. In contrast, the complex [P4Ag4I5(HgI)] is considered to be derived from an anionic silver cluster with an iodomercury(II) cation. Fluxionality of the complexes in solution is interpreted in terms of easy, reversible making and breaking of secondary bonds between the copper(I) or silver(I) cations and the mercurate anions. 相似文献
38.
The energy hypersurface for the system Li(H2O)–F(H2O) is investigated using the polarization model. A possible mechanism for the production of HF in this solution droplet is observed. 相似文献
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40.
Eisler DJ Less RJ Naseri V Rawson JM Wright DS 《Dalton transactions (Cambridge, England : 2003)》2008,(18):2382-2384
Dilithiation of 1,2-(PH2)2C6H4 with nBuLi followed by reaction with Sn(NMe2)2 in the presence of the Lewis base donor tmeda [Me2NCH2CH2NMe2] gives [(C6H4P2Sn)(Li.tmeda)2] , containing the phosphide-stabilised, 6pi stannylene dianion [C6H4P2Sn]2-. 相似文献