全文获取类型
收费全文 | 218篇 |
免费 | 2篇 |
国内免费 | 1篇 |
专业分类
化学 | 152篇 |
力学 | 7篇 |
数学 | 32篇 |
物理学 | 30篇 |
出版年
2022年 | 2篇 |
2014年 | 4篇 |
2013年 | 7篇 |
2012年 | 12篇 |
2011年 | 10篇 |
2010年 | 7篇 |
2009年 | 8篇 |
2008年 | 19篇 |
2007年 | 14篇 |
2006年 | 21篇 |
2005年 | 10篇 |
2004年 | 12篇 |
2003年 | 6篇 |
2002年 | 4篇 |
2001年 | 6篇 |
2000年 | 3篇 |
1999年 | 3篇 |
1997年 | 3篇 |
1996年 | 3篇 |
1994年 | 4篇 |
1993年 | 4篇 |
1989年 | 2篇 |
1986年 | 2篇 |
1981年 | 2篇 |
1978年 | 5篇 |
1972年 | 1篇 |
1970年 | 1篇 |
1969年 | 2篇 |
1968年 | 1篇 |
1967年 | 1篇 |
1966年 | 2篇 |
1965年 | 1篇 |
1964年 | 1篇 |
1963年 | 1篇 |
1961年 | 1篇 |
1959年 | 3篇 |
1958年 | 2篇 |
1939年 | 1篇 |
1938年 | 2篇 |
1937年 | 3篇 |
1933年 | 1篇 |
1931年 | 3篇 |
1930年 | 1篇 |
1929年 | 2篇 |
1926年 | 1篇 |
1919年 | 2篇 |
1918年 | 1篇 |
1917年 | 1篇 |
1909年 | 3篇 |
1900年 | 1篇 |
排序方式: 共有221条查询结果,搜索用时 31 毫秒
111.
We extend the computational method presented in [1] for tracking an interface immersed in a given velocity field to three spatial dimensions. The proposed method is particularly relevant to the simulation of unsteady free surface problems using the arbitrary Lagrangian–Eulerian framework, and has been constructed with two goals in mind: (i) to be able to accurately follow the interface; and (ii) to automatically maintain a good distribution of the grid points along the interface. The method combines information from a pure Lagrangian approach with information from an ALE approach. The new method offers flexibility in terms of how an “optimal” point distribution should be defined, and relies on the solution of two-dimensional surface convection problems. We verify the new method by solving model problems both in the single and multiple spectral element case, and we compare this method with other traditional alternatives. We have been able to verify first, second, and third order temporal accuracy for the new method by solving these three-dimensional model problems. 相似文献
112.
Dossmann Soldi-Lose H Afonso C Lesage D Tabet JC Uggerud E 《Angewandte Chemie (International ed. in English)》2012,51(28):6938-6941
A good fix: the structure and chemical reactivity of a reduced form of CO(2) bonded to magnesium, XMg(η(2)-O(2)C)(-), is reported. Upon reaction with water it loses CO, while it adds CH(3) upon reaction with alkyl halides, thereby signifying nucleophilicity of the carbon atom in XMg(η(2)-O(2)C)(-) in S(N)2 reactions. 相似文献
113.
Malinen E Waldeland E Hole EO Sagstuen E 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2006,63(4):861-869
Lithium formate electron paramagnetic resonance (EPR) dosimeters were irradiated using 60Co gamma-rays or fast neutrons to doses ranging from 5 to 20 Gy and investigated by EPR spectroscopy. Using a polynomial fitting procedure in order to accurately analyze peak-to-peak line widths of first derivative EPR spectra, dosimeters irradiated with neutrons had on average 4.4+/-0.9% broader EPR resonance lines than gamma-irradiated dosimeters. The increase in line width was slightly asymmetrical. Computer simulated first derivative polycrystalline EPR spectra of a *CO2- radical gave very good reconstructions of experimental spectra of irradiated dosimeters. The spectrum simulations could then be used as a tool to investigate the line broadening observed following neutron irradiation. It was shown that an increase in the simulated Lorentzian line width could explain both the observed line broadening and the asymmetrical effect. The ratio of the peak-to-peak amplitude of first derivative EPR spectra obtained at two different microwave powers (20 and 0.5 mW) was 7.8+/-1.2% higher for dosimeters irradiated with neutrons. The dependence of the spectrum amplitude on the microwave power was extensively investigated by fitting observations to an analytical non-linear model incorporating, among others, the spin-lattice (T1) and spin-spin (T2) relaxation times as fitting parameters. Neutron irradiation resulted in a reduction in T(2) in comparison with gamma-irradiation, while a smaller difference in T1 was found. The effects observed indicate increased local radical density following irradiation using high linear energy transfer (LET) neutrons as compared to low LET gamma-irradiation. A fingerprint of the LET may thus be found either by an analysis of the line width or of the dependence of the spectrum amplitude on the microwave power. Lithium formate is therefore a promising material for EPR dosimetry of high LET radiation. 相似文献
114.
An atmospheric molding protocol has been used to prepare an ionic methacrylate-based copolymer sample support chips for MALDI (pMALDI)-MS by targeting selected groups of various monomers copolymerized during molding, namely, carboxy, sulfo, dimethylalkyamino, and trimethylalkylammonium groups. The new disposable array chips provide analyte-oriented enhancement of protein adsorption to the modified substrates without requiring complicated surface coating or derivatization. The MALDI-MS performance of the new ionic copolymer chips was evaluated for lysozyme, beta-lactoglobulin A, trypsinogen and carbonic anhydrase I using washing with solutions prepared in pH or ionic strength steps. On cationic chips, the proteins are washed out at pH lower than their p/ values, and on anionic chips at pH higher than their p/ values. The ability of the microfabricated pMALDI chip set to selectively adsorb different proteins from real samples and to significantly increase their MS-signal was documented for the transmembrane photosystem I protein complex from the green alga Chlamydomonas reinhardtii. The proteins were almost exclusively adsorbed according to calculated pI values and grand average of hydropathy (GRAVY) indexes. The new disposable chips reduce manipulation times and increase measurement sensitivity for real-world proteomic samples. The simple atmospheric molding procedure enables additional proteomic operations to be incorporated on disposable MALDI-MS integrated platforms. 相似文献
115.
116.
Laerdahl JK Civcir PU Bache-Andreassen L Uggerud E 《Organic & biomolecular chemistry》2006,4(1):135-141
The gas phase reactions between HF and the protonated alkyl fluorides MeFH+, EtFH+, Pr(i)FH+, and Bu(t)FH+ have been studied using ab initio methods. The potential energy profiles for both nucleophilic substitution (S(N)2) and elimination (E2) pathways have been investigated. Both backside Walden inversion and frontside nucleophilic substitution reaction profiles have been generated. Backside substitution is very favourable, but shows relatively little variation with the alkyl group. Frontside substitution reaction barriers are only slightly higher than the barrier for backside substitution for HF + MeFH+, and the difference in barrier heights for frontside and backside displacement seems negligible for the larger alkyl groups. Reaction barrier trends have been analysed and compared with the results of similar studies of the H2O/ROH2+ and NH3/RNH3+ systems (R = Me, Et, Pr(i), and Bu(t)). Compared to the two other classes, protonated fluorides have extreme structures which, with the exception of the Me substrate, are weakly bound complexes between an alkyl cation and HF. The results nourish the idea that nucleophilic substitution reactions are better understood in view of competition between frontside and backside substitution than from the traditional S(N)1/S(N)2 perspective. 相似文献
117.
Attygalle AB Kharbatia N Bialecki J Ruzicka J Svatos A Stauber EJ 《Rapid communications in mass spectrometry : RCM》2006,20(15):2265-2270
The ion observed at m/z 145 when product ion spectra of iodobenzoate anions are recorded using ion-trap mass spectrometers corresponds to the adduct ion [I(H(2)O)](-). The elements of water required for the formation of this adduct do not originate from the precursor ion but from traces of moisture present in the helium buffer gas. A collision-induced decomposition (CID) spectrum recorded from the [M-H](-) ion (m/z 251) derived from 3-iodo[2,4,5,6-(2)H(4)]benzoic acid also showed an ion at m/z 145. This observation confirmed that the m/z 145 is not a product ion resulting from a direct neutral loss from the carboxylate anion. (79)Bromobenzoate anions produce similar results showing an ion at m/z 97 for [(79)Br(H(2)O)](-). The ion-molecule reaction observed here is unique to ion-trap mass spectrometers since a corresponding ion was not observed under our experimental conditions in spectra recorded with in-space tandem mass spectrometers such as triple quadrupole or quadrupole time-of-flight instruments. 相似文献
118.
Ohne Zusammenfassung 相似文献
119.
120.
Einar Biilmann I. Krarup F. Auerbach E. Smolczyk S. Bodforss H. Lund G. E. Cullen N. Bjerrum S. P. L. Sørensen Margarethe Sørensen K. Linderstrøm-Lang J. H. Blom E. Langseth Jensen E. Schreiner L. Ebert St. Veibel H. Baggesgaard-Rasmussen S. A. Schou S. Tovberg-Jensen Vera Lester O. M. Henriques R. Schaefer F. Schmidt E. Mislowitzer C. W. G Hetterschy J. Hudig R. Shoji W. Sturm P. F. Sharp F. H. Mac Dougall 《Analytical and bioanalytical chemistry》1931,83(1-2):45-59