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11.
Abstract Ribozymes that distinguish a single base change in RNA were synthesized and used to specifically cleave c-Ha-ras messenger RNA. Using phosphorothioate containing oligonucleotide substrates, we have shown that Mg2+ binds to the pro-R oxygen of the phosphate and that the RNA cleavage reaction occurs via an in-line mechanism. Oligoribonucleotides containing a modified nucleoside are described. 相似文献
12.
Katsumi Katoh Seiichiro Nagayama Eiko Higashi Katsuyuki Nakano 《Journal of Thermal Analysis and Calorimetry》2013,113(3):1239-1244
In the hydrosilylation of 1,6-divinyl(perfluorohexane) (FDV) with trichlorosilane (TCS) in the presence of catalytic chloroplatinic acid (Pt-Cat) under an air atmosphere (0.99 MPa), a runaway reaction accompanied by a severe pressure release occurred when Fe2O3 was present as an impurity in the system. In this study, we investigated the mechanism of action of Fe2O3 on this hydrosilylation by monitoring the thermal behavior of TCS/FDV/Pt-Cat/Fe2O3 mixtures with various compositions, using an accelerating rate calorimeter (ARC). In the case of TSC/FDV/Pt-Cat, a typical hydrosilylation composition in the industrial process, heat release, possibly due to hydrosilylation, began at 90 °C. On the other hand, for TCS/FDV/Pt-Cat/Fe2O, the heat release due to hydrosilylation was hardly observed, but abrupt heat and pressure releases occurred at higher temperatures (>170 °C). Like TCS/FDV/Pt-Cat/Fe2O3, TCS/FDV, which contain neither Pt-Cat nor Fe2O3, released heat and pressure at high temperatures (>210 °C), while the heat and pressure release rates were comparatively low. From these results, the runaway reaction may occur when hydrosilylation is prevented, and Fe2O3 behaves as a negative catalyst for hydrosilylation. In the FT-IR spectrum of TCS/FDV/Pt-Cat/Fe2O3 after heating, an absorption peak at approximately 1,710 cm?1, which may be attributed to a carbonyl group, was observed. Thus, it is considered that the runaway reaction observed during the hydrosilylation results from the action of Fe2O3 as a negative catalyst for hydrosilylation as well as as an oxidation catalyst for the by-product generated from the reaction between TCS and FDV. 相似文献
13.
Katsumi Katoh Nobuyuki Saeki Eiko Higashi Yuki Hirose Masahiko Sugimoto Katsuyuki Nakano 《Journal of Thermal Analysis and Calorimetry》2013,113(3):1275-1279
As a fundamental study on the development of dismantlable adhesives containing chemically reactive materials, the thermal behavior and dismantlability of an epoxy adhesive containing one of the twenty-seven inorganic salts (chlorides, perchlorates, and nitrates) were observed. In the thermal behavior measured by the differential scanning calorimetry, epoxy adhesives with inorganic salts containing iron, copper, zinc, and aluminum cations released heats of reaction at lower temperatures than the adhesive alone or the adhesives with other inorganic salts. Since such inorganic salts were considered to be effective candidates as fillers in dismantlable adhesives, the adhesion strengths of their mixtures with the adhesive were observed after heat aging at 270 °C for 30 min. The results showed that both chloride and perchlorate salts specifically decreased the adhesion strength after heating. On the other hand, the effect of nitrate salts on the decrease in adhesion strength was low in comparison with the chloride and perchlorate salts. 相似文献
14.
Dr. Ming-Shui Yao Prof. Jia-Jia Zheng Ai-Qian Wu Prof. Gang Xu Sanjog S. Nagarkar Gen Zhang Masahiko Tsujimoto Prof. Shigeyoshi Sakaki Prof. Satoshi Horike Prof. Kenichi Otake Prof. Susumu Kitagawa 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(1):178-182
Single-ligand-based electronically conductive porous coordination polymers/metal–organic frameworks (EC-PCPs/MOFs) fail to meet the requirements of numerous electronic applications owing to their limited tunability in terms of both conductivity and topology. In this study, a new 2D π-conjugated EC-MOF containing copper units with mixed trigonal ligands was developed: Cu3(HHTP)(THQ) (HHTP=2,3,6,7,10,11-hexahydrotriphenylene, THQ=tetrahydroxy-1,4-quinone). The modulated conductivity (σ≈2.53×10−5 S cm−1 with an activation energy of 0.30 eV) and high porosity (ca. 441.2 m2 g−1) of the Cu3(HHTP)(THQ) semiconductive nanowires provided an appropriate resistance baseline and highly accessible areas for the development of an excellent chemiresistive gas sensor. 相似文献
15.
Ming‐Shui Yao Jia‐Jia Zheng Ai‐Qian Wu Gang Xu Sanjog S. Nagarkar Gen Zhang Masahiko Tsujimoto Shigeyoshi Sakaki Satoshi Horike Kenichi Otake Susumu Kitagawa 《Angewandte Chemie (International ed. in English)》2020,59(1):172-176
Single‐ligand‐based electronically conductive porous coordination polymers/metal–organic frameworks (EC‐PCPs/MOFs) fail to meet the requirements of numerous electronic applications owing to their limited tunability in terms of both conductivity and topology. In this study, a new 2D π‐conjugated EC‐MOF containing copper units with mixed trigonal ligands was developed: Cu3(HHTP)(THQ) (HHTP=2,3,6,7,10,11‐hexahydrotriphenylene, THQ=tetrahydroxy‐1,4‐quinone). The modulated conductivity (σ≈2.53×10?5 S cm?1 with an activation energy of 0.30 eV) and high porosity (ca. 441.2 m2 g?1) of the Cu3(HHTP)(THQ) semiconductive nanowires provided an appropriate resistance baseline and highly accessible areas for the development of an excellent chemiresistive gas sensor. 相似文献
16.
17.
Eiko Yasui 《Tetrahedron letters》2009,50(33):4762-4765
We have developed a novel method for the synthesis of 3,4-diarylpyrrole-2,5-dicarboxylates via α-diazo esters, which are easily obtained from phenylalanine derivatives. Utilizing this method, intermediates of bioactive compounds having the structure of 3,4-diarylpyrrole-2,5-dicarboxylates were synthesized. 相似文献
18.
Yoshihiro Takebayashi Hiroyuki Hotta Atsushi Shono Katsuto Otake Kiwamu Sue Satoshi Yoda Takeshi Furuya 《Journal of solution chemistry》2009,38(5):545-555
Acid-base equilibria between 2,5-dichlorophenol (DCP) and various bases (LiOH, NaOH, and KOH) were studied in ambient to supercritical
methanol, by measuring the absorption spectrum of DCP at alkali metal hydroxide molalities ranging up to 10 mmol⋅kg−1, at temperatures up to 250 °C and a pressure of 25.0 MPa. The spectrum was deconvoluted into contributions for the acidic
(HA) and basic (A−) forms of DCP, taking into account a blue shift of the phenolate (A−) spectrum due to the effect of ion pairing with an alkali metal cation. Degrees of dissociation of DCP determined from the
spectra suggested that the dissociation constant of DCP has a maximum around 150 °C, whereas that of KOH decreases with temperature.
The phenolate-alkali metal ion pairing was examined from the peak shift of the phenolate spectrum in the presence of Li+, Na+, and K+. A smaller cation radius and higher temperature (thus a lower dielectric constant for methanol) give rise to stronger electrostatic
interaction in the ion pair. The basicities of the alkali metal hydroxides in supercritical methanol were compared using DCP
as an indicator, and were shown to follow the order LiOH < NaOH ≤ KOH. This order is the same as that for the catalytic effect
of alkali metal hydroxides on the methylation of phenol in supercritical methanol (Takebayashi et al.: Ind. Eng. Chem. Res.
47:704–709, 2008).
Electronic Supplementary Material The online version of this article () contains supplementary material, which is available to authorized users. 相似文献
19.
Takamitsu Otake Yoshie Aoyagi Takashi Yarita Masahiko Numata 《Analytical and bioanalytical chemistry》2010,397(6):2569-2577
Fish certified reference material (CRM), NMIJ CRM 7404-a, for the analysis of polychlorinated biphenyls (PCBs) and organochlorine
pesticides (OCPs) was developed by the National Metrology Institute of Japan, part of the National Institute of Advanced Industrial
Science and Technology. Fish samples (Japanese seabass) used for the preparation of the CRM were collected from Tokyo Bay,
and the edible part was freeze-dried, pulverized, sieved, homogenized, and sterilized by γ-irradiation. This sample is in
the form of a powder comprising approximately 10 g stored in a brown glass bottle. The certification was carried out using
multiple analytical methods such as pressurized liquid extraction, Soxhlet extraction, saponification, and homogenization
to ensure the reliability of analytical results; the certified values of target PCBs (PCB 28, PCB 70, PCB 105, PCB 153, and
PCB 170) and OCPs (trans-nonachlor, dieldrin, p,p′-DDE, p,p′-DDT, and p,p′-DDD) were 1.05–14.0 μg kg−1 and 1.57–18.0 μg kg−1 for PCBs and OCPs, respectively. This is the first fish powder CRM in which PCBs and OCPs were determined by isotope dilution
mass spectrometry. 相似文献
20.
T. Ino Y. ArimotoT. Yoshioka K. MishimaK. Taketani S. MutoH.M. Shimizu H. KiraY. Sakaguchi T. OkuK. Sakai T. ShinoharaJ. Suzuki H. OtonoH. Oide S. YamashitaS. Imajo H. FunahashiM. Yamada Y. IwashitaM. Kitaguchi M. HinoZ. Suzuki T. SanukiT. Seki K. HirotaK. Ikeda H. SatoY. Otake H. OhmoriT. Morishima T. Shima 《Physica B: Condensed Matter》2011,406(12):2424-2428
We measured the neutron beam polarization of the BL05/NOP (Neutron Optics and Physics) beamline at J-PARC with an accuracy of less than 10−3 using polarized 3He gas as a neutron spin analyzer. Precise polarimetry of the neutron beam is necessary to understand the beamline optics as well as for the asymmetry measurements of the neutron beta decay, which are planned in this beamline. 相似文献