全文获取类型
收费全文 | 440篇 |
免费 | 18篇 |
专业分类
化学 | 383篇 |
晶体学 | 2篇 |
力学 | 2篇 |
数学 | 6篇 |
物理学 | 65篇 |
出版年
2022年 | 4篇 |
2021年 | 4篇 |
2020年 | 9篇 |
2019年 | 8篇 |
2018年 | 4篇 |
2016年 | 6篇 |
2015年 | 11篇 |
2014年 | 10篇 |
2013年 | 15篇 |
2012年 | 18篇 |
2011年 | 30篇 |
2010年 | 11篇 |
2009年 | 17篇 |
2008年 | 20篇 |
2007年 | 13篇 |
2006年 | 28篇 |
2005年 | 15篇 |
2004年 | 12篇 |
2003年 | 11篇 |
2002年 | 12篇 |
2001年 | 9篇 |
2000年 | 12篇 |
1999年 | 8篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1994年 | 6篇 |
1993年 | 3篇 |
1992年 | 7篇 |
1991年 | 4篇 |
1990年 | 8篇 |
1989年 | 4篇 |
1988年 | 9篇 |
1987年 | 12篇 |
1986年 | 6篇 |
1985年 | 16篇 |
1984年 | 11篇 |
1983年 | 6篇 |
1982年 | 8篇 |
1981年 | 7篇 |
1980年 | 6篇 |
1979年 | 6篇 |
1978年 | 6篇 |
1977年 | 6篇 |
1976年 | 5篇 |
1975年 | 3篇 |
1968年 | 2篇 |
1967年 | 3篇 |
1966年 | 5篇 |
1929年 | 2篇 |
1927年 | 2篇 |
排序方式: 共有458条查询结果,搜索用时 15 毫秒
81.
Sitafloxacin (STFX) hydrate is a non-stoichiometric hydrate. The hydration state of STFX hydrate varies non-stoichiometrically depending on the relative humidity and temperature, though X-ray powder diffraction (XRPD) of STFX hydrate was not affected by storing at low and high relative humidities. The detailed properties of crystalline water of STFX hydrate were estimated in terms of hygroscopicity, thermal analysis combined with X-ray powder diffractometry, crystallography and density functional theory (DFT) calculation. STFX hydrate changed the water contents continuously and reversibly from an equivalent amount of dihydrate through that of sesquihydrate depending on the relative humidity at 25°C. Thermal analysis and X-ray powder diffraction (XRPD) simultaneous measurement also revealed that STFX hydrate dehydrated into a hydrated state equivalent to monohydrate by heating up to 100°C, whereas XRPD patterns were slightly affected. This indicated that the crystal structure of STFX hydrate was retained at the dehydration level of monohydrate. Single-crystal X-ray structural analysis showed that two STFX molecules and four water molecule sites were contained in an asymmetric unit. STFX molecules formed a channel structure where water molecules were included. At the partially dehydrated state, at least two of four water molecules were considered to be disordered in occupancy and/or coordinates. Insight into the crystal structure of STFX hydrate stored at low and high relative humidities and geometry of the hydrogen bond were helpful to estimate the origin of non-stoichiometric hydration of STFX hydrate. 相似文献
82.
A novel method for the determination of residual solvents in pharmaceuticals by thermal desorption (TD)-GC/MS has been established. A programmed temperature pyrolyzer (double shot pyrolyzer) is applied for the TD. This method does not require any sample pretreatment and allows very small amounts of the sample. Directly desorbed solvents from intact pharmaceuticals (ca. 1 mg) in the desorption cup (5 mm x 3.8 mm i.d.) were cryofocused at the head of a capillary column prior to a GC/MS analysis. The desorption temperature was set at a point about 20 degrees C higher than the melting point of each sample individually, and held for 3 min. The analytical results using 7 different pharmaceuticals were in agreement with those obtained by direct injection (DI) of the solution, followed by USP XXIII. This proposed TD-GC/MS method was demonstrated to be very useful for the identification and quantification of residual solvents. Furthermore, this method was simple, allowed rapid analysis and gave good repeatability. 相似文献
83.
Sachiyo Terada 《European Journal of Combinatorics》2000,21(8):1073
We show that for the split and non-split extensions ofFq2bySL (2, q) (q = 2e,e ≥ 3), the group association schemes have the same parameters but are not isomorphic. For the split and non-split extensions ofFq2by the standard Borel subgroup of SL(2,q ) (q = 2e, e ≥ 3), the group association schemes are shown to be isomorphic. 相似文献
84.
85.
86.
Yoshikazu Shizuri Jiro Ohtsuka Seiji Kosemura Yukimasa Terada Shosuke Yamamura 《Tetrahedron letters》1984,25(48):5547-5550
Some macrocyclic diterpenes derived from euphohelioscopin A and euphornin have been stereoselectively converted into the jatropholane- and daphnane-type compounds and the known tricyclic compound which has been treated with phCOCl - pyridine to afford euphohelionone, the new type of diterpene isolated from euphorbia helioscopia L. 相似文献
87.
Yosuke Kawai Toshinobu Hondo Kirk R. Jensen Michisato Toyoda Kentaro Terada 《Journal of the American Society for Mass Spectrometry》2018,29(7):1403-1407
Two different types of data acquisition methods, “averaging mode” and “ion-counting mode”, have been used in a time-of-flight (TOF) mass spectrometry. The most common method is an averaging mode that sums waveform signals obtained from each flight cycle. While it is possible to process many ions arriving at the same TOF in one flight cycle, low-abundance ions are difficult to measure because ion signals are overwhelmed by noises from the detection system. An ion-counting mode is suitable for the detection of such low-concentration ions, but counting loss occurs when two or more ions arrive at the detector within the dead time of the acquisition system. In this study, we introduce a technique that combines two methods to measure target ions with a high concentration difference, i.e., averaging mode and ion-counting mode are used simultaneously for high abundant and trace ions, respectively. By processing waveforms concurrently during data acquisition, one can choose to analyze either or both types of data to achieve a highly quantitative mass spectrum over a wide range of sample concentrations. The result of the argon isotope analysis shows that this method provides a more accurate determination of the isotope ratio compared to averaging mode alone at one-twentieth of the analysis time required by ion-counting alone. 相似文献
88.
T. Ito Y. Yoshioka T. Sonoda Y. Yoshihashi E. Yonemochi K. Terada 《Journal of Thermal Analysis and Calorimetry》2006,85(3):731-739
Glass
ampoule breakage during the freeze-drying process was prevented by the addition
of sodium chloride to the formulation of lyophilization products of sodium
thiopental. In order to clarify the ampoule breakage prevention mechanism,
the physicochemical behavior of the freeze-drying process was monitored by
simultaneous XRD-DSC measurements and thermal mechanical analysis (TMA). During
the freezing process of formulated solution, the smaller heat of fusion of
crystallized ice with the addition of sodium chloride was observed in comparison
to that without sodium chloride. Although a greater amorphous portion remained,
a higher crystal habit of hexagonal ice was reproducibly observed in the XRD
patterns with the addition of sodium chloride during the freezing process.
In the measurement of TMA, the scattering of the thermal expansion rate of
formulated solution was significantly reduced by the addition of sodium chloride.
These observations indicated that the addition of sodium chloride minimized
the scattering of the thermal expansion rate and might be a cause for the
inhibition of glass ampoule breakage during the freeze-drying process. 相似文献
89.
Terada A Yuasa A Tsuneda S Hirata A Katakai A Tamada M 《Colloids and surfaces. B, Biointerfaces》2005,43(2):99-107
Surface-modified polyethylene (PE) membrane sheets were prepared by the radiation-induced graft polymerization (RIGP) of an epoxy-group-containing monomer, glycidyl methacrylate (GMA). The epoxy ring of GMA was opened by introducing diethylamine (DEA) or sodium sulfite (SS). We examined the properties of these sheets by measuring the amount of grafting polymer, surface roughness and membrane potential, and also investigated the adhesion of five Gram-negative bacteria, Escherichia coli, Pseudomonas aeruginosa, Pseudomonas putida, Pseudomonas fluorescens and Paracoccus denitrificans, onto the prepared sheet surfaces. A linear relationship between the degree of grafting (dg) and surface roughness was observed. Moreover, membrane potential was dependent on the amount of DEA or SS as the ionizable group. These results indicate that RIGP enables the control of the physicochemical properties of such a sheet surface by adjusting dg and the subsequent conversion of functional groups. A batch test on bacterial adhesion onto the sheets clarified that the DEA-containing sheet (DEA sheet) exhibited an adhesion rate constant, k, significantly greater than those of other types of sheet. Clearly, the adhesion rate constant of the DEA sheet increased with dg, indicating that electrostatic interaction is the most decisive factor for bacterial adhesion when it works as an attractive force. Furthermore, the densities of bacteria adhering onto the GMA-containing sheet (GMA sheet) and the SS-containing sheet (SS sheet) were almost the same as that onto a PE sheet, whereas that onto a DEA sheet significantly increased. Thus, the introduction of the GMA- and SS-containing graft chain did not have much influence on bacterial adhesion onto the surfaces, supporting the conclusion that the promotion of bacterial adhesion onto the GMA and SS sheets was due to an increase in surface area resulting from RIGP. Moreover, the scanning electron microscopy images of the sheet surfaces indicate that the conditions and morphologies of initial bacterial adhesion are dependent on surface properties, particularly membrane potential. 相似文献
90.
A simple method is presented for the determination of arsenic in rocks and in sediments by neutron activation. After irradiating
a sample it is, without any other treatment, directly heated in condensed phosphoric acid containing sodium chloride or sodium
bromide to evolve arsenic as arsenic(III) chloride or bromide. The distillate is absorbed in distilled water, in which arsenic
is later precipitated in elementary form by adding hypophosphite to the solution. From arsenite, arsenic(III) oxide, arsenate
and arsenic(III) sulphide, arsenic chloride can be evolved with NaCl-CPA reagent, but elementary arsenic and arsenic(V) oxide
do not react with it. However, metallic arsenic is found to react with KIO3-NaCl-CPA and arsenic(V) oxide with the NaBr-CPA, both both evolving arsenic(III) chloride or bromide. Therefore, successive
distillations, the first with NaCl-CPA and the second with NaBr-CPA, give a satisfactory means of differential determination
of arsenic(III) and arsenate as well as arsenic(V) oxide. For the elementary arsenic a problem still now remains. The chemical
recovery of carrier goes well beyond 95%.
Part of this work was performed at the Research Reactor Institute, Kyoto University. 相似文献