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21.
Summary The spectral change of a small molecule (S) induced by addition of a large molecule (P) was examined theoretically and experimentally, assuming that the interaction betweenS andP follows theLangmuir adsorption isotherm. It was found that intermolecular binding constants could be determined accurately and conveniently by extrapolation to zero of two simple graphic relations, namely, the observed molar extinction coefficient ofS in the presence ofP versus the ratio of (the concentration ofS/the concentration ofP), and of the former versus the reciprocal value of the latter. This spectrophotometric method was applied to the binding of bovine serum albumin and Ponceau3 R and of bovine serum albumin and HABA at pH 7.0. The results obtained by this method were comparable with those obtained by equilibrium dialysis or by conventional spectrophotometric method.
Zusammenfassung Unter der Annahme, daß dieLangmuirsche Absorptionsisotherme auch bei der Assoziation hoch-(HMV) und niedermolekularer Verbindungen (NMV) gilt, wurden die Bindungskonstanten bestimmt. Es wurden die spektralen Änderungen in der UV-Absorption der NMV bei Zusatz verschiedener HMV-Mengen gemessen. Die Bindungskonstanten lassen sich durch Kombination zweier graphischer Darstellungen exakt und einfach bestimmen: erstens aus der Beziehung zwischen dem molaren Extinktionskoeffizienten der NMV in Anwesenheit verschiedener HMV-Konzentrationen und dem Konzentrationsverhältnis von NMV zu HMV und zweitens aus dem Zusammenhang der molaren Extinktionskoeffizienten mit den reziproken Werten des oben genannten Konzentrationsverhältnisses. Mit dieser neuen Methode wurden die Bindungskonstanten bei ph 7.0 von Rinderserumalbumin und Ponceau 3 R bzw. HABA berechnet und mit den durch andere Methoden bestimmten Konstanten verglichen. Die Werte stimmen mit denen aus der Dialysemethode und aus der üblichen spektralphotometrischen Methode überein.
  相似文献   
22.
A water-insoluble chelating material, p-dimethylaminobenzylidenerhodanine on silica gel (DMABR—SG) is described for preconcentration of trace amounts of silver(I), gold(III) and palladium(II) from water samples. Radioactive tracers (110mAg and 195Au) were used to study the behavior of silver and gold; palladium was monitored spectrophotometrically as its 1-(2-pyridylazo)naphthol complex in chloroform. In batch experiments, silver was quantitatively retained on the DMABR—SG at acidities ranging from 1.7 M to pH 5, and gold from 3 M to pH 5; equilibrium was achieved within 1 min for both elements. From sea water, silver ion was completely retained at pH 1.0–6.5 and gold ion at pH 1.0–3.5. In the case of palladium, shaking for about 20 min was required for quantitative retention at pH 1.0–5.0 for aqueous solution and at pH 1.0–7.0 for sea water. The chelating capacity of the DMABR—SG was 23 μmol Ag, 11 μmol Au and 11 μmol Pd per g. Quantitative recovery of silver and gold on DMABR—SG columns from sea water was achieved at higher flow rates (1–2 l h-1 and 2–3 l h-1, respectively) than with other chelating resins, e.g., Chelex 100, palladium required slower flow rate (150 ml h-1). Silver retained on the DMABR—SG column was completely eluted with 20 ml of 2.5% sodium thiosulfate solution but palladium remained on the column. Silver, gold and palladium were quantitatively eluted with 20 ml of 0.1% thiourea in 0.1 M hydrochloric acid.  相似文献   
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A catalytic enantioselective synthesis of β-amino secondary amides was achieved using vinyl azides as the enamine-type nucleophile and chiral N-Tf phosphoramide as the chiral Brønsted acid catalyst through a five-step sequential transformation in one pot. The established sequential transformation involves an enantioselective [4+2] cycloaddition reaction of vinyl azides with N-acyl imines as the key stereo-determining step that is efficiently accelerated by a chiral N-Tf phosphoramide catalyst in a highly enantioselective manner in most cases. Further generation of the iminodiazonium ion intermediate through ring opening of the cycloaddition product and subsequent skeletal rearrangement involving Schmidt-type 1,2-aryl group migration followed by recyclization of the resulting nitrilium ion were also initiated by the same acid catalyst. Final acid hydrolysis of the recyclized products in the same pot gave rise to enantioenriched β-amino amides through C−C bond formation at the α-position of the secondary amides.  相似文献   
26.
The effect of amines on the selective bromination of some β-substituted-2-butenoic esters is described. The bromination of methyl (Z)-4-t-butyldiphenylsilyloxy-3-methylbutenoate 2 in the presence of DIPEA (N, N-diisopropylethylamine) and the successive treatment of the obtained dibromide with potassium t-butoxide afford the desired Z bromide selectively. But the corresponding E bromide forms exclusively when 2, 6-di-t-butyl-4-methylpyridine is used in the bromination.  相似文献   
27.
Multi-step cascade reactions of O-propargylic oximes with isocyanates were carried out in the presence of copper catalysts to afford the corresponding 1,6-dihydropyrimidines in good yields. The multi-step reactions consisted of a 2,3-rearrangement, a [3+2] cycloaddition, decarboxylative ring opening involving a 1,4-hydrogen shift, and a 6π-electrocyclization.  相似文献   
28.
The 2:1 charge-transfer (CT) salts (1(2).FeBr(4) and 1(2).GaBr(4)) of ethylenedithiotetrathiafulvalenoquinone-1,3-dithiolemethide (1) with FeBr(4)(-) and GaBr(4)(-) counteranions were obtained as needle crystals, whose structures are almost the same as each other. The 1 molecules form a one dimensionally stacked column with alternation of their molecular axis direction, while the counteranions are aligned in parallel with the 1-stacked columns with the direction of their distorted-tetrahedral geometry maintained. The room-temperature electrical conductivities measured on the single crystals of 1(2).FeBr(4) and 1(2).GaBr(4) were 4.6 and 2.1 S cm(-1), respectively. From the temperature dependences of their electrical conductivities in both cases the electrical conducting properties were metallic between ca. 170 and 300 K, but below ca. 170 K converted to be semiconducting and continued till 5 K, although the activation energies are very small (4-10 meV). For 1(2).FeBr(4) very weak and antiferromagnetic interaction occurred between the d spins of FeBr(4)(-) ions in the temperature range of ca. 1-300 K. However, below ca. 15 K the ferromagnetic interaction was reversely preferential possibly by participation of the pi spin of 1.  相似文献   
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On the basis of the UV absorption spectra of the anti,cisoid alternating oligosilanes, the first experimental clear-cut evidence was presented for the generally accepted idea that the sigma conjugation in polysilanes does not effectively extend through a tetrasilane fragment with a small dihedral angle such as a cisoid turn.  相似文献   
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