首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   459篇
  免费   23篇
  国内免费   6篇
化学   291篇
晶体学   4篇
力学   55篇
数学   40篇
物理学   98篇
  2024年   1篇
  2023年   2篇
  2022年   19篇
  2021年   20篇
  2020年   26篇
  2019年   37篇
  2018年   38篇
  2017年   29篇
  2016年   24篇
  2015年   20篇
  2014年   38篇
  2013年   41篇
  2012年   49篇
  2011年   51篇
  2010年   28篇
  2009年   14篇
  2008年   13篇
  2007年   14篇
  2006年   6篇
  2005年   2篇
  2004年   5篇
  2003年   4篇
  2002年   2篇
  1996年   3篇
  1970年   1篇
  1968年   1篇
排序方式: 共有488条查询结果,搜索用时 955 毫秒
451.
We associate a graph Γ+(R) to a ring R whose vertices are nonzero proper right ideals of R and two vertices I and J are adjacent if I+J=R. Then we try to translate properties of this graph into algebraic properties of R and vice versa. For example, we characterize rings R for which Γ+(R) respectively is connected, complete, planar, complemented or a forest. Also we find the dominating number of Γ+(R).  相似文献   
452.
This paper deals with the free vibration behavior of laminated transversely isotropic circular plates with axisymmetric rigid core attached at the center. The governing equations of motion are obtained based on Mindlin's first-order shear deformation plate theory. Two possible categories of vibration modes related to up-down translation of the core and wobbly rotation of the core about a diameter are studied. Accurate natural frequencies hitherto not reported in the literature are presented for a wide range of thickness-to-radius ratio, inner-to-outer radius ratio, mass and moment of inertia ratios of the core and various boundary conditions at the outer edge of the plate. Numerical results are compared with those of a three-dimensional finite element method (3-D FEM) to demonstrate the high accuracy and reliability of the current analysis.  相似文献   
453.
Theoretical study of exohedral chemical functionalization of C48B6N6 with NH3 molecules has been investigated using DFT. It was found that NH3 molecule can be chemically adsorbed on boron sites of C48B6N6, with a charge transfer from NH3 to C48B6N6. Adsorption energy and the quantity of electron charge transfer from latest adsorbed ammonia to C48B6N6 decreased with increasing in the adsorbed NH3 molecules. Despite the strong adsorption energies, electronic properties of C48B6N6 is preserved after modification(s) with NH3 molecule(s) and chemical modification of C48B6N6 with NH3 molecules can be viewed as some kind of safe modification.  相似文献   
454.
The nonequilibrium Green's function approach in combination with density-functional theory is used to perform quantum mechanical calculations of the electron transport properties of furan and thiophene dimmers. Both the molecular systems have two S-linker and translated into the Gold junction with (1 1 1) surfaces. The studied molecular junctions at zero bias voltage are HOMO-based junctions and currents through these systems are driven by hole transport. The current–voltage characteristics of the both studied molecular junctions illustrate that negative differential resistance (NDR) feature is observed over the bias voltage of 2.0 V. Higher conductivity of fused furan dimmer and NDR character have been explained by the monitoring of the transmission resonance peak across the bias window against varying bias voltages.  相似文献   
455.
This article deals with constructing a confidence interval for the reliability parameter using ranked set sampling. Some asymptotic and resampling-based intervals are suggested, and compared with their simple random sampling counterparts using Monte Carlo simulations. Finally, the methods are applied on a real data set in the context of agriculture.  相似文献   
456.
The aim of this paper is to investigate Hyers–Ulam–Rassias stability of preserving lattice functional equation in various spaces. First, we prove stability of generalized preserving lattice functional equation in Banach lattices. Next, we show stability of preserving lattice cubic functional equation in Menger probabilistic normed Riesz spaces.  相似文献   
457.
A new PVC membrane electrode for manganese(II) ion based on a recently synthesized Schiff base of 5-[(4-nitrophenylazo)-N-hexylamine]salicylaldimine is reported. The electrode exhibits a Nernstian response for Mn2+ ions over a wide concentration range (4.0 × 10−7 to 1.8 × 10−2 mol L−1) with a slope of 30.1 (±1.0). The limit of detection is 1.0 × 10−7 mol L−1. The electrode has a fast response time (∼10 s), a satisfactory reproducibility and relatively long life time. The proposed sensor revealed good selectivities over a wide variety of other cations include hard and soft metals. This electrode could be used in a pH range of 4.5-7.5. It was used as an indicator electrode in potentiometric titration of manganese(II) ions with EDTA solution.  相似文献   
458.
By manipulating processing conditions, three levels of exfoliation of synthetic α-zirconium phosphate (α-ZrP) nanoplatelets in epoxy matrices have been achieved. Transmission electron microscopy and wide angle X-ray diffraction were utilized to confirm the three different levels of exfoliation of nanoplatelets in epoxy/α-ZrP nanocomposites. As expected, it was found that modulus and strength of the nanocomposite are affected by how well the nanoplatelets disperse. It was also found that the operative fracture mechanisms depend strongly on the state of the nanoplatelets dispersion. The crack deflection mechanism, which leads to a tortuous path crack growth, was only observed for poorly dispersed nanocomposites. Delamination of intercalated nanoplatelets and crack deflection were observed in a moderately dispersed system. In the case of fully exfoliated system, the crack only propagated in a straight fashion, which indicates that the fully exfoliated individual nanoplatelet can not affect the propagation of crack at all. The implication of the present findings for structural applications of polymer nanocomposites is discussed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1459–1469, 2007  相似文献   
459.
An effective route to functionalized hydantoin derivatives is described, involving the reaction of a urea derivative resulting from the addition of a primary amine to an arylsulfonyl isocyanate, and an alkyl propiolate or dialkyl acetylenedicarboxylate in the presence of triphenylphosphine. The reactive 1:1 intermediate obtained from the addition of triphenylphosphine to the alkyl propiolate or dialkyl acetylenedicarboxylate was trapped by NH-acids such as the urea derivative to produce functionalized hydantoin derivatives.  相似文献   
460.

Objective

The objective of this study was to develop quantitative T-weighted magnetic resonance imaging methodology for the detection and characterization of cartilage degeneration in a rabbit anterior cruciate ligament (ACL) transection model.

Methods

The right knee ACLs of 18 adult female New Zealand white rabbits were transected. The left knee joint served as a sham control. The rabbits were euthanized at 3 (Group 1), 6 (Group 2) and 12 (Group 3) weeks postoperatively. High-resolution 3D fat-saturated spoiled gradient echo images and T-weighted images were obtained in both the sagittal and axial planes at 3 T using a quadrature wrist coil. Following MR analysis, histological slides from the lateral femoral condyle cartilage were graded using the Mankin grading system.

Results

For all three groups, the average overall T values were significantly higher in the ACL-transected knee compared to control knee, and the percentage differences in T values between ACL-transected and control increased with the duration of time after transection. The average Mankin score for ACL-transected knees was higher than that for control for each time point, but this difference was statistically significant only for all groups combined.

Conclusions

This study demonstrates the feasibility of using T-weighted imaging as a useful tool in the detection and quantification of cartilage damage in all knee compartments in an ACL-transected rabbit model of cartilage degeneration.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号