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181.
We evaluate form factors for the scattering ofσ, ω andπ mesons from nucleons described by the MIT bag model. These form factors are then written covariantly and used for nuclear matter in the Hartree-Fock approximation to theσω model of quantum hadrodynamics with pions. For fixed parameters (meson couplings and masses) the inclusion of these form factors results in more binding at a higher saturation density. After refitting the parameters to reproduce the empirical saturation properties, the result is very close to that without form factors. 相似文献
182.
183.
A spin-dimer analysis of the anisotropic spin-exchange interactions in the distorted wolframite-type oxides CuWO4, CuMoO4-III, and Cu(Mo(0.25)W(0.75))O4 was performed by Koo and Whangbo (Inorg. Chem. 2001, 40, 2161-2169). For Cu(Mo(0.25)W(0.75))O4, a magnetic structure with a magnetic unit cell doubled along the a and b axes has been predicted, but neutron powder diffraction on Cu(Mo(0.25)W(0.75))O4 did not confirm such a magnetic structure. In the present work, a detailed spin-dimer analysis, considering the influence of particular atomic structure parameters, finally revealed that a wrong coordinate transformation of the Cu z coordinate of the Cu(Mo(0.25)W(0.75))O4 structure is responsible for the prediction of the new, hypothetical magnetic structure. The deviation from the correct value is too small to be recognized by unreasonable bond lengths or angles but is sufficient to change one specific calculated value that is responsible for the prediction of the hypothetical magnetic structure. 相似文献
184.
Sunil Kumar Selvakumar Arumugam Dr. Björn Schwarz Prof. Dr. Helmut Ehrenberg Prof. Dr. Kartik Chandra Mondal 《欧洲无机化学杂志》2023,26(10):e202200774
A representative Co(II) based single ion magnet (SIM) with N2O2 donor set and distorted pseudo-tetrahedral geometry has been synthesized and characterized to study the atomic and electronic structure. DC magnetometry results have been evaluated by means of a phenomenological Hamiltonian approach regarding zero field splitting (ZFS) parameters and compared with results from ab-initio multi-reference CASSCF (complete active space self-consistent field) calculations and qualitative ligand field theory (AILFT). Profound investigation of spin-lattice relaxation with the variation of temperature (from 1.8 to about 8 K) and magnetic field (at 14 different fields from zero up to 1 T) have been performed based on AC magnetometry. Under an applied dc magnetic field, spin-lattice relaxation occurs via a direct process with T2 temperature dependence due to limited heat transfer at very low temperature and above 5 K relaxation by an Orbach process with an energy barrier of ≈80 K dominates. 相似文献