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991.
Martin B. Hocking David T. Syme David E. Axelson Kirk H. Michaelian 《Journal of polymer science. Part A, Polymer chemistry》1990,28(11):2969-2982
The comonomer required, p-maleimidobenzoic acid (MBA) was first prepared in good yield by refinements of published methods. p-Carboxysuccinanilic acid (CSA), and p-succinimidobenzoic acid (SBA), were also prepared to provide models useful for IR and NMR for spectroscopic assignments of the new copolymers. Polymerization of MBA with acrylamide in glacial acetic acid at 60°C gave copolymers with estimated viscosity average molecular weights of 60,000 to 90,000. Yields and viscosity average molecular weights decreased as the MBA to acrylamide monomer feed ratio was increased. The rate of incorporation of MBA into the copolymer rose from 7 to 23% when the mole ratio in the feed was raised from 5 to 20%. Decreasing the initiator concentration increased molecular weights by less than predicted and reduced the yield of copolymer for any given feed ratio of MBA to acrylamide. In all cases about 30–40% of the MBA units in the purified copolymers were hydrolyzed. A change to dimethyl sulfoxide solvent gave good, and poor yields of copolymer at 5 and 10 mol % MBA, respectively, and no copolymer at 20 mol % MBA. Viscosity average molecular weights of the copolymer products prepared in DMSO were somewhat lower than obtained for the copolymers prepared in acetic acid. Polymerization in a DMSO-water mixture gave a negligible yield of polymeric product. Instead, only hydrolysates of MBA precipitated when the coloured polymerization solutions were added to methanol. 相似文献
992.
Titanium - catalyzed dimerization of cycloheptatriene affords pentacyclo[7.5.0.02,8.05,14.07,11]tetradeca-3,12-diene, , and pentacyclo[8.4.0.03,7.04,14.06,11]tetradeca-8,12-diene, . By heating, is converted quantitatively into . 相似文献
993.
H. Thielemann 《Fresenius' Journal of Analytical Chemistry》1978,292(3):237
Ohne Zusammenfassung
Separation and identification of the HCH ointment antiskabiosum using ready-made foils for thin-layer chromatography (purity test)
Verwendet wurden Silufol Fertigfolien UV 254 (Herstellerfirma: Sklárny Kavalier, SSR). Sorptionsmittel: Silpearl — weitporiges Silicagel nach Pitra mit Leuchtstoff für UV 254, Unterlage — Aluminiumfolie, Bindemittel — Stärke 相似文献
994.
A. Parlier H. Rudler N. Platzer M. Fontanille A. Soum 《Journal of organometallic chemistry》1985,287(1):c8-c12
Treatment of VO(acac)2 with the facial-tridentate organometallic ligand [η-CpCo{P(O)(OEt)2}3]? affords a new binuclear compound [η-CpCo{P(O)(OEt)2}3VO(acac)] (I). This compound undergoes protonation with HPF6 in the presence of 1,10-phenanthroline (phen), or 2,2′-bipyridyl (bipy), to yield binuclear cationic derivatives [η-CpCo{P(O)(OEt)2}3VO(phen))]+PF6? (II), and [η-CpCo{P(O)(OEth)2}3VO(bipy)]+PF6? (III). The X-ray crystal structure determination and full characterization of I has been performed. The catalytic oxygenation and oxygen transfer to 3,5-di-t-butylcatechol in the presence of I, II+, or III+ complexes is reported. 相似文献
995.
Diffusion of organic vapors at low concentrations in glassy PVC, polystyrene, and PMMA 总被引:1,自引:0,他引:1
Diffusion coefficients of various C1 to C6 organic vapors, at concentrations 0.5 wt. percent, have been determined by gravimetric sorption rate measurements on emulsion and suspension-polymerized powder samples of PVC, polystyrene, and PMMA. Fickian diffusion kinetics were observed at the lowest concentrations, with a second-stage, relaxation-controlled sorption appearing at higher concentrations. In conjunction with published data for diffusivities of fixed gases in these polymers, the results indicate that diffusivity decreases exponentially, and that diffusion activation energy (ED) increases linearly, with increasing diameter of “spherical” penetrant molecules (e.g., the noble gases, CH4, SF6, CCl4, and neopentane). Much of the observed scatter in these correlations is attributable to uncertainty in the molecular diameters. For C4 and larger n-alkanes and other elongated or flattened molecules, diffusivities are higher, and ED lower, than for spherical molecules of similar molar volume. This finding suggests that anisometric molecules are oriented and move along their long axes during diffusion through the glassy polymer matrix. Correlations of diffusivities with molecular dimensions suggests that transport of anisometric molecules is governed by a diameter smaller than the mean (equivalent sphere) diameter but larger than the minimum dimension of their extended-chain conformation. Among the three polymers studied, diffusivity of each penetrant, at a given temperature, decreases in the order polystyrene> PVC ≥ PMMA. 相似文献
996.
F. F. Blanko I. A. Korbukh M. N. Preobrazhenskaya H. Dorn 《Chemistry of Heterocyclic Compounds》1981,17(11):1102-1104
N-Glucoside analogs of the antibiotic pyrazofurine were obtained by fusion of 3-hydroxy-4-ethoxycarbonylpyrazole with tetra-O-acetyl-ß-D-ribofuranose in the presence of iodine.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1512–1514, November, 1981. 相似文献
997.
Dissoziation Behaviour of Dimerie Metal Halides and the Formation of MnAl2Cl8 The thermal dissoziation was measured of the gaseous dimeric metal halides Al2Cl6, Ga2Cl6, In2Cl6, and Mn2I4 and the formation of the gaseous chloride complex MnAl2Cl8 by MnCl2,f and Al2Cl6,g in a membrane manometer. The enthalpy and the entropy of these reactions were derived. 相似文献
998.
Soltero-Higgin M Carlson EE Phillips JH Kiessling LL 《Journal of the American Chemical Society》2004,126(34):10532-10533
The flavoenzyme uridine 5'-diphosphate (UDP)-galactopyranose mutase (UGM) plays a key role in the cell wall biosynthesis of many pathogens, including Mycobacterium tuberculosis. Using a synthetic fluorescent ligand, we screened 16 000 compounds in a fluorescence polarization assay. Effective inhibitors of UGM were identified. 相似文献
999.
A method is described for the determination by solid phase spectrophotometry (SPS) of trace amounts of vanadium in natural water and crude petroleum samples. The procedure is based on fixation on a dextran-type anion exchanger of the complex V(IV)-Eriochrome Cyanine R. The absorbance of the gel, at 563 and 750 nm, packed in a 1 mm cell, is measured directly. Vanadium can be determined in the 0.6-25.0 mug l(-1) range with a relative standard deviation of 2.2%. The comparison of the SPS method and the gallic acid persulphate method shows that the linearity, analytical sensitivity and precision were better for the SPS method, and that the latter method has lower detection and quantification limits than the gallic acid persulphate method. 相似文献
1000.
Nicolaou KC Baran PS Zhong YL Barluenga S Hunt KW Kranich R Vega JA 《Journal of the American Chemical Society》2002,124(10):2233-2244
The discovery and development of the o-iodoxybenzoic acid (IBX) reaction with certain unsaturated N-aryl amides (anilides) to form heterocycles are described. The application of the method to the synthesis of delta-lactams, cyclic urethanes, hydroxy amines, and amino sugars among other important building blocks and intermediates is detailed. In addition to the generality and scope of this cyclization reaction, this article describes a number of mechanistic investigations suggesting a single electron transfer from the anilide functionality to IBX and implicating a radical-based mechanism for the reaction. 相似文献