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201.
Fluorescence measurements have been used to follow the build-up of photoproducts during the direct and benzophenone-sensitized irradiation of the title compounds 1-IN, 1-BrN, and 1-ClN (HN = naphthalene). Compounds 1-IN and 1-BrN react by homolytic dissociation through their lowest triplet and singlet excited states, respectively. Compound 1-ClN does not undergo C–Cl bond fission, except through electron transfer in the presence of an amine A, In the absence of this electron transfer, 1-ClN reacts only through substitution and oxidation processes. 相似文献
202.
Edwin C. Constable Jack Lewis Michael C. Liptrot Paul R. Raithby Martin Schröder 《Polyhedron》1983,2(4):301-302
The synthesis and single crystal X-ray structure of the pentagonal bipyramidal nickel(II) complex [Ni(L)(EtOH)2](BF4)2 involving the quinquedentate terpyridyl macrocyclic ligand L is reported; the electrochemical reduction of such complexes yields, in solution, d9 nickel(I) species. 相似文献
203.
The problem of enrichment of a gas sample by a definite factor is considered. It occurs, for example, when the radiocarbon dating method is to be extended to higher ages. The case of a thermal diffusion column with finite reservoirs at both ends is investigated and the decisive benefit of a high separation factor for the sufficient knowledge and reproducibility of the enrichment factor is pointed out. The relation between the factors as well as their temporal behaviour is developed in two ways: Simple formulae with physical evidence are adapted to make allowance for the content of the column itself, and then verified by deriving the exact isotope distribution from the partial differential equation. 相似文献
204.
Lamellarity of artificial phospholipid-membranes determined by photometric phase-contrast microscopy
A method is presented to discern phospholipid vesicles larger than 30 μm surrounded by a single bilayer from those whose membrane is multilamellar. It is based on the photometric observation of the contrast of the membrane contours in a second image-plane of a phase-contrast microscope. 相似文献
205.
Summary Polytetrafluorethylene rods in transverse vibration exhibit sharp non-harmonic resonances when subjected to a static tensile
stress during vibration. The extent and location of the resonances are critically dependent on the exact static stress state
and history of the rods. Rods under no external tension have no anomalous behavior in the range 100 to 2000 cps, but under
static tension varying from 1.5×105 to 3.0×106 dynes/cm2 (2.2 to 44 psi) sharp resonances appear in the vicinity of 400 cps. The mechanical resonance dispersions in complex shear
compliance previously reported byFitzgerald are thus substantiated by the present work. The failure of certain other investigators to observe the dispersion in polytetrafluorethylene
is attributed to the fact that insufficient attention was paid to the static stress conditions in their tests.
Zusammenfassung Polytetrafluor?thylen-Streifen zeigen bei transversaler Schwingung scharfe nicht-harmonische Resonanzen, wenn sie w?hrend der Vibration einem statischen Zug unterworfen sind. Intensit?t und Lage der Resonanzen h?ngen kritisch vom statischen Spannungszustand und der Geschichte der Proben ab. Proben unter keiner ?u?eren Spannung zeigen im Bereich von 100–200 Hz kein anomales Benehmen, doch erscheinen bei statischer Belastung zwischen 1,5×105 zu 3,0×106 dyn/cm2 scharfe Resonanzen in der N?he von 400 Hz. Die mechanische Resonanzdispersion der komplexen Scherungsnachgiebigkeit, früher vonFitzgerald mitgeteilt, werden mit der vorliegenden Arbeit best?tigt. Da? anderen Bearbeitern die Beobachtung der Dispersion bei Polytetrafluor?thylen mi?lungen ist, ist der Tatsache zuzuschreiben, da? den statischen Spannungszust?nden in ihren Proben ungenügende Rechnung zuteil wurde.相似文献
206.
Siva R. Athreya Richard F. Bass Edwin A. Perkins 《Transactions of the American Mathematical Society》2005,357(12):5001-5029
We introduce a new method for proving the estimate
where solves the equation . The method can be applied to the Laplacian on . It also allows us to obtain similar estimates when we replace the Laplacian by an infinite-dimensional Ornstein-Uhlenbeck operator or other elliptic operators. These operators arise naturally in martingale problems arising from measure-valued branching diffusions and from stochastic partial differential equations.
where solves the equation . The method can be applied to the Laplacian on . It also allows us to obtain similar estimates when we replace the Laplacian by an infinite-dimensional Ornstein-Uhlenbeck operator or other elliptic operators. These operators arise naturally in martingale problems arising from measure-valued branching diffusions and from stochastic partial differential equations.
207.
208.
G.Edwin Wilson 《Tetrahedron》1982,38(17):2597-2625
209.
210.
Kirby N. Klump Edwin N. Lassettre 《Journal of Electron Spectroscopy and Related Phenomena》1978,14(3):215-230
Generalized oscillator strengths have been obtained for two transitions in CO2 from inelastic electron scattering determinations as a function of angle. Excitation energies for the two transitions are 11.04 and 11.38 eV, respectively. This spectral region was studied previously by Lassettre and Shiloff1 but at a resolution too low to resolve the two transitions. In the present experiments the two are clearly resolved. Results are compared with the previous experiments of Foo et al.2. Since substantial discrepancies are found both with the previous results of Lassettre and Shiloff and that of Foo et al., the accuracy of angular trends has been checked by comparing elastic scattering with the accurate determinations of Bromberg.6 Agreement is good. Multiple scattering is shown to be absent by varying the pressure. Generalized oscillator strengths are compared with the theoretical calculations of McKoy and collaborators. The change in the shape of the CO2 spectrum in the region of 7–10 eV excitation energy is also studied. 相似文献