Studies on amine hydrothiocyanates. IV. Thermal decomposition studies using TG

The thermal decomposition of piperidine hydrothiocyanate, piperazine hydrothiocyanate, and the dihydrothiocyanates of ethylenediamine and 1,3-diaminopropane has been studied using TG. Piperidine hydrothiocyanate decomposes in a single step while the dihydrothiocyanates follow more complicated decomposition patterns yielding H₂S and half of the organic moiety first. The second step involves the loss of H₂S and the remainder of the organic moiety. In each case, complex polymeric materials result. Piperazine hydrothiocyanate also decomposes in two steps, the first involving the loss of half of the piperazine and the second involving the loss of piperazine and H₂S. Kinetic parameters have been determined for all these reactions.     

Characteristics of propagation of light beams in gyrotropic crystals

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 54, No. 5, pp. 815–819, May, 1991.     

Charged Black Holes and Multidimensional Gravity

A multidimensional generalization of the Reissner-Nordström solution of general relativity is obtained for the case of n Ricci-flat internal spaces. A two-parameter family of black-hole solutions for an arbitrary dimensionality D is selected. Nontrivial black holes with D > 4 are shown to exist only with a nonzero electric charge. Observational consequences are discussed, in particular, a violation of Coulomb's law.     

Temperature dependence of corundum roentgenoluminescence and thermoluminescence

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 54, No. 3, pp. 438–444, March, 1991.     

Kaplansky conjecture in the theory of quadratic forms

This article considers the splitting properties of finite-dimensional division rings over universal splitting fields of quadratic forms. An example of a field with u-invariant equal to 6 is constructed, which contradicts Kaplansky's conjecture concerning u-invariants.Translated from Zapiski Nauchnykh Seminarov Leningradskogo Otdeleniya Matematicheskogo Instituta im, V. A. Steklova Akademii Nauk SSSR, Vol. 175, pp. 75–89, 1989.     

Investigation of the structure of a melt and molecular dynamics of ortho- and pyrophosphates by Raman spectroscopy

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 55, No. 4, pp. 535–540, October, 1991.     

Effective field and the Bloch-Siegert shift at bichromatic excitation of multiphoton EPR

The dynamics of multiphoton transitions in a two-level spin system excited by transverse microwave and longitudinal RF fields with the frequencies ω_mw and ω_rf, respectively, is analyzed. The effective time-independent Hamiltonian describing the “dressed” spin states of the “spin + bichromatic field” system is obtained by using the Krylov-Bogoliubov-Mitropolsky averaging method. The direct detection of the time behavior of the spin system by the method of nonstationary nutations makes it possible to identify the multiphoton transitions for resonances ω₀ = ω_mw + rω_rf (ω₀ is the central frequency of the EPR line, r = 1, 2), to measure the amplitudes of the effective fields of these transitions, and to determine the features generated by the inhomogeneous broadening of the EPR line. It is shown that the Bloch-Siegert shifts for multiphoton resonances at the inhomogeneous broadening of spectral lines reduce only the nutation amplitude but do not change their frequencies.     

Energy losses of dipoles traveling relative to a moving medium

We consider the radiation from nonoscillating dipoles traveling with constant velocity directed parallel or antiparallel to the velocity of a homogeneous transparent moving medium. It is assumed that the medium in its rest frame is isotropic and has no spatial dispersion. We obtain expressions for the radiative energy losses and estimate the polarization energy losses of electric and magnetic dipoles of different orientations. In particular, it is shown that the energy loss of a source is negative if it moves in the direction of the medium motion and the source velocity is less than the medium velocity. Estimates for the energy losses of dipoles in the cases of an electron beam and a flow of a weakly dispersive medium are given. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 49, No. 6, pp. 502–512, June 2006.     

Influence of Azimuthal Structure of Surface Waves on Efficiency of their Excitation by Tubular Electron Beams

The excitation of eigen surface waves by tubular electron beams in cylindrical discharge devices is studied. The influence of the wave‐field azimuthal structure on the excitation efficiency and nonlinear stage of the plasmabeam instability is investigated both numerically and analytically. Analytical expressions for the saturation amplitude and excitation efficiency of the wave under study are derived. They are found to agree well with results obtained by numerical modelling of the plasma‐beam interaction presented in this paper. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Method of lines with boundary elements for 1‐D transient diffusion‐reaction problems

Time‐dependent differential equations can be solved using the concept of method of lines (MOL) together with the boundary element (BE) representation for the spatial linear part of the equation. The BE method alleviates the need for spatial discretization and casts the problem in an integral format. Hence errors associated with the numerical approximation of the spatial derivatives are totally eliminated. An element level local cubic approximation is used for the variable at each time step to facilitate the time marching and the nonlinear terms are represented in a semi‐implicit manner by a local linearization at each time step. The accuracy of the method has been illustrated on a number of test problems of engineering significance. © 2005 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 2006