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111.
A qualitative model of the dynamics of a multiterawatt radiating Z-pinch with cold start and high rate of current rise is proposed. The model is used to analyze discharges with currents I ~ 2–5 MA (with dI/dt > 1013 A/s) through uniform or structured plasma-producing loads, including wire arrays. The most important consequence of cold start is that spatially nonuniform plasma production is prolonged to almost the entire current rise time. Under these conditions, the Ampére force begins to play a dominant role in the plasma dynamics before the plasma-producing load is completely transformed into an accelerated plasma. The results of computations of wire-array vaporization are presented. A formula is proposed for estimating the highest attainable velocity of plasma flow into a heterogeneous liner driven by the Ampére force. It is shown that local imbalance between radial motion of the produced plasma and supply of the plasma-producing substance to be ionized leads to axially nonuniform breakthrough of magnetic flux into the liner, which precedes plasma collapse. The magnetic-flux breakthrough gives rise to a chaotic azimuthal-axial plasma structure consisting of radial plasma jets of relatively small diameter, which is called a radial plasma rainstorm. The breaking-through azimuthal magnetic flux obstructs further current flow in the breakthrough region. Analyses of Z-pinch implosion based on the theory of Rayleigh-Taylor instability or the snowplow model are incorrect under the plasma-rainstorm conditions. The processes taking place in a stagnant Z-pinch include conversion of the energy carried by the current-generated magnetic field into turbulent MHD flow of the ion component of the plasma, its convective mixing with magnetic field, heating, energy transfer from ions to electrons, and emission from the plasma. Under typical experimental conditions, emission plays a key role in the energy balance in an imploding pinch. Z-pinch is modeled by an electric-circuit component that has a time-dependent nonlinear impedance and consumes the magnetic energy supplied by a generator through a magnetically insulated transmission line (MITL). The peak power reached in the circuit is comparable to the peak soft X-ray power output emitted by the pinch in terms of magnitude and timing. Optimum matching conditions are formulated for the generator-MITL-pinch circuit.  相似文献   
112.
Single crystals of lead gallium germanate Pb3Ga2Ge4O14 are grown from their own solution melts. The propagation of bulk acoustic waves is investigated, and the elastic, piezoelectric, and dielectric constants are calculated. The temperature dependences of the dielectric constants of this compound are analyzed.  相似文献   
113.
A theory of a planar disk-shaped RF plasma source under anomalous skin effect conditions is developed. In the absence of an external magnetic field, such conditions are satisfied for transverse electromagnetic waves with phase velocities below the electron thermal velocity, and, in the presence of this field, they are satisfied for electron cyclotron waves with frequencies corresponding to the resonant absorption line. For each of these cases, the RF field power deposited in a plasma with given parameters is determined and the equivalent plasma resistance is calculated.  相似文献   
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New results concerning the topology of the fragmentation of relativistic nuclei 7Li and 10B are presented. A program is proposed for studying the cluster structure of stable and radioactive nuclei. The use of emulsions in the investigation of nuclear clustering in the fragmentation of light nuclei at energies are in excess of 1 GeV per nucleon is discussed.  相似文献   
117.
A monolayer of covalently anchored, novel, binaphthyl ketone is used as a surface‐confined photochemical radical generator (PRG) for anchoring a variety of polymers to silicon surfaces. The precursor PRG is synthesized by the application of a facile and novel method for the oxidation of sterically hindered benzylic hydrocarbons to carbonyl compounds. Oxidation was carried out with a stoichiometric amount of potassium peroxydisulfate, in the presence of a catalytic amount of copper sulfate in an acetonitrile/water mixture. The PRG synthesized is characterized by 1H NMR, UV, and Fourier transform infrared (FTIR). The covalently attached monolayers are characterized by X‐ray photoelectron spectroscopy, ellipsometry, and water contact angle measurements. The method developed is applicable to the preparation of a monolayer of a variety of polymers on a wide range of substrates carrying surface hydroxyl groups. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5413–5423, 2004  相似文献   
118.
New hydrogen‐bonded liquid‐crystalline poly(ester amide)s (PEA)s were obtained from 1,4‐terephthaloyl[bis‐(3‐nitro‐N‐anthranilic acid)] (5) or 1,4‐terephthaloyl[bis‐(N‐anthranilic acid)] (6), with or without nitro groups, respectively, through the separate condensation of each with hydroquinone or dihydroxynaphthalene. The dicarboxylic monomers were synthesized from 2‐aminobenzoic acid. The phase behavior of the monomers and polymers were studied with differential scanning calorimetry, polarized light microscopy, and wide‐angle X‐ray diffraction methods. Monomer 5, containing nitro groups, exhibited a smectic liquid‐crystalline phase, whereas the texture of monomer 6 without nitro groups appeared to be nematic. The PEAs containing nitro groups exhibited polymorphism (smectic and nematic), whereas those without nitro groups exhibited only one phase transition (a nematic threaded texture). The changes occurring in the phase behavior of the polymers were explained by the introduction of nitro groups. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1289–1298, 2004  相似文献   
119.
The compatibilization effect of polystyrene (PS)‐poly(dimethylsiloxane) (PDMS) diblock copolymer (PS‐b‐PDMS) and the effect of rheological properties of PS and PDMS on phase structure of PS/PDMS blends were investigated using a selective extraction technique and scanning electron microscopy (SEM). The dual‐phase continuity of PS/PDMS blends takes place in a wide composition range. The formation and the onset of a cocontinuous phase structure largely depend on blend composition, viscosity ratio of the constituent components, and addition of diblock copolymers. The width of the concentration region of the cocontinuous structure is narrowed with increasing the viscosity ratio of the blends and in the presence of the small amount diblock copolymers. Quiescent annealing shifts the onset values of continuity. The experimental results are compared with the volume fraction of phase inversion calculated with various theoretical models, but none of the models can account quantitatively for the observed data. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 898–913, 2004  相似文献   
120.
The viscoelastic properties of binary blends of nitrile rubber (NBR) and isotactic polypropylene (PP) of different compositions have been calculated with mean‐field theories developed by Kerner. The phase morphology and geometry have been assumed, and experimental data for the component polymers over a wide temperature range have been used. Hashin's elastic–viscoelastic analogy principle is used in applying Kerner's theory of elastic systems for viscoelastic materials, namely, polymer blends. The two theoretical models used are the discrete particle model (which assumes one component as dispersed inclusions in the matrix of the other) and the polyaggregate model (in which no matrix phase but a cocontinuous structure of the two is postulated). A solution method for the coupled equations of the polyaggregate model, considering Poisson's ratio as a complex parameter, is deduced. The viscoelastic properties are determined in terms of the small‐strain dynamic storage modulus and loss tangent with a Rheovibron DDV viscoelastometer for the blends and the component polymers. Theoretical calculations are compared with the experimental small‐strain dynamic mechanical properties of the blends and their morphological characterizations. Predictions are also compared with the experimental mechanical properties of compatibilized and dynamically cured 70/30 PP/NBR blends. The results computed with the discrete particle model with PP as the matrix compare well with the experimental results for 30/70, 70/30, and 50/50 PP/NBR blends. For 70/30 and 50/50 blends, these predictions are supported by scanning electron microscopy (SEM) investigations. However, for 30/70 blends, the predictions are not in agreement with SEM results, which reveal a cocontinuous blend of the two. Predictions of the discrete particle model are poor with NBR as the matrix for all three volume fractions. A closer agreement of the predicted results for a 70/30 PP/NBR blend and the properties of a 1% maleic anhydride modified PP or 3% phenolic‐modified PP compatibilized 70/30 PP/NBR blend in the lower temperature zone has been observed. This may be explained by improved interfacial adhesion and stable phase morphology. A mixed‐cure dynamically vulcanized system gave a better agreement with the predictions with PP as the matrix than the peroxide, sulfur, and unvulcanized systems. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1417–1432, 2004  相似文献   
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