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141.
Wertheim’s integral equation theory for associating fluids is reformulated for the study of the connectedness properties of
associating hard spheres with four bonding sites. The association interaction is described as a square-well saturable attraction
between these sites. The connectedness version of the Ornstein-Zernike (OZ) integral equation is supplemented by the PY-like
closure relation and solved analytically within an ideal network approximation in which the network is represented as resulting
from the crossing of ideal polymer chains. The pair connectedness functions and the mean cluster size are calculated and discussed.
The condition for the percolation transition and the analytical form of the percolation threshold are derived. The connection
of the percolation with the gas-liquid phase transition is discussed. 相似文献
142.
Eduard Prugovečki 《Foundations of Physics》1994,24(7):989-1076
The various physical aspects of the general relativistic principles of covariance and strong equivalence are discussed, and their mathematical formulations are analyzed. All these aspects are shown to be present in classical general relativity, although no contemporary formulation of canonical or covariant quantum gravity has succeeded to incorporate them all. This has, in part, motivated the recent introduction of a geometro-stochastic framework for quantum general relativity, in which the classical frame bundles that underlie the formulation of parallel transport in classical general relativity are replaced by quantum frame bundles. It is shown that quantum frames can take over the role played by complete sets of observables in conventional quantum theory, so that they can mediate the natural transference of the general covariance and the strong equivalence principles from the classical to the quantum general relativistic regime. This results in a geometrostochastic mode of quantum propagation in general relativistic quantum bundles, which is mathematically implemented by path integration methods based on parallel transport along horizontal lifts of geodesics for the vacuum expectation values of a quantum gravitational field in a quantum spacetime supermanifold. The covariance features of this field are embedded in a quantum gravitational supergroup, which incorporates Poincaré as well as diffeomorphism invariance, and resolves the issue of time in quantum gravity. 相似文献
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Azedaralide, a potentially advanced intermediate for the total synthesis of various tetranortriterpenes, was constructed utilising the Fernández-Mateos protocol and assigned both relative and absolute stereochemistries. Both asymmetric aldol and classical chiral resolution attempts failed to deliver pure enantiomers whereas preparative chiral chromatography resolved racemic azedaralide with ease. 相似文献
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149.
Victoria L. Challinor Ryne C. Johnston Paul V. Bernhardt Reginald P. Lehmann Elizabeth H. Krenske James J. De Voss 《Chemical science》2015,6(10):5740-5745
A series of novel sesterterpenes (2–6) have been isolated from the roots of Aletris farinosa and structurally characterized by MS, NMR, and X-ray crystallography in conjunction with computational modeling. Their structures provide new insights into the mechanisms of sesterterpene biosynthesis. Specifically, we propose with support from density functional theory computations that the configuration at a single stereocenter determines the fate of a key tetracyclic carbocationic intermediate, derived from an oxidogeranylfarnesol precursor. Whereas one epimer of the carbocation undergoes H+ elimination to give 6, the other undergoes a spectacular cascade of seven 1,2-methyl and hydride migrations leading to the previously unreported carbon skeleton of 5. Theoretical calculations suggest that the cascade is triggered by substrate preorganization in the enzyme active site. 相似文献
150.
Improved Spectral Coverage and Fluorescence Quenching in Donor–acceptor Systems Involving Indolo[3‐2‐b]carbazole and Boron‐dipyrromethene or Diketopyrrolopyrrole
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Adis Khetubol Sven Van Snick Melissa L. Clark Eduard Fron Eduardo Coutiño‐González Arvid Cloet Koen Kennes Yuliar Firdaus Maarten Vlasselaer Volker Leen Wim Dehaen Mark Van der Auweraer 《Photochemistry and photobiology》2015,91(3):637-653
A novel π‐conjugated triad and a polymer incorporating indolo[3,2‐b]‐carbazole (ICZ) and 4,4‐difluoro‐4‐bora‐3a,4a‐diaza‐s‐indacene (BODIPY) were synthesized via a Sonogashira coupling. Compared to the parent BODIPY the absorption and fluorescence spectrum were for both compounds broader and redshifted. The redshift of the fluorescence and the decrease of the fluorescence quantum yield and decay time upon increasing solvent polarity were attributed to the formation of a partial charge‐transfer state. Upon excitation in the ICZ absorption band the ICZ fluorescence was quenched in both compounds mainly due to energy transfer to the BODIPY moiety. In a similar ICZ–π–DPP polymer (where DPP is diketopyrrolopyrrole), a smaller redshift of the absorption and fluorescence spectra compared to the parent DPP was observed. A less efficient quenching of the ICZ fluorescence in the ICZ–π–DPP polymer could be related to the unfavorable orientation of the transition dipoles of ICZ and DPP. The rate constant for energy transfer was for all compounds an order of magnitude smaller than predicted by Förster theory. While in a solid film of the triad a further redshift of the absorption maximum of nearly 100 nm was observed, no such shift was observed for the ICZ–π–BODIPY polymer. 相似文献