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91.
A generally applicable reductive method was elaborated by means of which numerous substances can be determined having oxidation potentials exceeding 0.3 V. The 0.1 N stannous chloride standard solution can be stored for some months, with a very slight decrease in titre, by using an automatic equipment for the supplying with carbon dioxide of the storage flask and burette. The procedure has so far been employed for the determination of ferric-, ferrous-, dichromate-, vanadate-, bromate-, iodate- and ferricyanide ions, furthermore of iodine. The advantage of the method is — in addition to the simplicity of the realization — that in the given ranges the experimental error never exceeds 0.5%, remaining usually under this limit. 相似文献
92.
Champagne B Botek E Nakano M Nitta T Yamaguchi K 《The Journal of chemical physics》2005,122(11):114315
The basis set and electron correlation effects on the static polarizability (alpha) and second hyperpolarizability (gamma) are investigated ab initio for two model open-shell pi-conjugated systems, the C(5)H(7) radical and the C(6)H(8) radical cation in their doublet state. Basis set investigations evidence that the linear and nonlinear responses of the radical cation necessitate the use of a less extended basis set than its neutral analog. Indeed, double-zeta-type basis sets supplemented by a set of d polarization functions but no diffuse functions already provide accurate (hyper)polarizabilities for C(6)H(8) whereas diffuse functions are compulsory for C(5)H(7), in particular, p diffuse functions. In addition to the 6-31G(*)+pd basis set, basis sets resulting from removing not necessary diffuse functions from the augmented correlation consistent polarized valence double zeta basis set have been shown to provide (hyper)polarizability values of similar quality as more extended basis sets such as augmented correlation consistent polarized valence triple zeta and doubly augmented correlation consistent polarized valence double zeta. Using the selected atomic basis sets, the (hyper)polarizabilities of these two model compounds are calculated at different levels of approximation in order to assess the impact of including electron correlation. As a function of the method of calculation antiparallel and parallel variations have been demonstrated for alpha and gamma of the two model compounds, respectively. For the polarizability, the unrestricted Hartree-Fock and unrestricted second-order M?ller-Plesset methods bracket the reference value obtained at the unrestricted coupled cluster singles and doubles with a perturbative inclusion of the triples level whereas the projected unrestricted second-order M?ller-Plesset results are in much closer agreement with the unrestricted coupled cluster singles and doubles with a perturbative inclusion of the triples values than the projected unrestricted Hartree-Fock results. Moreover, the differences between the restricted open-shell Hartree-Fock and restricted open-shell second-order M?ller-Plesset methods are small. In what concerns the second hyperpolarizability, the unrestricted Hartree-Fock and unrestricted second-order M?ller-Plesset values remain of similar quality while using spin-projected schemes fails for the charged system but performs nicely for the neutral one. The restricted open-shell schemes, and especially the restricted open-shell second-order M?ller-Plesset method, provide for both compounds gamma values close to the results obtained at the unrestricted coupled cluster level including singles and doubles with a perturbative inclusion of the triples. Thus, to obtain well-converged alpha and gamma values at low-order electron correlation levels, the removal of spin contamination is a necessary but not a sufficient condition. Density-functional theory calculations of alpha and gamma have also been carried out using several exchange-correlation functionals. Those employing hybrid exchange-correlation functionals have been shown to reproduce fairly well the reference coupled cluster polarizability and second hyperpolarizability values. In addition, inclusion of Hartree-Fock exchange is of major importance for determining accurate polarizability whereas for the second hyperpolarizability the gradient corrections are large. 相似文献
93.
94.
Edith Nadler 《Mikrochimica acta》1939,27(3):231-239
Ohne ZusammenfassungUmfaßt die Literatur des Zeitraumes vom 5. Mai bis 20. Juni 1939. 相似文献
95.
Edith Gabriel 《Methodology and Computing in Applied Probability》2014,16(2):411-431
Non-parametric estimates of the K-function and the pair correlation function play a fundamental role for exploratory and explanatory analysis of spatial and spatio-temporal point patterns. These estimates usually require information from outside of the study region, resulting to the so-called edge effects which have to be corrected. They also depend on first-order characteristics, which have to be estimated in practice. In this paper, we extend classical edge correction methods to the spatio-temporal setting and compare the performance of the related estimators for stationary/non-stationary and/or isotropic/anisotropic point patterns. Further, we explore the influence of the estimated intensity function on these estimators. 相似文献
96.
Jürgen Brüning Edith Alig Martin U. Schmidt 《Acta Crystallographica. Section C, Structural Chemistry》2010,66(7):o341-o344
Ezetimibe {systematic name: (3R,4S)‐1‐(4‐fluorophenyl)‐3‐[(3S)‐3‐(4‐fluorophenyl)‐3‐hydroxypropyl]‐4‐(4‐hydroxyphenyl)azetidin‐2‐one}, C24H21F2NO3, is used to lower cholesterol levels by inhibiting cholesterol resorption in the human intestine. The crystal structure of ezetimibe anhydrate was solved from laboratory powder diffraction data by means of real‐space methods using the program DASH [David et al. (2006). J. Appl. Cryst. 39 , 910–915]. Subsequent Rietveld refinement with TOPAS Academic [Coelho (2007). TOPAS Academic User Manual. Version 4.1. Coelho Software, Brisbane, Australia] led to a final Rwp value of 8.19% at 1.75 Å resolution. The compound crystallizes in the space group P212121 with one molecule in the asymmetric unit. The molecules are closely packed and two intermolecular hydrogen bonds form an extended hydrogen‐bond architecture. 相似文献
97.
Nakano M Champagne B Botek E Ohta K Kamada K Kubo T 《The Journal of chemical physics》2010,133(15):154302
This contribution reveals the effects of a static electric field on the static second hyperpolarizability γ of symmetric singlet diradical molecules using the valence configuration interaction scheme. It is found that under the effect of a field, the component of γ along the axis joining the two radical sites can be gigantically (approximately two to three orders) enhanced for symmetric diradicals having intermediate diradical characters with respect to those of closed-shell and pure diradical molecules in the absence of a field. Moreover, this electric field enhancement of γ increases as a function of the diradical character. These results and their analysis propose therefore a new strategy to design materials with exceptional nonlinear optical responses. 相似文献
98.
Edith Berger-Preiß Susanne Gerling Elisabeth Apel Alfonso Lampen Otto Creutzenberg 《Analytical and bioanalytical chemistry》2010,398(1):313-318
We have developed a highly selective and sensitive method using gas chromatography-mass spectrometry with negative chemical
ionization for measuring 3-chloropropane-1,2-diol (3-MCPD) in rat blood and urine. Samples were adsorbed on silica gel, extracted
with ethyl acetate, and derivatized by chemical derivatization with heptafluorobutyric acid anhydride. For quantification,
matrix-based calibration curves and 3-MCPD-d
5, as an isotope-labeled internal standard, were used. The relative recoveries of 3-MCPD were between 80 and 110% in most cases
and the relative standard deviations were typically less than 10%, with some exceptions. The limit of quantification of the
method was found to be about 2 ng/mL. In conclusion, a valuable, robust, and sensitive method for detection of 3-MCPD is now
available for biokinetics studies. 相似文献
99.
Encarnación Rodríguez‐Gonzalo Rita Carabias‐Martínez Edith Miranda Cruz Javier Domínguez‐Álvarez Jesús Hernández‐Méndez 《Journal of separation science》2009,32(4):575-584
In the present work we address the development of a simple and effective method for the determination of triazine herbicide residues in horticultural products by CE in nonaqueous media (NACE). Potato samples were selected as a representative matrix of such foods with a nonfatty content. Isolation of the analytes from the sample matrix was accomplished by extraction with organic solvents, assisted by ultrasound; a clean‐up step of the organic extracts was carried out with SPE, using an Oasis MCX® sorbent to retain the analytes directly from the organic medium. The detection limits achieved in spiked potatoes (1.7–4.0 μg/kg) were lower than the default value of maximum residue level (MRL) established by current EU legislation for pesticide residues in foodstuffs. The results obtained were compared with HPLC in order to evaluate the performance of the NACE procedure. 相似文献
100.
David Nadler 《Selecta Mathematica, New Series》2009,15(4):563-619
Let X be a compact real analytic manifold, and let T* X be its cotangent bundle. In a recent paper with Zaslow (J Am Math Soc 22:233–286, 2009), we showed that the dg category Sh
c
(X) of constructible sheaves on X quasi-embeds into the triangulated envelope F(T* X) of the Fukaya category of T* X. We prove here that the quasi-embedding is in fact a quasi-equivalence. When X is a complex manifold, one may interpret this as a topological analogue of the identification of Lagrangian branes in T* X and regular holonomic DX{{\mathcal D}_X} -modules developed by Kapustin (A-branes and noncommutative geometry, arXiv:hep-th/0502212) and Kapustin and Witten (Commun
Number Theory Phys 1(1):1–236, 2007) from a physical perspective. As a concrete application, we show that compact connected
exact Lagrangians in T* X (with some modest homological assumptions) are equivalent in the Fukaya category to the zero section. In particular, this
determines their (complex) cohomology ring and homology class in T* X, and provides a homological bound on their number of intersection points. An independent characterization of compact branes
in T* X has recently been obtained by Fukaya et al. (Invent Math 172(1):1–27, 2008). 相似文献