首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   187篇
  免费   0篇
化学   68篇
晶体学   13篇
力学   2篇
数学   28篇
物理学   76篇
  2019年   6篇
  2018年   2篇
  2017年   4篇
  2016年   3篇
  2014年   4篇
  2013年   7篇
  2011年   6篇
  2010年   5篇
  2009年   2篇
  2008年   8篇
  2007年   2篇
  2006年   3篇
  2004年   2篇
  2003年   8篇
  2002年   4篇
  2001年   3篇
  2000年   5篇
  1999年   2篇
  1997年   2篇
  1996年   6篇
  1994年   2篇
  1993年   7篇
  1992年   7篇
  1986年   4篇
  1985年   2篇
  1984年   3篇
  1983年   7篇
  1982年   1篇
  1980年   4篇
  1979年   3篇
  1978年   3篇
  1977年   1篇
  1975年   6篇
  1974年   1篇
  1973年   3篇
  1972年   2篇
  1970年   5篇
  1969年   3篇
  1968年   3篇
  1967年   10篇
  1964年   1篇
  1963年   1篇
  1960年   1篇
  1938年   1篇
  1934年   1篇
  1933年   2篇
  1932年   2篇
  1930年   1篇
  1928年   2篇
  1920年   2篇
排序方式: 共有187条查询结果,搜索用时 15 毫秒
61.
    
In the presence of sufficient concentrations of water, stable, hydrated hydronium ions are formed in the pores and at the surface of solid acids such as zeolites. For a medium‐pore zeolite, such as zeolite MFI, hydrated hydronium ions consist of eight water molecules and have an effective volume of 0.24 nm3. In their presence, larger organic molecules can only adsorb in the portions of the pore that are not occupied by hydronium ions. As a consequence, the available pore volume decreases proportionally to the concentration of the hydronium ions. The higher charge density (the increasing ionic strength) that accompanies an increasing concentration of hydronium ions leads to an increase in the activity coefficients of the adsorbed substrates, thus, weakening the interactions between the organic part of the molecules and the zeolite and favoring the interactions with polar groups. The quantitative understanding of these interactions makes it possible to link a collective property such as hydrophilicity and hydrophobicity of zeolites to specific interactions on molecular level.  相似文献   
62.
63.
We have measured the complex conductivity sigma of a Bi(2)Sr(2)CaCu(2)O(8+delta) thin film between 0.2 and 0.8 THz. We find sigma in the superconducting state to be well described as the sum of contributions from quasiparticles, condensate, and order parameter fluctuations which draw 30% of the spectral weight from the condensate. An analysis based on this decomposition yields a quasiparticle scattering rate on the order of k(B)T/Planck's over 2pi for temperatures below T(c).  相似文献   
64.
Photoinduced magnetization dynamics is investigated in chemically ordered (LaMnO3)2n/(SrMnO3)n superlattices using the time-resolved magneto-optic Kerr effect. A monotonic frequency-field dependence is observed for the n=1 superlattice, indicating a single spin population consistent with a homogeneous hole distribution. In contrast, for n> or =2 superlattices, a large precession frequency is observed at low fields indicating the presence of an exchange torque in the dynamic regime. We attribute the emergence of exchange torque to the coupling between two spin populations-viscous and fast spins.  相似文献   
65.
Equilibrium conductivity fluctuations of mesoscopic domains are found in film and bulk single-crystal manganite colossal magnetoresistive material. Temperature and field dependences of the Boltzmann factors for a collection of two-state fluctuators give measures of the magnetic moment and entropy differences between the states, and of the fluctuator volumes. The large resistance step size implies dramatic current inhomogeneities. Occasional anomalous temperature dependences indicate that the film inhomogeneous phase is stabilized by a repulsive interaction between conducting regions.  相似文献   
66.
The temperature dependence of the d.c. conductivity, the dielectric loss and the permittivity of NaNO3 single crystals prepared by epitaxial accretion of the (111) plane of NaNO3 on the (001) plane of mica were investigated. The measurements were performed in a temperature range from 20–300C. Below the melting point a region of intrinsic conductivity (U I=3·08 eV), caused by Na+ ions which are in interstitial sites, was observed. At lower temperature a region II (U II= 0·87 eV), where the conductivity is due to the presence of divalent impurities, probably Ca+ + followed (structurally sensitive region). Up to 250C polarization is observed, most probably due to ion and electron shifting only. Above that temperature the influence of the relaxed orientation of the NO 3 groups becomes evident. At 275C the NO 3 s- groups behave in a completely disordered way as indicated by a sudden increase of the permittivity plotted against temperature.We should like to express our gratitude to RNDr. A. Kessler, DrSc, for his very valuable advice.  相似文献   
67.
The author grew CdS single crystals by his own method which is described here in addition to other methods. The material was either prepared by the author or commercial luminescence-pure material was used. The amount of impurities in the commercial material was an order higher than in the author's own material. It was found that the physical properties (e.g. hole density) are worse in large single crystals than in crystals with a mosaic structure. For this reason it is thought that some of the properties are caused by stoichiometric deviations and other by defects in the crystal lattice. In this case impurification plays only a secondary role.  相似文献   
68.
Sputtering studies with the Monte Carlo Program TRIM.SP   总被引:2,自引:0,他引:2  
The Monte Carlo Program TRIM.SP (sputtering version of TRIM) was used to determine sputtering yields and energy and angular distributions of sputtered particles in physical (collisional) sputtering processes. The output is set up to distinguish between the contributions of primary and secondary knock-on atoms as caused by in- and outgoing incident ions, in order to get a better understanding of the sputtering mechanisms and to check on previous theoretical models. The influence of the interatomic potential and the inelastic energy loss model as well as the surface binding energy on the sputtering yield is investigated. Further results are sputtering yields versus incident energy and angle as well as total angular distributions of sputtered particles and energy distributions in specific solid angles for non-normal incidence. The calculated data are compared with experimental results as far as possible. From this comparison it turns out that the TRIM.SP is able to reproduce experimental results even in very special details of angular and energy distributions.  相似文献   
69.
70.
Superlattices of (LaMnO3){2n}/(SrMnO3){n} (1or=3. Measurements of transport, magnetization, and polarized neutron reflectivity reveal that the ferromagnetism is relatively uniform in the metallic state, and is strongly modulated in the insulating state, being high in LaMnO3 and suppressed in SrMnO3. The modulation is consistent with a Mott transition driven by the proximity between the (LaMnO3)/(SrMnO3) interfaces. The insulating state for n>or=3 obeys variable range hopping at low temperatures. We suggest that this is due to states at the Fermi level that emerge at the (LaMnO3)/(SrMnO3) interfaces and are localized by disorder.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号