全文获取类型
收费全文 | 5760篇 |
免费 | 202篇 |
国内免费 | 43篇 |
专业分类
化学 | 4033篇 |
晶体学 | 35篇 |
力学 | 136篇 |
数学 | 1066篇 |
物理学 | 735篇 |
出版年
2024年 | 10篇 |
2023年 | 44篇 |
2022年 | 132篇 |
2021年 | 164篇 |
2020年 | 105篇 |
2019年 | 128篇 |
2018年 | 106篇 |
2017年 | 82篇 |
2016年 | 193篇 |
2015年 | 174篇 |
2014年 | 203篇 |
2013年 | 345篇 |
2012年 | 397篇 |
2011年 | 442篇 |
2010年 | 285篇 |
2009年 | 288篇 |
2008年 | 355篇 |
2007年 | 371篇 |
2006年 | 341篇 |
2005年 | 330篇 |
2004年 | 241篇 |
2003年 | 179篇 |
2002年 | 181篇 |
2001年 | 77篇 |
2000年 | 68篇 |
1999年 | 55篇 |
1998年 | 42篇 |
1997年 | 46篇 |
1996年 | 71篇 |
1995年 | 40篇 |
1994年 | 38篇 |
1993年 | 37篇 |
1992年 | 45篇 |
1991年 | 33篇 |
1990年 | 20篇 |
1989年 | 28篇 |
1988年 | 22篇 |
1987年 | 21篇 |
1986年 | 26篇 |
1985年 | 35篇 |
1984年 | 26篇 |
1983年 | 22篇 |
1982年 | 29篇 |
1981年 | 17篇 |
1980年 | 20篇 |
1979年 | 15篇 |
1978年 | 11篇 |
1977年 | 7篇 |
1975年 | 8篇 |
1974年 | 7篇 |
排序方式: 共有6005条查询结果,搜索用时 125 毫秒
51.
We consider a class of multitype particle systems in
d
undergoing spatial diffusion and critical stable multitype branching, and their limits known as critical stable multitype Dawson-Watanabe processes, or superprocesses. We show that for large classes of initial states, the particle process and the superprocess converge in distribution towards known equilibrium states as time tends to infinity. As an application we obtain the asymptotic behavior of a system of nonlinear partial differential equations whose solution is related to the distribution of both the particle process and the superprocess.Research partially supported by CONACyT (Mexico), CNRS (France) and BMfWuF (Austria). 相似文献
52.
Luiza Amália Moraes Luis Romero Grados 《Journal of Mathematical Analysis and Applications》2003,281(2):575-586
Let Au(BG) be the Banach algebra of all complex valued functions defined on the closed unit ball BG of a complex Banach space G which are uniformly continuous on BG and holomorphic in the interior of BG, endowed with the sup norm. A characterization of the boundaries for Au(BG) is given in case G belongs to a class of Banach spaces that includes the pre-dual of a Lorentz sequence space studied by Gowers in Israel J. Math. 69 (1990) 129-151. The non-existence of the Shilov boundary for Au(BG) is also proved. 相似文献
53.
LuisVazauez 《计算数学(英文版)》2003,21(4):491-494
We present a generalization of the linear one-dimensional diffusion equation by com-bining the fractional derivatives and the internal degrees of freedom. The solutions areconstructed from those of the scalar fractional diffusion equation. We analyze the in-terpolation between the standard diffusion and wave equations defined by the fractionalderivatives. Our main result is that we can define a diffusion process depending on theinternal degrees of freedom associated to the system. 相似文献
54.
The classes ofL
1-matrices,L
2-matrices,L
3-matrices andW-matrices are introduced to study solvability of a linear complementarity problem via solving a linear program. Three sufficient
conditions are presented to guarantee that a linear complementarity problem is solvable via a linear program. The new sufficient
conditions are weaker than the ones introduced by Mangasarian. This fact is also illustrated by an example.
Partially supported by NSFC.
This author is also with College of Business Administration of Human University as a Lotus chair professor. 相似文献
55.
Gheorghe Dinca Luis Sanchez 《NoDEA : Nonlinear Differential Equations and Applications》1994,1(2):163-178
In this paper we derive the existence of multiple solutions for boundary value problems of the type $$u\prime \prime + f\left( {t,u} \right) = 0,u\left( 0 \right) = 0,u\left( \pi \right) = 0$$ , in terms of the behaviour of the ratiof(t,u)/u nearu=0 and near infinity. The nonlinear termf is assumed to be locally Lipschitz inu, so that the shooting method can be used. (AMS Subject Classification: 34B15). 相似文献
56.
Luis M. Reyes Geraldo M. Ribeiro Benedicto J.O. Franco JoséLuiz A. Alves Manoel L. de Siqueira 《Solid State Communications》1981,40(12):1031-1034
We have interpreted the KCl:Cu? spectrum in the context of the MS-Xα method. The results, considering only allowed electric-dipole transitions, are in good agreement with the experimental data. Four new absorption bands, peaking at 573, 390, ~324 and ~310nm, at room temperature, are reported. 相似文献
57.
Eichhorn P Pérez S Aceña J Gardinali P Abad JL Barceló D 《Journal of mass spectrometry : JMS》2012,47(6):701-711
Recent publications on pharmaceutical monitoring are increasingly covering the field of illicit drugs and lately the forensic evaluation of designing illegal analogs of lifestyle drugs like the phosphodiesterase type 5 (PDE-5) inhibitors Viagra (sildenafil), Levitra (vardenafil) and Cialis (tadalafil). Recently, the presence of all three erectile dysfunction treatment drugs has been reported in wastewaters at very low concentrations. In the environment, contaminants undergo various physical or chemical processes classified into abiotic (photolysis, hydrolysis) and biotic (biodegradation) reactions. Thus, changes in the chemical structure lead to the formation of new transformation products, which may persist in the environment or be further degraded. This study describes the photolysis of sildenafil (SDF) and its human metabolite N-demethylsildenafil (DM-SDF) under simulated solar radiation (Xenon lamp). Following chromatographic separation of the irradiated samples, eight photoproducts in the SDF samples and six photoproducts for DM-SDF were detected and characterized. The combination of ultra performance liquid chromatography-electrospray ionization-quadrupole time-of-flight-mass spectrometry (UPLC-ESI-QToF-MS), liquid chromatography-atmospheric pressure chemical ionization-triple quadrupole mass spectrometry (LC-APCI-QqQ-MS) and hydrogen/deuterium-exchange experiments allowed to propose plausible chemical structures for the photoproducts, taking into account the characteristic fragmentation patterns and the accurate mass measurements. These mass spectral data provided sound evidence for the susceptibility of the piperazine ring toward photodegradation. A gradual breakdown of this heterocyclic structure gave rise to a series of products, which in part were identical for SDF and DM-SDF. The sulfonic acid, as the formal product of sulfonamide hydrolysis, was identified as key intermediate in the photolysis pathway. In both drug/metabolite molecules, phototransformation processes taking place beyond the sulfonamide group were deemed to be of minor relevance. 相似文献
58.
Leonard I. Wassenaar Liang-Feng Han Thomas Schiefer Gustav Kainz Luis Araguas-Araguas Pradeep K. Aggarwal 《Isotopes in environmental and health studies》2018,54(3):274-287
Tritium (3H) is an essential tracer of the Earth's water cycle; yet widespread adoption of tritium in hydrologic studies remains a challenge because of analytical barriers to quantification and detection of 3H by electrolytic pre-concentration. Here, we propose a simple tritium electrolytic enrichment system based on the use of solid polymer electrolyte membranes (PEMs) that can be used to enrich 3H in 250–3000?mL environmental water samples to a 10-mL final volume. The IAEA PEM-3H system reported here can produce high enrichment factors (>70-fold) and, importantly, removes some of the deterrents to conventional 3H enrichments methods, including the use of toxic electrolysis and neutralization chemicals, spike standards, a complex electrolysis apparatus that requires extensive cooling and temperature controls, and improves precision by eliminating the need for tracking recovery gravimetrics. Preliminary results with varying operating conditions show 3H enrichments to 70-fold and higher are feasible, spanning a wide range of tritium activities from 5 to 150 TU with a precision of ~4.5?%. Further work is needed to quantify inter-sample memory and to establish lower 3H detection limits. The IAEA PEM-3H system is open source, with 3-D CAD and design files made freely available for adoption and improvement by others. 相似文献
59.
Luis F. Lafuerza Louise Dyson Bruce Edmonds Alan J. McKane 《The European Physical Journal B - Condensed Matter and Complex Systems》2016,89(7):159
A recently proposed model of social interaction in voting is investigated by simplifyingit down into a version that is more analytically tractable and which allows a mathematicalanalysis to be performed. This analysis clarifies the interplay of the different elementspresent in the system – social influence, heterogeneity and noise – and leads to a betterunderstanding of its properties. The origin of a regime of bistability is identified. Theinsight gained in this way gives further intuition into the behaviour of the originalmodel. 相似文献
60.