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31.
This study focuses on the application of the carbon arc‐generated molybdenum‐ and tungsten‐based catalyst systems, MoCl5? C and WCl6? C, to effect ring‐opening metathesis polymerization (ROMP) of bicyclo[2.2.1]hept‐2‐ene (norbornene). The results are compared with those previously obtained by the electrochemically generated MoCl5? ē? Al? CH2Cl2 and WCl6? ē? Al? CH2Cl2 systems. The polymer products are characterized using 1H and 13C NMR, gel permeation chromatography, differential scanning calorimetry and thermo gravimetric analysis. According to NMR spectra analyses, the molybdenum‐based catalyst system produced polynorbornene with ca 48% cis structure whereas tungsten system produced ca 56% cis structure polynorbornene and in both cases the polynorbornene had a blocky distribution. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
32.
Zekerıya Biyiklioğlu Ece Tuğba Güner Halit Kantekin 《Journal of inclusion phenomena and macrocyclic chemistry》2008,60(3-4):235-240
A new (E,E)-dioxime, (2Z,3Z)-9,20-bis[(4-methylphenyl)sulfonyl]-1,4,7,8,9,10,11,12,14,15,17, 18,19,20,21,22-hexadecahydro-13,16-ethano[1,4,7,11,14,18]dioxatetraazacycloicosino[2,3-g] quinoxaline-2,3-dione dioxime (6) (H2L) has been synthesized by reacting cyanogen-di-N-oxide (5) with 4,15-bis[(4-methylphenyl)sulfonyl]-2,3,4,5,6,7,9,10,12,13,14,15,16,17-tetradecahydro-8,11-ethano-1,18,4,8,11,15-benzodioxatetraazacycloicosine-20,21-diamine
(4). Mononuclear complexes (7) and (8) of this ligand have been synthesized by reacting the vic-dioxime (H2L) with NiCl2.6H2O and CoCl2.6H2O respectively. The BF2+ capped Ni(II) and Co(III) complexes (9) and (10) of the dioxime have been synthesized from (7) and (8), respectively. The new compounds were characterized by a combination of elemental analysis, 1H- and 13C-NMR, IR. and MS. spectral data. 相似文献
33.
34.
We report the microstructural and magnetic properties of transition (3d) and rare earth (4f) metal substituted into the Ax:Zn1?xO (A=Mn, Gd and Mn/Gd) nanocrystal samples synthesized by solgel method. The structural properties and morphology of all samples have been analysed using X-ray diffraction (XRD) method and scanning electron microscopy. The impurity phase in the XRD patterns for all samples is not seen, except (Mn/Gd):ZnO sample where a very weak secondary phase of Gd2O3 is observed. Due to the large mismatch of the ionic radii between Mn2+ and Gd3+ ions, the strain inside the matrix increases, unlike the crystallite size decreases with the substitution of Mn and Gd into ZnO system. A couple of additional vibration modes due to the dopant have been observed in Raman spectrum. The magnetic properties have been studied by vibrating sample magnetometer. The magnetic hysteresis shows that Mn:ZnO and Gd:ZnO have soft ferromagnetic (FM) behaviour, whereas (Mn/Gd):ZnO has strong FM behaviour at room temperature (RT). The enhancement of ferromagnetism (FM) in (Mn/Gd):ZnO sample might be related to short-range FM coupling between Mn2+ and Gd3+ ions via defects potential and/or strain-induced FM coupling due to the expansion lattice by doping. The experimental results indicate that RTFM can be achieved by co-substitution of 3d and 4f metals in ZnO which can be used in spintronics applications. 相似文献
35.
Bulak E Leboschka M Schwederski B Sarper O Varnali T Fiedler J Lissner F Schleid T Kaim W 《Inorganic chemistry》2007,46(14):5562-5566
Complexes cis-MCl2(big), big=bis(1-methylimidazol-2-yl)glyoxal, M=Pt, Pd, were prepared and characterized through electrochemistry, spectroscopy, and for M=Pt, by X-ray structure analysis. The seven-membered chelate ring formed through N,N' coordination of the ligand big shows a boat conformation in agreement with density functional theory (DFT) calculation results. No significant intermolecular interactions were observed for the platinum compound. Both the PdII and PtII complexes undergo reversible one-electron reduction in CH2Cl2/ 0.1 M Bu4NPF6; the reduced palladium compound disintegrates above -30 degrees C. Electron paramagnetic resonance (EPR), UV-vis, and IR spectroelectrochemistry studies were employed to study the monoanions. The anion radical complex [cis-PtCl2(big)]*- exhibits a well-resolved EPR spectrum with small but well-detectable g anisotropy and an isotropic 195Pt hyperfine coupling of 12.2 G. DFT calculations confirm the spin concentration in the alpha-semidione part of the radical complex with small delocalization to the bis(imidazolyl)metal section. The results show that EPR and electroactive moieties can be linked to the cis-dichloroplatinum(II) group via imidazole coordination. 相似文献
36.
Analytical high-performance liquid chromatographic enantioseparation of 1-(4-chlorobenzhydryl) piperazine benzamide derivatives was accomplished on different chiral stationary phases. The enantiomers of the compounds were resolved by normal-phase chromatography on silica-based amylose tris(3,5-dimethylphenylcarbamate) (Chiralpak AD-H), cellulose tris(3,5-dimethylphenylcarbamate) (Chiralcel OD-H) and cellulose tris(4-methylbenzoate) (Chiralcel OJ) columns with mobile phases consisting of mixtures of n-hexane and ethanol in different proportions (90: 10, 80: 20). The mobile phase and the chiral stationary phase were varied to achieve the best resolution. The effect of the concentration of ethanol in the mobile phase was studied. The resolution obtained on the three columns was significant. 相似文献
37.
In sampling theory, the traditional ratio estimator is the most common estimator of the population mean when the correlation between study and auxiliary variables is positively high. We introduce a new ratio-type estimator based on the order statistics of a simple random sample. We show that this new estimator is considerably more efficient than the traditional ratio estimator under non-normality, and remarkably robust to data anomalies such as presence of outliers in data sets. 相似文献
38.
The synthesis and characterization of new peripherally tetra-4-benzyloxybenzoxy substituted metal-free, zinc and lead phthalocyanines are described for the first time in this study. The influence of various organic solvents and the nature of the central metal ion on the spectroscopic, photophysical and photochemical properties has been investigated. General trends are described for photodegradation, singlet oxygen and fluorescence quantum yields, and fluorescence lifetimes of these compounds in different solvents. Photophysical and photochemical properties of phthalocyanine compounds are very useful for photodynamic therapy applications. Especially high singlet oxygen quantum yields are very important for Type II mechanism. The studied phthalocyanine compounds showed good singlet oxygen generation and these compounds show potential as Type II photosensitizers. The fluorescences of the studied compounds are effectively quenched by 1,4-benzoquinone in different solvents. 相似文献
39.
In our study, the single‐use & eco‐friendly electrochemical sensor platform based on herbal silver nanoparticles (AgNPs) was developed for detection of mercury (II) ion (Hg2+). For this purpose, the surface of pencil graphite electrode (PGE) was modified with AgNPs and folic acid (FA), respectively. The concentrations of AgNPs and FA were firstly optimized by differential pulse voltammetry (DPV) to obtain an effective surface modification of PGE. Each step at the surface modification process was characterized by using cyclic voltammetry (CV) and electrochemical impedence spectroscopy (EIS). The limit of detection (LOD) for Hg2+ was estimated and found to be 8.43 μM by CV technique. The sensor presented an excellent selectivity for Hg2+ against to other heavy metal ions such as Ca2+, Cd2+, Cr3+, Cu2+, Mg2+, Ni2+, Pb2+, Zn2+, Co2+ and Mn2+. Moreover, a rapid, selective and sensitive detection of Hg2+ was successfully performed in the samples of tap water within 1 min. 相似文献
40.
Ece Aktas Jesús Jiménez-López Cristina Rodríguez-Seco Dr. Rajesh Pudi Dr. Manuel A. Ortuño Prof. Núria López Prof. Emilio Palomares 《Chemphyschem》2019,20(20):2702-2711
Truxene derivatives, due to their molecular structure and properties, are good candidates for the passivation of defects when deposited onto hybrid lead halide perovskite thin films. Moreover, their semiconductor characteristics can be tailored through the modification of their chemical structure, which allows-upon light irradiation- the interfacial charge transfer between the perovskite film and the truxene molecules. In this work, we analysed the use of the molecules as surface passivation agents and their use in complete functional solar cells. We observed that these molecules reduce the non-radiative carrier recombination dynamics in the perovskite thin film through the supramolecular complex formation between the Truxene molecule and the Pb2+ defects at the perovskite surface. Interestingly, this supramolecular complexation neither affect the carrier recombination kinetics nor the carriers collection but induced noticeable hysteresis on the photocurrent vs voltage curves of the solar cells under 1 sun illumination. 相似文献